• Title/Summary/Keyword: UV stability

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Evaluation of dimension stability according to UV-C ultrasonic cleaning of full arch artificial teeth made with DLP printer for photopolymerization (광중합용 DLP 프린터로 제작한 전악 인공치아의 UV-C 초음파 세척에 따른 체적 안정성 평가)

  • Kim, Dong-Yeon;Lee, Gwang-Young
    • Journal of Technologic Dentistry
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    • v.43 no.3
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    • pp.84-92
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    • 2021
  • Purpose: The purpose of this study was to compare the dimension safety evaluation between a general ultrasonic cleaner and an ultrasonic cleaner equipped with UV-C (ultraviolet-C). Methods: An edentulous model was prepared. A denture base and an occlusal rim were fabricated, and scanning was performed. After scanning, a denture base and full arch artificial teeth were designed. The full arch artificial teeth were printed using a three-dimensional printer (n=10). The residual resin was washed with alcohol and then scanned (reference data). The printed specimens were classified and cleaned using a general ultrasonic cleaner (GU group) and an ultrasonic cleaner equipped with UV-C (UC group). After each washing, a rescan was performed (scan data). Reference data and scan data were superimposed using overlapping software. Data were statistically analyzed using the Mann-Whitney test (α=0.05). Results: In the deviation values of full arch artificial teeth, the GU group showed a high deviation of 18.02 ㎛ and the UC group showed a low deviation of 15.02 ㎛. The two groups demonstrated a statistically significant difference (p<0.05). Conclusion: Full arch artificial teeth prepared using photopolymerized resin were deformed according to the temperature of water generated in the ultrasonic cleaner. It is judged that there is no deformation according to the UV-C ultrasonic cleaner.

Stability of Photochromism in New Bifunctional Copolymers Containing Spiropyran and Chalcone Moiety in the Side Chain

  • Choi, Dong-Hoon;Ban, Si-Young;Kim, Jae-Hong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.441-445
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    • 2003
  • We synthesized three copolymers bearing photochromic spiropyran dye and chalcone moiety in the side chain for studying the dynamic properties of their photochromism. They contain methacrylate-spiropyran (MAspiropyran) and methacrylate-chalcone (MA-chalcone) with the different concentration. The photosensitivity of the newly synthesized copolymers was investigated by using UV-Vis absorption spectroscopy. We observed photodimerization and photochromic behavior under UV irradiation at the same time. The effect of photocrosslink on the rate and stability of photochromism in three copolymers was considered in this study. This study might be helpful to design photochromic materials for irreversible optical memory by virtue of photocrosslinking reaction.

Degumming Characteristics and Color Stability of GoldenSilk Cocoon

  • Kweon, Hae-Yong;Lee, Kwang-Gill;Park, Kwang-Young;Kang, Seok-Woo;Seok, Young-Seek
    • International Journal of Industrial Entomology and Biomaterials
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    • v.24 no.1
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    • pp.1-5
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    • 2012
  • A newly developed silkworm variety, GoldenSilk makes bright yellow cocoon. In this article, the basic characteristics of GoldenSilk cocoon were examined through color analysis, degumming characteristics and UV spectrophotometer. The colorant of GoldenSilk cocoon was not distributed evenly throughout the cocoon layer but existed in the outer layer of the cocoon. The colorant has not good resistance against sunlight. The degumming loss percentage of GoldenSilk cocoon was 29.2%, which is relatively higher than that of the authorized one. UV spectrophotometer showed specific absorption band around 400 to 500 nm, which is the specific yellow colorant of the GoldenSilk cocoon extracted to the degumming solution during the degumming process.

Stability to the spreading solvent of(3-Alkyl benzimidazolium)-TCNQ(1:1) Complex for Langmuir-Blodgett Technigue (Langmuir-Blodgett법을 위한(3-Alkyl benzimidazolium)-TCNQ(1:1)착물의 분산용매 중에서의 안정성)

  • Sohn, Byoung-Chung;Hwang, Kyo-Hyun;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.39-44
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    • 1994
  • A Stability to the Spreading solvents, Which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex was investigated by UV-visible Spectrometer and was confirmed stabilized on acetonitrile, acetonitrilbenzene(1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett (LB) Films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex. For the identification of deposition of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Partial Purification and Stability of a Water-soluble Yellow Pigment from Bacillus sp. PY123. (Bacillus sp. PY123 균주가 생성하는 수용성 황색수소의 부분 정제 및 그 안정성)

  • 김지연;김광현;김병우;이광배
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.35-40
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    • 1999
  • For application of a yellow pigment as food additives, stability of a water-soluble yellow pigment from Bacillus sp. PY123 was investigated. The yellow pigment from Bacillus sp. PY123 was purified with pH treatment, activated carbon and silica gel column chromatography. The partial purified yellow pigment appeared only one spot on silica gel TLC after 12 evaporation and under irradiation of UV 253nm at dark room. Rf value of the pigment was measured at 0.04 and 0.12 with development of a solvent mixture (Butanol : Acetic acid : water = 4 :1:5) and a solvent mixture (Isopropanol : Ammonia : Water = 9 :1: 2), respectively, The partial purified pigment appeared a white fluorescence under UV365nm irradiation. The partial purified yellow pigment had a main peak and a minor peak on HPLC using 20mM phosphate buffer(pH 7.0) at 1ml/min flow rate. The partial purified pigment was stable at heat treatment, acidic pH, oxide-reductants and surfactants.

