• 한국응용과학기술학회지
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• 제26권2호
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• pp.171-178
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• 2009

A comparative analysis of the hindered amine light stabilizers (HALS) and UV abosrber (UVA) and their respective photostabilizing effect on wood plastic composites (WPCs) are reported in this study. The influence of accelerated weathering on the mechanical properties of the composites and the microscopic morphology of a degraded layer on the cross section and the surface were studied. UV absorbers were more efficient at preventing composite lightening than was UV stabilizer. The amount of whitening decreased with the increase of photostabilizers. With the addition of a UV absorber (Tinuvin360), the tensile modulus and strength of the composites increased slightly. However, the addition of a light stabilizer (Tinuvin770) and a UV absorber decreased the tensile modulus and strength of the composites. After 250 and 500 hr exposure, tensile modulus and strength of the un stabilized and stabilized composites decreased. The tensile strength of UV absorber (Chimassorb81)-stabilized composites was significantly greater than that of control and light stabilizer (Tinuvin770)- and UV absorber (Tinuvin360)-stabilized composites. UV absorber-stabilized samples showed less whitening and photodegradation than control and light stabilizer-stabilized samples.

• Journal of the Korean Wood Science and Technology
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• 제24권4호
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• pp.47-55
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• 1996

UV transmission spectra of water-soluble acrylic resin films containing hydroxybenzophenolic, hydroxyphenylbenzotriazolic UV absorber and HALS(hindered amine light stabilizer) were investigated by exposure time(before exposure weathered for 160 and 320hours) in QUV Weather-Ometer. Also the YID(yellowness index difference), LID(lightness index difference) and CD(color difference) of dried water-soluble acrylic resin films and the coated woods of Larix leptolepis were analyzed by addition level of UV absorber(0, 1, 2 and 3%) and HALS(0, 0.5, 1 and 1.5%) and by exposure time in QUV Weather-Ometer. They showed no significant effects on UV transmission spectra of dried water-soluble acrylic resin films in the range of 300 to 400nm irrespective of exposure time. However, UV transmission decreased as increase of exposure time. UV transmission spectra were lower in dried water-soluble acrylic resin films containing hydroxybenzophenolic UV absorber and HALS than in these containing hydroxyphenylbenzotriazolic UV absorber and HALS in the range of 350 to 400nm. The least YID, LID and CD in the coated woods of Larix leptolepis appeared at the addition level of 3%, based on non-volatile content, in hydroxybenzophenolic and hydroxyphenylbenzotriazolic UV absorber, and of 1.5% in HALS to water-soluble acrylic resin.

• 대한치과보철학회지
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• 제37권3호
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• pp.343-357
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• 1999

The color change of maxillofacial silicone has been attributed to certain environmental factors such as exposure to the UV component of natural sunlight, wetting and drying of the elastomer and surface abrasion resulting from the application and removal of cosmetics. The purpose of this study was to evaluate the color change of maxillofacial silicone (Silastic MDX4-4210) according to type of pigment (cadmium yellow, titanium white, cosmetic red), and UV absorber application method after 200, 400, and 600 hours of 350nm UV light irradiation. The results were as follows. 1. According to type of pigments, after 200 hours cosmetic red showed significantly larger color change than cadmium yellow and titanium white, and after 400 and 600 hours color change significantly decreased in the order of cosmetic red, cadmium yellow, and titanium white (p<0.05). 2. In the cadmium yellow group, after 200 hours, the non-treatment group showed significantly larger color change, but after 400 and 600 hours, color change significantly decreased in the order of non-treatment, surface application and mixed group (p<0.05). 3. In the titanium white group, there was no significant color change difference between the three groups after 200 and 400 hours, but after 600 hours, the mixed group showed significantly smalt or color change than the non-treatment and surface application groups (p<0.05). 4. In the cosmetic red group, there was significant decrease in color change in the order of non-treatment, surface application and mixed group (p<0.05). From the results above, the effect of UV light absorber differed according to the type of pigment, but mixing UV light absorber with maxillofacial silicone is thought to give superior resistance against UV light irradiation in the long run.

