• Title/Summary/Keyword: Ultra-fine structure

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Manufacture of Ultra Fine CuO Powder from Waste Copper Chloride Solution by Spray Pyrolysis Process

  • Yu, Jae-Keun;Ahn, Zou-Sam;Sohn, Jin-Gun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.165-170
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    • 2001
  • The main purpose of this study is to generate a fine copper oxide powder of high purity, with a compact structure and a uniform particle size by a spray pyrolysis process. The raw material is a waste copper chloride solution formed in the manufacturing process of Print Circuit Board (PCB). This study also examines the influences of various factors on the properties of the generated powder. These factors include the reaction temperature, the inflow speed of the raw material solution, the inflow speed of the air, the size of the nozzle tip, and the concentration of the raw material solution. It is discovered that, as the reaction temperature increases from 80$0^{\circ}C$ to 100$0^{\circ}C$ , the particle size of the generated powder increases accordingly, and that the structure of the powder becomes much more compact. When the reaction temperature is 100$0^{\circ}C$, the particle size of the generated powder increases as the concentration of copper in the raw material solution increases to 40g/l, decreases as the concentration increases up to 120g/l, and increases again as the concentration reaches 200g/1. In the case of a lower concentration of the raw material solution, the generated powder appears largely in the form of CuO. As the concentration increases, however, the powder appears largely in the form of CuCl. When the concentration of copper in the raw material solution is 120g/1, the particle size of the generated powder increases as the inflow speed of the raw material solution increases. When the concentration of copper in the raw material solution is 120g/1, there is no evident change in the particle size of the generated powder as the size of the nozzle tip and the air pressure increases. When the concentration is 40g/1, however, the particle size keeps increasing until the air pressure increases to 0.5kg/$\textrm{cm}^2$, but decreases remarkably as the air pressure exceeds 0.5kg/$\textrm{cm}^2$.

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The Effects of the Annealing on the Reflow Property of Cu Thin Film (열처리에 따른 구리박막의 리플로우 특성)

  • Kim Dong-Won;Kim Sang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.38 no.1
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    • pp.28-36
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    • 2005
  • In this study, the reflow characteristics of copper thin films which is expected to be used as interconnection materials in the next generation semiconductor devices were investigated. Cu thin films were deposited on the TaN diffusion barrier by metal organic chemical vapor deposition (MOCVD) and annealed at the temperature between 250℃ and 550℃ in various ambient gases. When the Cu thin films were annealed in the hydrogen ambience compared with oxygen ambience, sheet resistance of Cu thin films decreased and the breakdown of TaN diffusion barrier was not occurred and a stable Cu/TaN/Si structure was formed at the annealing temperature of 450℃. In addition, reflow properties of Cu thin films could be enhanced in H₂ ambient. With Cu reflow process, we could fill the trench patterns of 0.16~0.24 11m with aspect ratio of 4.17~6.25 at the annealing temperature of 450℃ in hydrogen ambience. It is expected that Cu reflow process will be applied to fill the deep pattern with ultra fine structure in metallization.

A study on the optimal control of Long Stroke Fast Tool Servo Systems (장거리 구동용 FTS 의 최적 제어에 관한 연구)

  • 이상호;이찬홍;김갑순
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.818-821
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    • 2004
  • With a rapid development in the area of micro and ultra precision technology, the micro surface machining of small size parts are explosively increased. Especially, to improve efficiency of various beams in lens and reflector, non-rotational symmetric form and several mm level heights changeable surface can be machined at a time. These geometric complex 3D surface cannot be machined by general short stroke FTS. The long stroke FTS if firmly needed to move directly several mm and have nm level positioning accuracy for the complex surface form. The long stroke FTS used linear motors to drive moving unit long and fine, aero static bearings to decrease friction and moving errors in guide way, optical linear scale with nm level resolution to measure position of FTS. Furthermore, to increase the performance of acceleration of FTS, the light material, such as AL is used for the structure and the high stiffness box type structure is selected. In this paper, the genetic algorithm approach is described to determine a set of design parameters for auto tuning. The authors have attempted to model the design problem with the objective of minimizing the error, such as variable pattern change. This method can give the better alternative than existing other method.

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Tensile Properties of High Mn Austenitic Stainless Steel with Two Phases of Martensite and Austenite (마르텐사이트와 오스테나이트의 2상 조직을 갖는 고 Mn 오스테나이트계 스테인리스강의 인장성질)

  • Kim, Young-Hwa;Kang, Chang-Yong
    • Journal of Ocean Engineering and Technology
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    • v.27 no.4
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    • pp.9-13
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    • 2013
  • The tensile properties of high manganese austenitic stainless steel with the two phase structures of deformation-induced martensite and reversed austenite were studied. Reversed austenite with an ultra-fine grain size of less than $0.3{\mu}m$ was obtained by reversion treatment. The two phases structures of deformation-induced martensite and reversed austenite were obtained by an annealing treatment in the range of $500^{\circ}C-700^{\circ}C$ for various times in 70% cold- rolled high-manganese austenitic stainless steel. The volume fraction of the reversed austenite increased rapidly with increases in the annealing temperature and time. In the stainless steel with the two phases of austenite and martensite, the strength decreased rapidly, while the elongation increased slowly and then rapidly increased with an increase in the volume fraction of the reversed austenite. Therefore, the strength and elongation were strongly controlled by the volume fraction of reversed austenite. A good combination of high strength and elongation could be obtained by the mixed structure of reversed austenite and deformation-induced martensite.

