• 제목/요약/키워드: UV-spectroscopic

검색결과 343건 처리시간 0.041초

Identification of Afzelin and Quercitrin from Pinus koraiensis and Their Contents in Genus Pinus Using HPLC/UV Analysis

  • Lee, Dong Gu;Ryu, Min Ju;Cho, Sunghun;Chung, Ha Sook;Lee, Sanghyun
    • Natural Product Sciences
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    • 제20권3호
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    • pp.206-210
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    • 2014
  • Phytochemical constituents were isolated from Pinus koraiensis needles by open column chromatography. The structures isolated from the ethyl acetate fraction of P. koraiensis needles were elucidated as afzelin (1) and quercitrin (2) on the basis of spectroscopic analyses including $^1H$-NMR and MS. The amounts of afzelin (1) and quercitrin (2) in genus Pinus were determined by HPLC/UV analysis. Afzelin (1) and quercitrin (2) contents were highest in P. thunbergii needles. Because P. thunbergii needles contain high amounts of afzelin (1) and quercitrin (2), they have promising potential as new additives to natural medicinal products, health supplements, and beverages.

전도성 양친매성의 Nanoscale LB 막의 전기적 특성 (Electrical Properties of Nanoscale LB Layers of Amphiphilic Conducting Material)

  • 최인희;박수길;김재호;조병호;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.221-224
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    • 1996
  • We synthesized amphiphilic material including dye skeleton, p-phenylenediamine(PD) by attaching norma-decyl group of two strands at a part of coordinating atom, for obtaining reasonable design of LB uniform films. The synthesis of this compounds was quantitatively carried out under ultra pure state. This product was identified with FT-lR spectroscopy, UV absortion spectroscopy, and $^1$H-NMR spectroscopy, respectively. When manufacturing monolayer, we confirmed molecular area from pressure-area($\pi$-A) cutie of thiscompound onto the surface of the water. The spectroscopic approach also has done by UV absortion spectroscopy. It was shown that PD-complex LBfilms were deposited well with monolayer thickness. The conductivity based on I-V characteristics of PD-complex LB films were in the range of 10$^{-10}$ S/cm at room temperture. The microscopic properties by AFM, showed the good orientation of various monolayer or multilayer molecules

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Spectroscopic investigations on the interaction of bovine serum albumin with amoxicillin and cloxacillin

  • BHALCHANDRA P. KAMAT,
    • Journal of Photoscience
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    • 제12권1호
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    • pp.11-15
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    • 2005
  • The mechanism of interaction of two drugs viz., amoxicillin and cloxacillin with bovine serum albumin has been investigated using fluorescence absorption and circular dichroism spectroscopy. The quenching mechanism of fluorescence of bovine serum albumin by amoxicillin and cloxacillin was discussed. The binding sites number n and apparent binding constant Kwere measured by fluorescence quenching method. The thermodynamic parameters obtained from data at different temperatures were calculated. The distance r between donor (bovine serum albumin) and acceptor (amoxicillin and cloxacillin) was obtained according to Forster theory of non-radiative energy transfer. The effect of common ions on binding constant was also investigated. The results of synchronous fluorescence spectra, UV-vis absorption spectra and circular dichroism of BSA in presence of amoxicillin and cloxacillin show that the conformation of bovine serum albumin changed

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MEASUREMENT OF PESTICIDES RESIDUES USING SPECTROSCOPY ON AGRICULTURAL PRODUCTS

  • Kim, Y. W.;S. H. Noh
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 2000년도 THE THIRD INTERNATIONAL CONFERENCE ON AGRICULTURAL MACHINERY ENGINEERING. V.III
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    • pp.525-532
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    • 2000
  • A new spectroscopic method for pesticide residues detection on agricultural products was developed. The general determination methods are high performance liquid chromatography (HPLC), gas chromatography (GC) or GC-mass spectrometry. They have provided relatively good detection limit and accuracy with complicated and time-consuming (5hrs above) procedures. In addition freshness is very important for evaluating qualities of agricultural products. This requires a simple and fast method for detection of pesticides. Reflectance, transmittance and fluorescence spectrometry of pesticides were tested using UV range because most of pesticides contain conjugation band in the molecular structures. Fluorescence spectrometry showed better sensitive to detect pesticide residues than did reflectance and transmittance spectrometry. Intensity and shape of fluorescence spectra showed different patterns with different structures of pesticides. Detection limit for fluorescence spectrometry was 0.1 ppm to 10 ppm depending on the structures of pesticides. Application of fluorescence spectrometry appears to be an easy method for detection of pesticide residues on agricultural products.