• 한국산학기술학회논문지
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• 제7권6호
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• pp.1296-1301
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• 2006

눈은 자외선과 가시광선에 노출되어 있다. 눈은 자외선 노출에 해로우므로 모든 자외선으로부터 눈을 보호해야 한다. 본 연구에서는 자외선 차단을 위해 투명 플라스틱에 유-무기 하이브리드 재료와 자외선 흡수제의 배합에 의한 자외선 차단 코팅하였고, PMMA, CR 39 및 PC기재에 적용하여 자외선 차단 효과를 조사하였다. 자외선 흡수제의 양이 증가할수록 자외선의 투과도는 낮았다. PMMA의 경우 자외선 투과도를 현저히 감소시켰으며 CR 39에서도 자외선 차단 효과가 있는 것으로 나타났다. 한편, PC자체에서는 자외선 차단효과가 있는 것으로 평가되었다. CR 39 렌즈의 부착력, 내약품성, 내온수성은 우수하였고, 연필 경도의 경우 4H였으며 내마모성은 좋지 않았다.

• 한국의류학회지
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• 제25권5호
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• pp.925-932
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• 2001

The influence of ultraviolet(UV)-ray in sun light on human skin has been noted. Textiles can provide protection against harmful UV-radiation. Normally UV-absorbing finishes are used to get better protection. The purpose of this study is to evaluate the UV-cut properties of cotton fabrics treated with UV-absorber. 2,2-dihydroxy-4,4-dimethoxbenzophenone, as UV-absorber was applied to 100% cotton fabric. Reagents added in finishing solution were Triton X-100, polyethylene glycol 400, and $MgCl_2{\cdot}6H_2O$, and C.I. Direct Red 81. Both untreated and treated cotton fabrics were exposed to a xenon arc lamp for 20 and 80 hours. UV absorption spectra of finishing solutions and UV transmission spectra of fabrics were measured by the UV/VIS spectrophotometer. The results of this study can be summarized as follows. The results of this study can be summarized as follows. Absorption and the related transmission spectra were modified in a controlled way with UV-absorber. Absorption effect of UV-absorber was improved by adding Triton X-100, PEG 400, and $MgCl_2{\cdot}6H_2O$ in finishing solution. The UV absorption of finishing solution was in the following order: U/D/T/P/M>D/T/P/M> D/T> D/P, D>U/T/P/M>U/T>T/P/M>T. The UV transmittance of cotton fabrics was remarkably decreased by the application of UV-absorber and additives. The UV-cut properties were most improved by the application of U/D/T/P/M.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.33-33
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• 2011

삶의 질 향상에 따른 의류 및 산업소재의 발전이 가속화되고 있는 현재 상황에 Benzotriazol 또는 Benzophenone계열의 UV-absorber들은 수많은 종류들이 개발되고 사용되고 있는 실정이지만 UV-A와 UV-B 영역을 전반적으로 protecting하고 염색 후 내열성이 떨어지고 및 색상변이(일광견뢰도 저하)를 가져오는 한계가 있다. 이에 Bezotriazine 계열의 새로운 UV-absorber에 대한 필요성에 의하여 amide와 chloride화합물에 의해 oxazinone을 합성 할 수 있었고 이를 amidine 화합물과 축합하여 S-Triazine을 고 순도로 합성 할 수 있었다. 이 화합물을 섬유 염색 시 적용이 가능토록 formulation화하여 당사에서 생산 판매되는 자동차용삼원색에 적용하여 염색하였고 현재 한국 및 유럽의 자동차 maker의 일광견뢰도 실험 방법에 따라 test한 결과 우수한 일광견뢰도를 갖는 것을 확인 할 수 있었다.