Joint properties and Interface Analysis of Friction Stir Welded Dissimilar Materials between Austenite Stainless Steel and 6013 Al Alloy (마찰교반접합한 오스테나이트계 스테인리스강과 6013알루미늄 합금 이종 접합부의 접합 특성 및 계면 성질)

  • Lee, Won-Bae;Biallas, gehard;Schmuecker, Martin;Jung, Seung-Boo
    • Journal of Welding and Joining
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    • v.23 no.5
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    • pp.61-68
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    • 2005
  • Dissimilar joining of Al 6013-T4 alloys and austenite stainless steel was carried out using friction stir welding technique. Microstructures near the weld zone and mechanical properties of the joint have been investigated. Microstructures in the stainless steel side were composed of the heat affected zone and the plastically deformed zone, while those in the Al alloy side were composed of the recrystallized zone including stainless steel particles, the thermo-mechanically affected zone and the heat affected zone. TEM micrographs revealed that the interface region was composed of the mixed layers of elongated stainless steel and ultra-fine grained Al alloy with lamella structure and intermetallic compound layer. Thickness of the intermetallic layer was approximately 300nm and was identified as the A14Fe with hexagonal close packed structure. Mechanical properties, such as tensile and fatigue strengths were lower than those of 6013 Al alloy base metal, because tool inserting location was deviated to Al alloy from the butt line, which resulted in the lack of the stirring.

Diagnostic Application of Temporomandibular Joint Disorder and Ultra Sound Guided Oral &Maxillofacial application (초음파를 이용한 턱관절질환의 진단과 초음파 가이드의 활용)

  • Seong, Tae-Hwan;Park, Jung-Hyun;Kim, Sun-Jong
    • The Journal of the Korean dental association
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    • v.55 no.11
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    • pp.789-799
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    • 2017
  • Ultrasound images are noninvasive, can be observed in real time, have no radiation exposure, do not cause pain, and are not restricted in use depending on the patient's prosthetic implant or medical condition. Since the use of ultrasound in the dental field was first applied for tooth preparation in 1957, the use of diagnostic ultrasound for the first time in 1963 has been reported. Currently, it is used in the diagnosis of soft tissue lesions such as malignant tumor or salivary gland disease, fine needle aspiration test, temporomandibular joint disease, lymph node metastasis, measurement of muscle thickness and inflammatory diseases, differentiation of periapical cyst and granulation tissue, measurement of periodontal tissue thickness. The ultrasound image can be visualized in real time. The clinician can explain the structure to the patient while consulting the patient and consult the patient. When injecting the drug into a specific site or aspirating a specific site or substance, So that it can be confirmed and practiced. Recently, ultrasonic equipment specialized in the dental field has been developed and marketed, and it is expected that the use of ultrasonic waves will become active in the dentistry. In the future, development of popular equipment with size and frequency suitable for dental diagnosis and various researches on maxillofacial ultrasonic anatomy. If clinical studies are continuously carried out to demonstrate efficacy, ultrasound is expected to aid in accurate diagnosis and treatment throughout the dentistry.

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Properties of Ultra High Performance Fiber Reinforced Cementitious Composites Mixed with Limestone Powder (석회석 미분말을 혼입한 초고성능 섬유보강 시멘트복합재의 특성)

  • Han, Sang-Mook;Wu, Xiang-Guo
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.2
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    • pp.23-30
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    • 2008
  • UHPC has high performance, high strength and excellent mechanical properties. Moreover UHPC(Ultra High Performance Cementitious Composite) has advantage to reduce cross section under the same load compared with other kinds of concrete. But silica fume which is imported from foreign country has a abundant portion in UHPC mixture in comparison with normal concrete. This is one of the main reason to raise the construction cost. Superior mechanical properties of UHPC due to the optimum filling composition can be changed by replacing the very fine ingredient. The purpose of this research is to grasp the characteristic of UHPC which silica fume and silica flour is replaced with limestone powder. This experiment can be divided into three classes according to the kinds of replacement. The compressive strength and flow of all types were measured and microstructure and hydration phenomena for comparing RPC were analyzed by SEM, XRD, NMR method. As a result, the replacement can be considered to be effective by for the decrease of the UHPC structure construction cost and improvement of the fresh UHPC.

