• Current Optics and Photonics
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• 제2권3호
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• pp.286-290
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• 2018

We investigated the dependence of the retardation dispersion on the polarization direction of ultraviolet (UV) light during the photopolymerization of self-organized smectic reactive mesogen (RM) molecules. RM retarder film that was photopolymerized with UV light linearly polarized parallel to the layer plane showed negative dispersion (ND) of retardation for a wide range of UV polymerization temperatures. On the other hand, film that was photopolymerized with unpolarized UV light showed negative dispersion in a narrow range of UV polymerization temperatures. With a certain UV polymerization temperature, the dispersion of retardation was converted from positive to negative, depending on the UV polarization.

• Macromolecular Research
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• 제11권3호
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• pp.146-151
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• 2003

The dependence of electrical conductivity on concentrations of diallyldimethylammonium chloride (DADMAC) monomer, linear poly(DADMAC) and their mixture monomer/poly(DADMAC) in dilute aqueous solution exhibits a linear relationship. It was possible to calculate conversion of DADMAC polymerization by measuring its electric conductivity. Although the electrical conductivity of the poly(DADMAC) solution decreased with increasing its molecular weight, in the process of UV or ionizing radiation polymerization the molecular weight of the polymers could be kept constant in the case of fixed temperature, UV-luminous intensity or dose rate. Based on the method mentioned above, the kinetics of UV induced polymerization of DADMAC in aqueous solution was studied; the overall activation energy of polymerization of DADMAC in the water phase was calculated to be 18.8 kJ mol$^{-1}$ . ${\gamma}$-Radiation-induced polymerization of DADMAC in aqueous solution as a function of absorbed dose was studied as well. The conversion of DADMAC increased quickly with dose before 30 kGy and then increased slowly. The experimental data of both UV- and ${\gamma}$-induced polymerization were verified to be reliable by inverted ultracentrifugation method.

• 펄프종이기술
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• 제46권2호
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• pp.46-56
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• 2014

The aim of this reviews is to introduce the information concerning design of the UV-curable jet ink composition in order to provide a good adhesive property on non-porous surface. In order to clarify the viscosity dependence of flying speed for the UV curable jet ink, rheological analysis and observation of the flying state of the ink were carried out. The relationship between ink formulas and adhesive property on non-porous surface was investigated. It was examined the adhesive property of radical polymerization type UV curable jet ink included hydrogen abstraction type photo-initiator, it was expected that the strong adhesive strength can be obtained between the ink and non-porous surface in this study. UV curable jet ink with a slight amount of water was prepared. Optimum ratio of the cationic polymerization type UV curable jet ink shows an adequate adhesive strength towards two kinds of non-porous surface such as glass, poly(vinyl chloride) when tests were conducted on the ink jet-printing test machine.

• Macromolecular Research
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• 제11권6호
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• pp.495-500
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• 2003

UV-induced graft polymerization of glycidyl methacrylate (GMA) to a polypropylene (PP) membrane was carried out in the vapor phase with benzophenone (BP) as a photoinitiator. Attenuated total reflection Fourier transform infrared spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM) were utilized to characterize the copolymer. The degree of grafting increased with increasing reaction time, increased UV irradiation source intensity, and increased immersion concentration of the BP solution. The optimum synthetic condition for the PP-g-GMA membrane was obtained with a reaction time of 2 hrs, a UV irradiation source intensity of 450 W, and an immersion concentration of the BP solution of 0.5 mol/L. The pure water flux decreased upon increasing the degree of grafting and increasing the amount of diethylamino functional group introduced. The analysis of AFM and SEM images shows that the graft chains and diethylamino groups of PP-g-GMA grew on the PP membrane surface, resulting in a change in surface morphology.

• 한국인쇄학회지
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• 제18권1호
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• pp.13-24
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• 2000

UV-curable resin has the properties of quick-drying, high productivity at low temperature, energy, space saving, solventless, non-polluting and low-stinking, and thus, UV-curing system has been widely used in the fields of printing inks, adhesives, paints and coating agents. This study has been executed to develop a new functionnal material by the polymerization induced phase separation. The results obtained were as follows. As for the curing properties of the monomer/prepolymer/alkyd resin blends, it was found out that there was a peak by the polymerization induced phase separation when measuring the changes of viscosity and elasticity. It was also found out that such polymerization phase separation occurred in case that the alkyd resin contents were 20wt% and 30wt% and not found at the contents of 40wt%. Therefore, it would be desirable to maintain the contents of alkyd resin at less than 30wt% in order to use the polymerization induced phase separation.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2005년도 ICCAS
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• pp.1158-1162
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• 2005

Drug delivery systems have been developed to reduce the side toxicity of drugs by localizing them in the site of action. But it depends on the circulation of the blood and it doesn't have the function of locomotive mechanism of itself for searching for the region of disease. However, this problem could be solved by nanobot which have the locomotive function. So, we mimic the movement of cell that can move in a human body. In this paper, to polymerize the encapsulated actin within the liposome, electroporation technique is employed. In order to optimize polymerization and depolymerization of the liposome, we compare the time of polymerization and depolymerization by concentration of crown ether. we synthesis the liposome which contain azobenzene Linked crown Ether conjugated Actin protein. Azobenze linked crown ether holds the K+ ion by exposure of UV light and this disturbs the actin polymerization. In result, UV light could control the liposome growth. Finally, we could develop the liposome robot and control the growth and degeneration of the liposome by external stimuli such s UV light. The merit of the controlling by UV light doesn't need to inject proteins which induce polymerization and depolymerization of actin protein.

• 분석과학
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• 제15권4호
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• pp.341-345
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• 2002

UV 광 중합 반응의 진행정도를 near-IR 분광학적 방법을 사용하여 관찰하였다. 광중합반응의 반응체는 4차 암모늄염을 포함하고 있는 아크릴 모노머를 사용하였으며 광 개시제로는 Darocur 1174를 사용하였다. 반응의 진척도는 광중합 반응의 정도를 나타내 주는 척도가 되는 중합 반응체인 아크릴 모노머의 -C=$CH_2$ 기와 관련된 흡수 띠인 1615 nm(6190 $cm^{-1}$)와 2105 nm(4750 $cm^{-1}$)에서 관찰된 띠 세기의 전환율로부터 구하였다. Near-IR 분광법이 광 중합 반응의 진행정도를 관찰하는데 효과적인 방법이 될 수 있음을 알 수 있었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.623-624
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• 2009

Here we report a photo polymerization-induced hybrid alignment of a nematic liquid crystal cell which can be applied for a roll to roll fabrication process. Predominant polymerization in the vicinity of UV incident front induced a diffusion of monomers toward front slide and anisotropic polymer network was formed parallel to the polarization direction of the UV light. This induced planar alignment of liquid crystals at the front slide. Simultaneously, homeotropic alignment was induced at the bottom slide as the polymers are phase-separated from a bottom slide.

• E2M - 전기 전자와 첨단 소재
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• 제10권6호
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• pp.576-580
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• 1997

In this paper, the viewing angle characteristics of amorphous (a) - twisted nematic (TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surface with UV (ultraviolet) light irradiation were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. We observed that the domain size of a-TN-LCD decreases with increasing the photo polymerization by increasing UV light irradiation time on PVC films. Also, we observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide (PI) surface.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.651-652
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• 1993