• Title/Summary/Keyword: UV-Vis 법

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Isolation and Characterization of Aquatic Humic Acid and Fulvic Acid (수질계의 Humic Acid와 Fulvic Acid의 분리 및 특성)

  • Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.36-42
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    • 2002
  • The dissolved organic carbon extracted from groundwater is separated into humic acid and fulvic acid. They are characterized for their chemical composition, spectroscopic characteristics using UV/VIS, IR and solid state $^{13}C-NMR$ spectroscopy, proton exchange capacity and molecular size distribution. The results are comparable with the literature data. The study explains that the aquatic humic and fulvic acid in this experiment are site-specipic and polydisperse natural organic matter with considerable proton exchange capacity.

A Study of The Photosensitive Characteristic and Fabrication of Polyimide Thin Film by Dry Processing (건식법을 이용한 폴리이미드 박막의 제조 및 광특성)

  • Lee, Boong-Joo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.139-141
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    • 2007
  • Thin films of polyimide (Pl) were fabricated by a vapor deposition polymerization method (VDPM) and studied for the photosensitive characteristic. Polyamic acid (PAA) thin films fabricated by vapor deposition polymerization (VDP) from 6FDA and 4-4' DDE were converted to PI thin films by thermal curing. From AFM and Ellipsometer experimental, the films thickness was decreased and the reflectance was increased as the curing temperature was increased. Those results implies that thin film is uniform. From UV-Vis spectra, PI thin films showed high absorbance in 225 $\sim$ 260 [nm] region.

The research of one-step emulsion polymerization of aniline and its conducting blends with polystyrene (에멀젼중합법으로 제조된 폴리아닐린과 폴리스타이렌과의 전도성블렌드에 대한 연구)

  • 이보현;김태영;김종은;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.259-262
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    • 2001
  • Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivities of obtained PANI-DBSA complexes increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra and TGA thermograms of PANI-DBSA complexes also supported these results. PANI-DBSA/PS blends were prepared by mixing PANI-DBSA complexes with PS in toluene. These blends exhibited electrical conductivity of 0.371S/cm at a low PANI-DBSA content (7 wt.%)

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Electrical and Optical Propeties of CdS Films Prepared by Vacuum Evaporation (진공증착법으로 제조한 CdS 박막의 전기적 및 광학적 성징)

  • 김동섭;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.12-16
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    • 1991
  • Cadmium sulphide films with thickness of 0.6∼1.2$\mu\textrm{m}$ were deposited onto corning 7059 glass substrate under a vacuum of 5${\times}$10$\^$-6/ Torr. Source and substrate temperature ranges used were 800∼1100$^{\circ}C$ and 100∼200$^{\circ}C$, respectively. The microstructures and semiconducting properties of the films were studied using X-ray diffraction, UV-VIS-IR spectrophotometer and Hall measurement unit. Electrical resistivity and optical transmission of the CdS films decrease with an increase in source temperature while they increase with an increase in substrate temperature. The resistivity of the film evaporated at 1100$^{\circ}C$ varied from 7${\times}$10$^3$ohm-cm at the substrate temperature of 100$^{\circ}C$ to 2${\times}$10$\_$6/ohm-cm at 190$^{\circ}C$. All the films had hexagonal structure and strong texture with c-axis of grains normal to the substrate glass.

Electrical and optical properties of ZnO:Ga, Al thin films prepared by sol-gel method (Sol-gel법에 의한 ZnO:Ga, Al 박막의 투명 전도막 제작과 전기 광학적 특성)

  • Nam, Gil-Mo;Kwon, Myoung-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.305-306
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    • 2006
  • Ga-doped and Al-doped ZnO thin films were fabricated via a sol-gel technique and electrical and optical properties of the films were investigated. Film deposition was performed by spin coating at 4000 rpm for 30 s on $SiO_2$ glass substrate FE-SEM was used to obtain the surface morphology images and the film thickness Four-point probe and UV-VIS spectrophotometer were used to measure the sheet resistance and the optical transparency, respectively.

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Preparation of AZO/Ag/AZO multilayer for transparent electrode by using facing targets sputtering method (대향 타겟 스퍼터링 법을 이용한 투명전극용 AZO/Ag/AZO 다층 박막의 제작)

  • Cho, Bum-Jin;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.290-291
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    • 2006
  • We prepared the multilayer with Al doped ZnO (AZO)/Ag/AZO structure. The multilayer were deposited with various thickness of Ag layer on glass substrates at room temperature by using facing targets sputtering (FTS) method. To investigate the electrical, optical and structural properties, we used Hall Effect measurement system, four-point probes. UV-VIS spectrometer with a wavelength of 300 - 100nm, X-ray Diffractometer(XRD) and scanning electron microscopy (SEM). We obtained multilayer thin film with the low resistivity $5,9{\times}10^{-5}{\Omega}cm$ and the average transmittance of 86% m the visible range (400 - 800nm).

