• Title/Summary/Keyword: Ultra Violet(UV)

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Long-Term Performance of Geomembranes by Oxidative Induction Time

  • Jeon, Han-Yong;Kim, Hong-Kwan;Keum, Jae-Ho;Jang, Yong-Chea;Lyoo, Won-Seok;Ghim, Han-Do
    • Journal of the Korean Geosynthetics Society
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    • v.2 no.3
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    • pp.19-24
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    • 2003
  • Long-term performance of smooth and textured type HDPE geomembranes which were used to the liner and slope systems of waste landfills was examined. Artificial surface defects were added to the surface of geomembranes by scratch addition apparatus specially designed. The mechanical and frictional properties, chemical and ultra violet light resistances and oxidative induction time(OIT) of geomembranes were examined for the cases of defective/non-defective surfaces. Frictional properties of textured type geomembranes showed more excellent than those of smooth type geomembranes. Finally, it was known that the long-term performance of non-defective and textured geomembranes was better than that of defective geomembranes through chemical and UV resistance and OIT tests etc.

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Catalytic combustion type hydrogen gas sensor using TiO2 and UV LED (TiO2 광촉매와 UV LED를 이용한 접촉연소식 수소센서)

  • Hong, Dae-Ung;Han, Chi-Hwan;Han, Sang-Do;Gwak, Ji-Hye;Lee, Sang-Yeol
    • Journal of Sensor Science and Technology
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    • v.16 no.1
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    • pp.7-10
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    • 2007
  • A thick film catalytic gas sensors which can be operated at $142^{\circ}C$ in presence of ultra violet-light emitting diode has been developed to measure hydrogen concentration in 0-5 % range. The sensing material as a combustion catalyst consists of $TiO_{2}$ (5 wt%) and Pd/Pt (20 wt%) supported on $Al_{2}O_{3}$ powder and the reference material to compensate the heat capacity of it in a bridge circuit was an catalyst free $Al_{2}O_{3}$ powder. Platinum heater and sensor materials were formed on the alumina plate by screen printing method and heat treatment. The effect of UV radiation in the presence of photo catalyst $TiO_{2}$ on the sensor sensitivity, response and recovery time has been investigated. The reduction of operating temperature from $192^{\circ}C$ to $142^{\circ}C$ for hydrogen gas sensing property in presence of UV radiation is attributed to the hydroxy radical and superoxide which was formed at the surface of $TiO_{2}$ under UV radiation.

A Study on the Development of an Energy Saving Ballast Water Treatment Device (I) (에너지 절감형 평형수 처리장치 개발에 관한 연구 (I))

  • Park, Dae-Won;Kil, Gyung-Suk;Choi, Yong-Ki;Choi, Chul-Young;Chang, Ji-Ho;Cheon, Sang-Gyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.6
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    • pp.880-886
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    • 2010
  • In this paper, we studied the application of low pressure ultra-violet (UV) lamps for the development of an energy saving ship's ballast water treat (BWT) device. We proposed the optimal arrangement of UV lamps by analyzing the energy radiated from medium- and low-pressure UV lamps. Based on the experimental results, we manufactured a disinfection chamber which is composed of low-pressure UV lamps. The rated power and the treatment capacity of the chamber are 216 [W] and 10 [$m^3$/h], respectively. This can replace a disinfection chamber treated by two 2 [kW] medium pressure lamps. The disinfection performance, however the power consumption is about one-eighteen compare to the medium pressure UV lamp, is over 94 [%] for bacteria, 93 [%] for zooplankton, and 94 [%] for phytoplankton. Therefore, it would be possible to develop an energy saving BWT device in a low capacity below 100 [$m^3$/h].

New Photochemistry of UV-Absorbing Chemicals in Phase-Controlled Polymer Microspheres (상구조가 조절된 고분자 미립구에서 자외선 흡수제의 거동에 대한 연구)

  • Lee Jong-Suk;Kim Jin-Woong;Kim Junoh;Han Sang-Hoon;Chang Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.361-367
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    • 2004
  • In this study, a different UV (ultra-violet) ray absorption system is presented in which butyl methoxydiben-zoylmethane (BMDM, a model UV-A absorbent, 320$\~$400 nm) is stabilized in phase-controlled poly(methyl methacrylate) (PMMA) microspheres. The photochemistry of BMDM in the microspheres was investigated considering its phase characteristics therein. The analysis of a differential scanning calorimeter and X-ray diffractometer showed that the BMDM in the microspheres was present with a non-crystalline state. The phase control of BMDM in the polymer microsphere has an excellent ability to protect UV-A with maintaining its photo- and thermal stability. The results obtained in this study illustrate well that the phase control of the UV absorbents in the polymer microspheres is another key factor that de-termines its photochemistry and photostability in the final formulations.

Measurement of the Refractive Index of a Mixed Polymer by a Prism Spectrometer and its Application (프리즘 분광계를 이용한 혼합 폴리머의 굴절률 측정과 응용)

  • Kim, Ji-Young;Ju, Young-Gu
    • Korean Journal of Optics and Photonics
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    • v.28 no.5
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    • pp.221-228
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    • 2017
  • We measured the refractive index of a mixed polymer (NOA61, NOA84) in the liquid and solid states. First we made a hollow prism and filled it with UV (ultraviolet) epoxy. Measurement of the apex angle and the minimum-deviation angle gave the refractive index of the liquid polymer. To measure the refractive index of the solid polymer, an additional structure was included in the hollow prism, and the UV epoxy filling in the hollow prism was hardened. In both cases of liquid and solid polymers, the refractive index of the mixed polymer turned out to be proportional to the mix ratio. These results provide a method to vary the focal length of a double stacked cylindrical microlens array using UV epoxy.