Ultra high precision Dual stage system Using Air bearing and VCM for Nano level Scanning (VCM을 이용한 나노 정밀도 스캐닝 용 초정밀 이중 스테이지)

  • Kim Ki-Hyun;Gweon Dae-Gab;Choi Young-Man;Kim Dong-Min;Nam Byoung-Uk;Lee Suk-Won;Lee Moon-Gu
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.5 s.170
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    • pp.103-112
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    • 2005
  • This paper presents one-axis high precision scanning system and illustrates the design of modified $X-Y-{\theta}$ stage as a tracker using VCM and commercialized air bearings for it. The scanning system for 100nm resolution is composed of the 3-axis stage and one axis long stroke linear motor stage as a follower. In this study a previous proposed and presented structure of VCM for the fine stage is modified. The tracker has 3 DOF($X-Y-{\theta}$ motions by four VCM actuators which are located on the same plane. So 4 actuating forces are suggested and designed to create least pitch and roll motions. This article will show about the design especially about optimal design. The design focus of this fine stage is to have high acceleration to accomplish high throughput. The optimal design of maximizing acceleration is performed in restrained size. The most sensitive constraint of this optimal design is heat dissipation of coil. There are 5 design variables. Because the relationship between design variables and system parameters are quite complicated, it is very difficult to set design variables manually. Due to it, computer based optimal design procedure using MATLAB is used. Then, this paper also describes the procedures of selecting design variables for the optimal design and a mathematical formulation of the optimization problem. Based on the solution of the optimization problem, the final design of the stage is also presented. The results can be verified by MAXWELL. The designed stage has the acceleration of about 5 $m/s^{2}$ with 40kg total mass including wafer chuck and interferometer mirror. And the temperature of coil is increased $50^{\circ}C$. In addition, the tracker is controlled by high precision controller system with HP interferometer for it and linear scaler for the follower. At that time, the scanning system has high precision resolution about 5nm and scanning resolution about 40nm in 25mm/s constant speed

Analysis of Infiltration of Outdoor Particulate Matter into Apartment Buildings (외기 중 미세먼지의 공동주택 실내 유입에 관한 연구)

  • Bang, Jong-Il;Jo, Seong-Min;Sung, Min-Ki
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.1
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    • pp.61-68
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    • 2018
  • Recently, concentration of fine and ultra-fine particulate matter(PM) has been increased in KOREA. The increase of PM in KOREA is due to increase of domestic industries and yellow dust from china. PM is known to cause diseases such as dyspnoea, asthma, arrhythmia. Since PM is harmful to human, KOREA Ministry of Environment(ME) warns people to stay indoors when the outdoor PM concentration is high. However, prior studies has shown that indoor PM concentration can be relatively high when outdoor PM concentration is high due to infiltration of PM into buildings though leakage areas. In this study, airtightness, indoor and outdoor pressure difference and PM 2.5 & 10 concentration were measured in an apartment complex to observe PM infiltrating into building. Field measurement was conducted in newly-built apartment buildings to avoid the influence of indoor PM which can be generated by residents. The airtightness test was conducted to identify the leakage areas of the apartment, such as electric outlets and supply/exhaust diffusers. The airtightness test result showed that the air leakage area of the building was dominant in buildings envelop. According to indoor and outdoor pressure difference measurement result and PM concentration measurement result, it can be concluded that outdoor PM can infiltrate into indoor by leakage areas when wind is blown toward the apartment. As a result, pressure difference formed by the external weather condition and architectural characteristics such as the airtightness in building can influence PM to infiltrate into buildings. In further studies, I/O ratio, stack-effect, infiltration and penetration factor will be considered.

A weld-distortion analysis method of the shell structures using ultra structural FE model (초대형 구조모델을 활용한 쉘구조물의 용접변형 해석)

  • Ha, Yunsok;Yi, Myungsu
    • Journal of Welding and Joining
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    • v.33 no.3
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    • pp.62-67
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    • 2015
  • A very large shell-structure built in shipyards like ship hulls or offshore structures are joined by welding through full process. As the welding contains a high thermal cycle at a local area, the welded structures should be distorted unavoidably. Because a distorted ship block should be revised to the designed value before the next stage, the ability to predict and to control the weld distortion is an accuracy level of the yard itself. Despite the ship block size, several present thermal distortion methodologies can deal those sizes, but it is a different story to deal full ship size model. Even a fully constructed ship hull not remaining any welding can have an accuracy issue like outfitting installation problems. Any present thermal distortion methodology cannot accept this size for its recommended element size and the number. The ordinary welding breadth at erection stage is about 20~40 mm. It can hardly be a good choice to make finite element model of these sizes considering human effort and computational environment. The finite element model for structure analysis of a ship hull is prepared at front-end engineering design stage which is the first process of the project. The element size of the model is as fine as the longitudinal space, and it is not proper to obtain a weld distortion at the erection stage. In this study, a methodology is suggested that a weldment can be shrunk at original place instead of using structural finite element model. We cut the original shell elements at erection weld-line and put truss elements between the edges of cut elements for weld shrinkage. Additional truss elements are used to facsimile transverse weld shrinkage which cannot be from the weld-line truss element shrink. They attach to weld-line truss element like twigs from barks. The capacity of developed elements is verified through an accuracy check of erection process of a container vessel at the apt. hull. It can be a useful tool for verifying a centering accuracy after renew and for block-separating planning considering accuracy.