• 한국산학기술학회논문지
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• 제21권12호
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• pp.10-15
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• 2020

파장 400 nm 이하의 자외선은 눈 건강에 매우 해롭다. 또한 고에너지 가시광도 망막 세포에 영향을 줄 수 있음이 최근에 밝혀졌다. 따라서 자외선 및 고에너지 가시광 차단 기능의 안경렌즈 개발이 시대적으로 요청되고 있다. 본 연구에서는 m-자일릴렌 디이소시아네이트 모노머와 2,3-bis((2-mercaptoethyl)thio)-1-propanethiol 모노머 및 벤트리아졸 UV 흡수제, 알킬인산에스터 이형제, 안료혼합물(CI solvent violet 13), 이염화부틸주석 촉매제 등의 혼합물을 인젝션 몰드 방법으로 열중합 공정을 적용하여, 굴절률 1.67의 고굴절률 폴리머 안경렌즈를 제조하였다. 제조된 폴리머 안경렌즈의 양면에 전자빔 진공증착 시스템으로 다층 반사방지 코팅을 하였다. 제조된 안경렌즈의 자외선 및 고에너지 가시광 차단 기능을 UV-visible spectrophotometer로 분석하였다. 그 결과 UV 흡수제를 0.5wt% 첨가한 폴리머 안경렌즈가 411 nm 파장 이하의 자외선 및 고에너지 가시광을 99 % 이상 차단하였다. 또한 460 ~ 660 nm 파장의 명소시 시각 민감도 10% 이상의 영역에서 평균 투과율이 97.9%를 나타내어 명소시에서 선명한 상을 얻을 수 있었다.

• 한국의류산업학회지
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• 제21권2호
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• pp.231-236
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• 2019

This study investigated the proper dyeing conditions, color fastness and functionality of wool fabrics dyed with Zizania latifolia Turcz. We also tried to improve light fastness through treatment with benzophenone ultraviolet absorber. The dyeing of wool fabrics using Zizania latifolia Turcz was good even without pretreatment or mordanting treatment. Optimal wool fabric dyeing conditions were colorant concentration of 200% (o.w.f.), dyeing temperature of $100^{\circ}C$, dyeing time of 80 minutes and a dye bath pH of 3. Color fastness of dyed wool fabrics to washing, rubbing, perspiration and light was 4-5, 5, 4-4-5 (acidic), 4-5 (alkaline) and 2 respectively. The results after treatment with ultraviolet absorber for improving the fastness of daylight were improved to 3-4 grade. The UV protection rate were increased after dyeing and the deodorization of ammonia gas improved to 98%. Bacterial reduction rate (Staphylococcus aureus) of wool fabrics was excellent at 99.9%. All dye fastness (except for light fastness) was excellent; in addition, the functionality of wool fabrics dyed with Zizania latifolia Turcz also improved. The results are expected to be applied to various fields because they indicate excellent results after treatment with ultraviolet absorber for improving the fastness of daylight.

• 대한화장품학회지
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• 제26권1호
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• pp.41-58
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• 2000

최근 환경오염으로 인한 지구오존층의 파괴로 자외선의 지표면의 도달 량이 증가하고 그로 인한 인간에 대한 피해가 증가하고 있다 . 과도한 자외선의 피부에 대한 직접적인 노출은 피부에 많은 문제점을 야기하므로 일차적으로 자외선차단제를 이용하여 인체에 대한 직접적인 피해를 최소화 해야한다 . 현재 자외선 차단제는 유기자외선흡수제와 무기자외선산란제가 많이 사용이 되는데 적은량으로도 효과가 높은 유기자외선차단제는 사용 시 주의를 요하므로 국가별로 사용량과 사용여부에 대하여 규제를 하고 있다. 본 연구에서는 플라보노이드류 ,알카로이드류 같은 자외선 흡수 성분을 함유한 식물중 UV/vis spectrophotometer 에서 자외선 흡수 peak을 나타내는 금은화 , 포공영, 녹차 , 황금추출물을 이용하여 화장품의 자외선 흡수제로서의 사용가능성여부를 조사하였다. 또한 식물추출물이 가진 자극성 성분과 오염성, 그들이 가진 유효성분들을 보호하고자 실리콘을 이용한 겔화를 시도하였다 . 자연친화적인 천연물로써 식물추출성분을 이용 유기자외선흡수제의 사용량을 줄이는 자외선홉수보조제로서 가능성을 보여주었다.

• 대한치과보철학회:학술대회논문집
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• 대한치과보철학회 1999년도 Asian Academy of Prosthodntics. Korean Academy of Prosthodontics
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• pp.97-97
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• 1999