A Study for Degradation Mechanism of Plastic Materials (플라스틱 소재의 탈변색 열화 메커니즘 분석)

  • Youn, Hyung-Joon;Jung, Won-Wook;Byun, Doo-Jin;Choi, Gi-Dae
    • Journal of Applied Reliability
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    • v.7 no.4
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    • pp.173-181
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    • 2007
  • Out door exposure to daylight and weather climate conditions can cause adverse effect on the properties of automotive plastic materials. The effects of sunlight exposure, especially ultra violet (UV) radiation, can break down the chemical bonds in a polymeric material. This degradation process is called photo-degradation and ultimately leads to color changes, cracking, chalking, the loss of physical properties and deterioration of other properties. To explore the effect of sunlight exposure on the automotive materials, this study investigated photo-oxidation degree and surface property change of molding parts by analytical methods. For the further study, accelerated weathering test methods are proposed, which can correlate with out door weathering, to predict long term performance of automotive plastic materials.

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Photodecomposition of Tar Colorant With Zinc Oxide Suspension (산화아연 현탁액에 의한 타르색소의 광분해)

  • Jeong, Kap-Seop
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1155-1161
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    • 2006
  • The characteristics of photocatalytic degradation of tar colorants such as brilliant blue FCF(BBF) and tartrazine(TTZ) with zinc oxide suspension was studied in a batch reactor under irradiation of ultra-violet ray. Photocatalytic degradation of TTZ with ZnO was more higher than that of BBF, and was Increased with dosage of ZnO below 5g, but was nearly affected with initial pH of two tar colorants aqueous solution. Ammonium persulfate was more effective oxidant than potassium bromate which slightly increased the degradation of BBF, but not increased the degradation of TTZ. The photocatalytic degradation rates of BBF and TTZ were pseudo-first order with rate constants of 0.0066, 0.0092 and $0.015min^{-1}$ for BBF, 0.042, 0.017 and $0.110min^{-1}$ for TTZ at the dosage of 1, 2 and 5g ZnO, respectively.

Development of Optical Head Unit for Nano Optical Probe Array (나노 광 프로브 어레이 구현을 위한 광학 헤드 유닛 개발)

  • Kim H.;Lim J.;Kim S.;Han J.;Kang S.
    • Transactions of Materials Processing
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    • v.15 no.1 s.82
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    • pp.21-26
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    • 2006
  • A optical head unit for nano optical probe array was developed. The optical probe array is generated by Talbot effect. The shape and thickness of microlens array(MLA) were designed to minimize the spot size at the foci of MLA. To increase the optical efficiency of the system and obtain the large tolerance for fabrication, aperture size was theoretically optimized. Then microlens illuminated aperture array(MLIAA) as an optical head unit was fabricated using a ultra violet(UV) molding process on aluminum aperture array. In this process, Al aperture array was fabricated separately using the photolithography and reactive ion etching(RIE) process. Optical properties of the generated optical probes were measured and compared at Talbot distance from the aperture array having a diameter of $1{\mu}m$ and MLIAA.

Photocatalytic Degradation of Brilliant Blue FCF with TiO2 Suspension (TiO2현탁액에 의한 Brilliant Blue FCF의 광촉매 분해)

  • Jeong, Gap Seop;Choe, Su Il
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.599-603
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    • 2004
  • In a batch reactor, the characteristics of photocatalytic degradation of brilliant blue FCF in titanium dioxide suspension was studied under the irradiation of ultra-violet ray. Photocatalytic degradation in anatase type of TiO$_2$ was more effective than in rutile type of $TiO_2$ below the dosage of 5g. The degradation rate was slightly increased with decreasing initial pH of brilliant blue FCF aqueous solution, but rapidly increased with the addition of oxidant. Potassium bromate acted as more effective oxidant than ammonium persulfate. The photocatalytic degradation rate of brilliant blue FCF was pseudo-first order with rate constants of 0.012, 0.006 and $0.003min^{-1}$ at initial pH 3.1, 5.2 and 7.1 of brilliant blue FCF solution, respectively.

Effective Annealing and Crystallization of Si Film for Advanced TFT System

  • Noguchi, Takashi
    • Journal of Information Display
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    • v.11 no.1
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    • pp.12-16
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    • 2010
  • The effect of the crystallization and activated annealing of Si films using an excimer laser and the new CW blue laser are described and compared with furnace annealing for application in advanced TFTs and for future applications. Pulsed excimer laser annealing (ELA) is currently being used extensively as a low-temperature poly-silicon (LTPS) process on glass substrates as its efficiency is high in the ultra-violet (UV) region for thin Si films with thickness of 40-60 nm. ELA enables extremely low resistivity relating to high crystallinity for both the n- and p-type Si films. On the other hand, CW blue laser diode annealing (BLDA) enables the smooth Si surface to have arbitral crystal grains from micro-grains to an anisotropic huge grain structure only by controlling its power density. Both annealing techniques are expected to be applied in the future advanced TFT systems.