• 제목/요약/키워드: UV polarization

검색결과 71건 처리시간 0.025초

Schiff Bases as Anticorrosive Additives for Mild Steel Corrosion in Acid Media

  • Abirami, M.;Sasikala, S.;Chitra, S.;Parameswari, K.;Selvaraj, A.
    • Corrosion Science and Technology
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    • 제8권1호
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    • pp.1-10
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    • 2009
  • The influence of Schiff bases on the corrosion inhibition of mild steel in 1 M $H_2SO_4$ have been investigated by weight loss, gasometry, impedance and polarization techniques. The results obtained reveal that these compounds act as good inhibitors. The inhibition efficiency of Schiff bases increased with concentration and synergistically increased on addition of chromate, sulphate and halide ions. Potentiodynamic polarization measurements clearly reveal that the investigated inhibitors are of mixed type but they are more cathodic in nature. The adsorption of these compounds on mild steel surface for both the acids were found to obey Langmuir adsorption isotherm. The surface morphology was studied by SEM and UV reflectance spectra.

Detection of AGN outflows in micro-arcsec scales

  • Oh, Junghwan;Trippe, Sascha;Krichbaum, Thomas;Sohn, Bong Won;Bremer, Michael
    • 천문학회보
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    • 제38권2호
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    • pp.43.1-43.1
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    • 2013
  • We report the preliminary results of our GMVA(Global mm VLBI Array) observation at the frequency of 86 GHz. Observation were made in the dual polarization mode (LCP and RCP), to produce the polarimetric maps with the maximum angular resolution which the array is capable of. We aim to link the source-integrated AGN polarization properties with the polarized spatial source structure, by mapping the polarized "fine structure" of the target AGN. We selected 2 targets, 0954+658 and 0716+714, which (1) have been observed multiple times by the PdBI polarimetric monitoring program; (2) have sufficient integrated fluxes ($S_{90GHz}$ > 1 Jy) ; (3) are close enough to resolve the source structure < 1 pc with given angular resolution ; and (4) are located at high northern declination for good UV coverages. As preliminary results, we present LL and RR polarized images of each target with the maximum angular resolution of ${\sim}60{\mu}as$. Extended structures, probably the jet outflows, are discovered in both sources.

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Mechanisms of Photoalignment of Liquid Crystals on Polyvinyl-fluoro-cinnamate

  • Buluy, O.;Gerus, I.;Nobili, M.;Reznikov, Yu.;Kim, Dong-Soo;Ha, Ki-Ryong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.806-808
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    • 2006
  • In order to understand the origin of liquid crystal orientation on a surface of photoaligning polymer polyvinyl-fluoro-cinnamate (PVCN-F), we used FTIR, AFM, UV/Vis and XPS techniques as well as we studied the rejuvenation of the photoalignment after repeated UV exposure with mutually perpendicular polarization. We found that both photodimerization of cinnamoil moieties and their trans-cis isomerisation contribute to the light-induced anchoring on PVCN-F surface, and trans-cis isomerisation is responsible for the rejuvenation of the photoalignment.

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Langmuir-Blodhett법을 이용한 유기초박막의 제적과 전기적 특성 (Fabrication of the Organic Ultra thin Film Using the Langmuir-Blodgett Technique and Its Electrical Properties)

  • 강도열;손병청;권영수;최명규;유덕선
    • 대한전기학회논문지
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    • 제40권9호
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    • pp.913-919
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    • 1991
  • For an elementary study of the molecular electronic devices, in this study, N-alkylpyridinium(TCNQ) (1:1) and (1:2) complexed were synthesized. These complexes were verified by the UV, IR and the elemental analysis. Deposition of the LB films were verified by the reciprocal capacitance, UV absorbance and decresement area of Langmuir fims as functions of number of layers. The internal voltage of LB membrane devices fabricated with Y-type resides in 100-300mV. Finally, it seemed that self-polarization of LB membrance generates internal voltage.

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Photo polymerization-induced Hybrid Alignment of Nematic Liquid Crystal for Roll to Roll Fabrication

  • Kim, Kyoung-Sun;Kwon, Soon-Bum;Lee, Ji-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.623-624
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    • 2009
  • Here we report a photo polymerization-induced hybrid alignment of a nematic liquid crystal cell which can be applied for a roll to roll fabrication process. Predominant polymerization in the vicinity of UV incident front induced a diffusion of monomers toward front slide and anisotropic polymer network was formed parallel to the polarization direction of the UV light. This induced planar alignment of liquid crystals at the front slide. Simultaneously, homeotropic alignment was induced at the bottom slide as the polymers are phase-separated from a bottom slide.

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Effects of lanthanum doping on ferroelectric properties of direct-patternable $Bi_{4-x}La_xTi_3O_{12}$ films prepared by photochemical metal-organic deposition

  • Park, Hyeong-Ho;Kim, Hyun-Cheol;Park, Hyung-Ho;Kim, Tae-Song
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.287-287
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    • 2007
  • The ferroelectric and electric properties of UV-irradiated bismuth lanthanum titanate (BLT) films prepared using photosensitive starting precursors were characterized. The effects of lanthanum doping on ferroelectric and electric properties were investigated by polarization-electric field hysteresis loops and leakage current-voltage measurements. X-ray diffractometer and ellipsometry were served to provide the information about the crystalline structure and thickness of the films after annealing. The images of the surface microstructure and direct-patterned BLT films were observed by using scanning electron microscopy. The effects of lanthanum doping on the electric properties of direct-pattern able BLT films and their direct-patterning were studied.