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Stability to the Spreading Solvent of (3-Alkyl Benzumidazolium)-TCNQ(l:2) Complex for Langmuir-Blodgett Technique (Langmuir-Blodgett법을 위한(3-Alkyl benzimidazolium)-TCNQ(1:2)착물의 분산용매 중에서의 안정성)

  • Jeoung, Soon-Wook;Hwang, Kyo-Hyun;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.99-103
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    • 1994
  • A stability to the spreading solvent, which is acetonitrile, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazdium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, acetonitrile-benzene (1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett(LB) films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex. For the identification of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Stability to the Spreading Solvent of (N-docosyl Quinolinium)-TCNQ(1:2) Complex by Langmuir-Blodgett Technique (Langmuir-Blodgett법을 위한(N-docosyl quinolinium)-TCNQ(1:2)착물의 분산용매 중에서의 안전성)

  • Jeoung, Soon-Wook;Lee, Yoong-Kook;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.93-97
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    • 1994
  • A Stability to spreading solvent, which is acetonitrile, dichloromethane, benzene, chloroform, and acetonitrile-benzene (1:1, v/v) of (N-docosyl quinolinium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, dichloromethane, and acetonitrile-benzene(1:1, v/v) for 7 hours. Using buffer solution($ph{\doteqdot}6.0$) as subphase for Langmuir-Blodgett(LB) film, it was achieved successively to fabricate the Y type LB films of (N-docosyl quinolinium)-TCNQ(1:2) complex. For the identification of deposition of (N-docosyl quinolinium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Study of the Photo-alignment Technique through the Surface Modification

  • Song, Dong-Mee;Shin, Dong-Myung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.197-198
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    • 2000
  • A surface-assisted photo-control of the liquid crystal (LC) alignment has been achieved by modifying the topmost surface of the polyimide film with photo-reactive molecules. Recently, photo-alignment technique using a thin film of poly(vinyl cinnamates) have been reported. However their commercial potentiality is limited by their low thermal stability. To enhance thermal stability, we synthesized the chalcone derivatives as the photo-reactive molecules and introduced the materials on the surface-modified polyimide film.. We identified that the photo-chemical reaction of the chalcone derivatives occur in few minutes with irradiation of UV light. The photo-alignment characteristics of the modified polyimide films treated by polarized UV light and their LC cells are investigated as a function of exposure dose.

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Synthesis of Hexyltriphenylphosphonium-TCNQ Complex and Stability in Spreading Solvent (Hexyltriphenylphonium-TCNQ 착물(錯物)의 합성(合成)과 분산용매 중에서의 안정성)

  • Han, Jong-Soo;Hwang, Kyo-Hyeon;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.115-118
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    • 1995
  • Hexyltriphenylphosphonium-TCNQ(HTPP-TCNQ) complex for preparing organic thin film by Langmuir-Blodgett technique was synthesized from LiTCNQ and Hexyltriphenylphosphonium bromide. The structure of the new complex was confirmed by $^{1}H$ NMR, $^{31}P$ NMR, IR, UV spectroscopies, TGA and elemental analysis. A stability to spreading solvent, which is acetonitrile, ethylacetate, ethanol and acetonitrile-ethylacetate(1:1 v/v), of HTPP-TCNQ complex was investigated by UV-visible spectrophotometer. The complex was stabilized in acetonitrile, ethylacetate, aceton, acetonitrile-ethylacetate (1:1 v/v) for 6 h.

Preparation and Characterization of Ophthalmic Hydrophilic Silicone Lens Containing Zinc Oxide and Iron Oxide Nanoparticles

  • Shin, Su-Mi;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.31 no.8
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    • pp.427-432
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    • 2021
  • This study uses silicone monomer, DMA, crosslinking agent EGDMA, and initiator AIBN as a basic combination to prepare hydrogel lenses using fluorine-based perfluoro polyether and iron oxide and zinc oxide nanoparticles as additives. After manufacturing the lens using iron oxide nanoparticles and zinc oxide nanoparticles, the optical, physical properties, and polymerization stability are evaluated to investigate the possibility of application as a functional hydrogel lens material. As a result of this experiment, it is found that the addition of the wetting material containing fluorine changes the surface energy of the produced hydrogel lens, thereby improving the wettability. Also, the addition of iron oxide and zinc oxide nanoparticles satisfies the basic hydrogel ophthalmic lens properties and slightly increases the UV blocking performance; it also increases the tensile strength by improving the durability of the hydrogel lens. The polymerization stability of the nanoparticles evaluated through the eluate test is found to be excellent. Therefore, it is judged that these materials can be used in various conditions as high functional hydrogel lens material.