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Electrical and optical properties of ZnO : Al thin films deposited by Facing Targets Sputtering (대향타겟스퍼터법으로 증착된 ZnO : Al 박막의 전기적 광학적 특성)

  • Yang, J.S.;Seong, H.V.;Keum, M.J.;Park, Y.W.;Ka, C.H.;Kim, K.H.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1478-1480
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    • 2001
  • ZnO : Al transparent conductive thin films were prepared by facing targets sputtering system with a DC power supply which can deposit a high quality thin films and control deposition condition in all range of $O_2$ gas ratio using ZnO target containing 8 at% of Al. Sputtering was carried out at a substrate temperature of R T with a DC current of 0.6 A and $O_2$ flow rate of 0 $\sim$ 0.9. The characteristics of ZnO : Al thin films was investigated by $\alpha$-step, four point probe, X-ray diffraction and UV/VIS spectrometer.

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Preparation of Heat-resistance Waterborne Coating Containing Synthetic Hectorite Clay (합성헥토라이트 점토를 함유한 내열성 수성코팅제의 제조)

  • 이석기;이병교
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.122-127
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    • 2001
  • 수열법으로 합성한 헥토라이트 점토(SHC), 아크릴 라텍스 및 코팅첨가제들을 배합하여 성분이 다른 수성코팅제(WBC-0, WBC-1, WBC-2) 3종류를 제조하였다. 제조한 수성코팅제(WBC)의 pH, 용액점도 및 고형분을 조사하였고, 전단력에 따른 유동성을 레오메타로 측정하였다. 또한 WBC로부터 주조된 필름의 열안정성과 투명성을 각각 TGA와 UV-VIS 분광광도계로 조사하였다. SHC가 8 phr 포함된 WBC-2는 전단력에 따라 졸과 겔의 상전이 현상, 즉 요변성을 나타내었으며 이로 인해 저장안정성이 우수하였다. 주조한 WBC-1과 WBC-2 필름의 초기분해온도와 투명성은 시판 WBC(OP-55W)의 필름보다 각각 99.6~110.2$^{\circ}C$와 20.9~21.7%의 범위로 증가하였다. 결과적으로, SHC가 함유된 WBC는 수팽윤성 점토에 의해 내열성과 용액점도의 증대효과가 나타났다.

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Characterisecs of GAZO Films Deposited by DC Magnetron Co-Sputtering System (DC 마그네트론 동시방전 시스템을 이용하여 증착한 GAZO 박막의 특성 평가)

  • Jie, Luo;Park, Se-Hun;Song, Pung-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.187-187
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    • 2009
  • GAZO 박막의 증착은 $Ga_{2}O_{3}$의 첨가량 (6.65wt%) GZO 타겟과 $Al_{2}O_{3}$의 첨가량 (2.0wt%) AZO 타겟이 각각 장착된 2개의 캐소드를 이용한 DC 마그네트론 동시방전법에 의하여 non-alkali glass 기판위에 다양한 조건(파워, 기판온도, $H_2$ 참가량)에서 행하였다. GAZO박막의 전기적 특성은 Hall Effect measurements를 사용하여 측정 하였으며, 구조적 특성, 박막의 화학적 조성 및 광학적 특성은 XRD(X-ray diffraction), FESEM(Filed Emission Scanning Electron Microscope) 및 UV-Vis Spectrophotometer를 사용하여 평가 하였다. Al을 도입함으로써 캐리어밀도의 증가에 의해 GZO 박막의 특성은 개선됨을 확인 할 수 있었다.

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The effect of ammonium hydroxide with different concentration on fabrication of CdS thin film by Chemical Bath Deposition (CBD) (용액성장법 (CBD)으로 CdS 박막 성장 시 수산화 암모늄 농도 조절이 미치는 영향)

  • Chun, Seung-Ju;Lee, Hyun-Ju;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.365-365
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    • 2009
  • CBD 증착 방법은 저비용으로 양질의 CdS 박막을 얻을 수 있는 증착 밥법으로, 고효율의 CdTe/CdS 태양전지를 얻기에도 적당하다. CdS 박막의 증착 과정에서 수산화 암모늄 (ammonium hydroxide) 은 박막의 특성을 결정하는 주요한 요소 인자 이다. ITO가 증착된 유리기판위에 CdS 박막 증착 과정에서 동일한 조건에서 산화 암모늄 (ammonium hydroxide) 의 농도만을 조절하여서, XRD, Raman spectrometer, UV-Vis, SEM 분석 장치를 이용하여 구조 및 광학 특성의 변화를 살펴보았다.

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