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Complex Detection Between Transcription Regulator and Promoter DNA by UV Spectroscopic Method

  • Lee, Kyungmin;Gang, Jongback
    • 통합자연과학논문집
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    • 제5권3호
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    • pp.163-167
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    • 2012
  • UV spectrophotometer was used to detect protein-DNA complex from DNA melting profile under constant temperature increase. Melting temperature (Tm) was $43^{\circ}C$ in copA duplex DNA alone. In the presence of Proteus mirabilis transcription regulator protein (PMTR) protein at 0.2 and 0.4 ${\mu}M$, Tm's were $45{\pm}0.5$ and $47.6{\pm}0.6^{\circ}C$, respectively. According to fluorescence polarization and gel shift assay. PMTR:copA complex was detected by the retarded migration on gel and the dissociation constant ($K_d$) was $(9.2{\pm}2.8){\times}10^{-9}M$.

$C_{22}$-quinolinium(TCNQ) langmuir-blodgett 박막의 열처리 온도에 따른 광학적 및 유전특성 (Optical and electrical properties of $C_{22}$-quinolinium(TCNQ) langmuir-glodgett films depending on the annealing temperatures)

  • 홍언식;유덕선;김태완
    • E2M - 전기 전자와 첨단 소재
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    • 제8권4호
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    • pp.458-463
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    • 1995
  • The optical and electrical properties of $C_{22}$-Quinolinium(TCNQ) Langmuir-Blodgett films have been studied depending on the annealing temperatures. The optimal properties were investigated using UV/visible(300-800[nm]) absorption spectra and FTIR(Fourier-transformed- infrared) absorption measurements. The electrical properties were investigated in a frequency range of 10[Hz]-13[MHz]. The UV/visible absorption spectra at room temperature show that there are four characteristic peaks at 320, 380, 494 and 678[nm]. These absorption peaks decrease very rapidly above the annealing temperature of 180[.deg. C], which is due to a structural change of TCNQ. The FTIR absorption measurements strongly support the result of the UV/visible absorption spectra, because the absorption peak of TCNQ- at 2181[$cm^{-1}$ /] also decreases above 140[.deg. C]. The frequency-dependent dielectric constant shows that there is a dielectric dispersion near 1[MHz] which is due to an orientational polarization of the molecules inside the film. The overall frequency-dependent dielectric constant is higher near 80[.deg. C]. It may be due to a softness of the alkyl chains.s.

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광감성 폴리비닐플루오로신나메이트의 액정 배향에 관한 연구 (Studies of Liquid Crystal Alignment on the Photosensitive Polyvinylfluorocinnamate)

  • 김동수;안원술;하기룡
    • 폴리머
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    • 제31권5호
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    • pp.393-398
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    • 2007
  • 편광 푸리에 변환 적외선 분광법(polarized fourier transform infrared spectroscopy)과 자외선 분광법(ultraviolet spectroscopy)을 이용하여 액정 디스플레이 (liquid crystal display, LCD)의 배향막으로 사용 가능한 Polyvulylfluoroclnnamate(PVCN-F) 필름의 편광 자외선(Polarized UV, PUV) 조사 및 러빙에 따른 액정의 배향 메커니즘에 관한 연구를 수행하였다. UV의 조사시간이 증가함에 따라 PVCN-F cinnamoyl group의 C=C기들의 cycloaddition 반응으로 인하여 $1638cm^{-1}$에서 나타나는 vinylene -C=C- FT-IR 흡수 피크들의 면적이 감소하고, $1712cm^{-1}$에서 나타나는 conjugated C=O 신축진동에 의한 피크가 nonconjugated C=O 신축진동 피크인 $1734cm^{-1}$로 이동함을 확인하였다. 또한 PUV가 조사된 PVCN-F 배향막을 사용하여 제조된 액정 셀에서는 조사된 PUV의 극성 방향과 수직으로 액정이 배향함을 확인하였고, 러빙 방법으로 제조된 PVCN-F 배향막을 사용한 액정 셀에서는 액정이 러빙 방향과 수평으로 배향됨을 dichroic dye(이색성 염료)의 첨가 없이 편광 FT-IR 스팩트럼을 사용하여 확인하였다.

Sol-gel 법으로 제조된 강유전체 Sr0.9Bi2.1Ta1.8Nb0.2O9 박막의 저온결정화 공정 (Low Temperature Sintering Process of Sol-gel Derived Ferroelectric Sr0.9Bi2.1Ta1.8Nb0.2O9 Thin films)

  • 김영준;김병호
    • 한국세라믹학회지
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    • 제40권3호
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    • pp.279-285
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    • 2003
  • Sol-gel 법으로 200 nm 정도의 두께를 가진 강유전성 S $r_{0.9}$B $i_{2.1}$T $a_{1.8}$ N $b_{0.2}$ 박막을 Pt/Ti $O_2$/ $SiO_2$/Si 기판 위에 증착하였다. 본 실험에서는 Sr(O $C_2$ $H_{5}$)$_2$, Bi(TMHD)$_3$, Ta(O $C_2$ $H_{5}$)$_{5}$ 그리고, Nb(O $C_2$ $H_{5}$)$_{5}$를 출발 물질로 사용하였으며 2-methoxyethanol을 용매로 사용하였다. UV 노광과 급속열처리가 SBTN 박막의 구조와 전기적 특성에 어떤 영향을 주는 가를 연구하였다. UV 노광과 급속열처리를 한 후에 $650^{\circ}C$ 열처리한 SBTN 박막의 3V와 5V 인가 전압하에서의 잔류분극 값은 각각 8.49와 11.94 $\mu$C/$ extrm{cm}^2$이었다.