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Ultraviolet Color-Magnitude Relations of Early-type Dwarf Galaxies in the Viro Cluster

  • Kim, Suk;Rey, Soo-Chang;Sung, Eon-Chang;Jerjen, Helmut;Lisker, Thorsten;Lee, Youngdae;Chung, Jiwon;Yi, Wonhyeong;Park, Mina
    • 천문학회보
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    • 제38권2호
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    • pp.47.2-47.2
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    • 2013
  • We present ultraviolet (UV) color-magnitude relations (CMRs) of early-type dwarf galaxies in the Viro cluster, combining Galaxy Evolution Explorer (GALEX) UV data with SDSS optical data, based on the Extended Virgo Cluster catalog (EVCC). We find that dwarf lenticular galaxies (dS0s) show a surprisingly distinct and tight locus separated from that of ordinary dEs, which is not clearly seen in previous CMRs. The dS0s in UV CMRs follow a steeper sequence than dEs and show bluer UV-optical color at a given magnitude. We explore the observed CMRs with population models of a luminosity-dependent delayed exponential star formation history. The observed CMR of dS0s is well matched by models with relatively long delayed star formation. The dS0s are most likely transitional objects at the stage of subsequent transformation of late-type progenitors to ordinary red dEs in the cluster environment. Most early type dwarf galaxies with blue UV colors (FUV-r < 6 and NUV-r < 4) are identified as those showing spectroscopic hints of recent or ongoing star formation activities. In any case UV photometry provides a powerful teel to disentangle the diverse subpopulations of early-type dwarf galaxies and uncover their evolutionary histories. lenticular galaxies, and irregular high surface brightness (HSB) galaxies, respectively. Dwarf elliptical galaxies and dwarf irregular LSB galaxies occupy the similar structural parameter spaces. We suggest that giant elliptical galaxies and dwarf elliptical galaxies may have different origin.

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IUE ARCHIVAL SPECTRA OF 31 CYGNI

  • Kang, Young-Woon
    • Journal of Astronomy and Space Sciences
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    • 제8권1호
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    • pp.53-61
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    • 1991
  • UV light curve of 31 Cygni has been made from the IUE high dispersion specta. The depth of primary minimum of the light curve is 5.2 magnitudes because the B4 star's steep spectral gradient. The light curve has been analyzed by the method of Wilson and Devinney Differential Correction (WD). The radial velocities have been measured using the Mg II h lines. The spectroscopic elements have been determined by the method of WD. The change of the Mg II resonance doublet has been investigated based on the eight representative spectra taken at well distributed orbital phases.

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Ionophore Activity of Frangufoline

  • Park, Man-Ki;Park, Jeong-Hill;Cho, Jung-Hwan;Park, Jun-Kyu;Han, Yong-Nam;Han, Byung-Hoon
    • Archives of Pharmacal Research
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    • 제14권2호
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    • pp.103-104
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    • 1991
  • The ionophore activity of frangufoline (1), a sedative cyclopeptide alkaloid isolated from Zizyphus jujuba, was investigated by UV and CD spectroscopic methods. Frangufoline (1) showed ion binding activity to calcium and magnesium ions.

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녹두의 성분연구 (Studies on the Components of the Seeds of Phaseolus radiatus)

  • 신순희;강삼식;권경숙
    • 약학회지
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    • 제34권4호
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    • pp.282-286
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    • 1990
  • An hydrocarbon alcohol and steroids were isolated from the hexane fraction of the extract from the seeds of Phaseolus radiatus L. And also a flavonoid was identified from the ethyl acetate and butanol fraction. The structure of the obtained compound were elucidated by spectroscopic methods (UV, IR, mass and NMR) and their physicochemical properties. As the results, triacontanol, stigmasterol, ${\beta}-sitosterol$ and vitexin were identified.

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Antioxidant Polyphenol Glycosides from the Plant Draba nemorosa

  • Rahman, Md. Aziz Abdur;Moon, Surk-Sik
    • Bulletin of the Korean Chemical Society
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    • 제28권5호
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    • pp.827-831
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    • 2007
  • Bioassay-directed fractionation of Draba nemorosa led to the isolation of two new phenolic glycosides, 1-O- (sinapoyl)-glucitol (2) and 1,3-disinapoylgentiobiose (5) along with five known phenolic glycosides (1, 3, 4, 6, and 7). Their structures were characterized based on spectroscopic methods (2D NMR, HRTOFMS, IR, and UV). The isolated compounds showed antioxidant activities (IC50) in the range of 14-98 mM which were estimated by DPPH radical-scavenging assay.