• Journal of the Korean Graphic Arts Communication Society
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• v.25 no.1
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• pp.95-107
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• 2007

This study starts to find a way out, experiment and apply commercial UV coatings to the cap closures. The cap closures is made form coating and succeeding deformation process. It is coated with several printing layers, printing and over print varnish coating. Then it pressed in three steps of press called 'deep-drawing'. In this study, two kinds of coating was designed and accomplished in the base of the same manufacturing and environment conditions. Consequently, UV curable ink have adequate performance in this experiment (T-bending, Erichsen Test), but it were experienced several damages in this experiments (web-bending, impact test). They were not cured enough to endure the friction and a unique shape of serial cracks were appeared.

• Journal of the Korean Wood Science and Technology
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• v.32 no.6
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• pp.23-35
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• 2004

The goal of study was to investigate the influence of the acrylated urethane oligomer on mechanical properties, the chemical resistance and thermal resistance of the UV curable urethane acrylate coatings for fancy veneer overlayed plywood flooring. The pencil hardness and abrasion resistance of the coated fancy veneer overlayed plywood floorings increased with increasing the acrylate functionality of the acrylated urethane oligomer. In the case of the UV cured film containing hexa-functional acrylated aliphatic urethane oligomer, high discoloration of the coated fancy veneer overlayed plywood flooring was observed near the cracks at the beginning of the chemical treatment. In this study, it was found that the degradation of the UV cured film caused by an alkaline reagent was higher than that of the UV cured film caused by an acidic treatment.

• Journal of the Microelectronics and Packaging Society
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• v.29 no.2
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• pp.107-112
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• 2022

In this study, a silver paste capable of UV curing without using any solvent was developed. The viscosity and viscoelasticity of the silver paste developed as a solvent-free type were measured. And after printing the pattern by screen printing, an electrode coating film was formed by UV curing. Conductivity, pencil hardness, and adhesive force of the formed electrode coating film were evaluated. Finally, the curing characteristics of the electrode coating film were evaluated by TGA and FT-IR. Summarizing these results, in terms of conductivity, adhesion, and curing characteristics, it was found that Paste (4), that is, silver paste obtained by mixing 1.2 ㎛ spherical silver powder and 50 nm silver powder at 72:8% had the best physical properties.

• Applied Chemistry for Engineering
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• v.2 no.2
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• pp.175-184
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• 1991

Ultraviolet curable coatings are often used to protect the surface of polymer materials exposed to the ultraviolet radiation. However, the adhesion of epoxy acrylate on poly(vinyl chloride) and the UV curable coating on polystyren are poor. The objective of this work was to improve the adhesion of coating according to various formulations of the reactive diluents and finishing methods using the photografting of multifunctional acrylate and the surface activation on polymer surface impregnated a phtoinitiator. The addition of Tripropylene glycole diacrlate in the formulation of coating results in the improvement of adhesion of coating due to the flexibility. But the increase of the crosslinking density which results from the oxidation of surface during the exposure of UV radiation caused the loss of adhesion of coating exept the photografting method. In the trimethylolpropane triacrylate the improvement of adhesion are considerable due to the chemical bond between multifundtional acrylate and surface. From this work we expect to achieve the varity and functionality in the formulation of coating according to the photografting and surface activating of polymer.

• Journal of Adhesion and Interface
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• v.3 no.3
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• pp.22-29
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• 2002

UV curable coating system described here consists of double layers, namely under layer and top laser coatings. The former consists of organic-inorganic conductive materials and the latter consists of multifunctional acrylates. Transparent double layer coatings were prepared on the transparent substrates i.e. PMMA, PC, PET etc. by the wet and wet coating procedure. Their surface resistances and film properties were measured as a function of the top layer thickness and relative humidity. As the thickness of the top layer was less than $10{\mu}m$, the surface resistance in the range of $10^8{\sim}10^{10}{\Omega}/cm^2$ was obtained. The surface properties of the two-layer coating were remarkably improved compared with the single layer coating. The effects of migration of conducting materials on the film properties of multilayer coating were investigated by using contact angle and Fourier transform infrared/attenuated total reflection(FT-IR/ATR). It was found that the migration of dopant(dodecyl benzenesulfonic acid, DBSA) molecules were occurred from film-substrate interface to film-air interface in the organic conductive coating system but not in the inorganic one.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.E
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• pp.39-46
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• 2000

Volatile Organic Compounds (VOCs) are considered as the precursors of atmospheric ozone and photochemical smog formation. In particular, chemical plants have produced a lot of VOCs and thus they have been forced to reduce or remove air emissions from the on-site chemical facilities. For the effective removal of VOCs produced in the chemical plants, the authors employed a titanium oxide(TiO$_2$) mediated photo-catalytic oxidation method. The initiation methods employed in this study to produce oxygen radicals for th photo-catalytic oxidation of the VOCs were Ultra-Violet(UV), Non-Thermal Plasma(NTS), and a combination of Uv and NTP. This study focused on a comparison of the removal efficiencies of VOCs as a function of the initiation method such as NTP and/or UV techniques. Removal efficiency change of VOCs as was investigated as a function of the wavelength of the UV lamp(254, 302, and 365 nm) and the degree of TiO$_2$ coating (10 and 30%). In this study, it was identified that removal efficiencies if the VOCs under the normal air environment were much better than those under the nitrogen gas environment containing small amount of oxygen. Removal efficiency by NTP technique was much better than the UV or the combination of UV and NTP techniques. In a comparison if UV wavelengths employed, it was found that shorter wavelength showed better removal efficiency, compared with longer ones. When the removal efficiencies of VOCs were compared in terms of the degree of TiO$_2$ coating, the higher TiO$_2$coating showed better removal efficiency that the lower TiO$_2$ coating

• Journal of the Korean Chemical Society
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• v.38 no.7
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• pp.480-484
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• 1994

The durability of UV radiation cured coatings near the film-substrate interface has been studied. Particularly, the influence of the reactive diluent and oligomer in the UV-cured urethane acrylate formulation on the wrinkle formation of coating films was investigated. Results showed that wrinkle resistance increases when DMTA loss peaks of coating network are broad and has shoulder. When modified aromatic urethane acrylate oligomer is used to replace the aliphatic one, resulting cured network provides coating film of high hardness and flexibility. Therefore, the high values of loss modulus as low temperature are considered to be the main reason for wrinkle resistance improvements. The SEM and instron data support above conclusion.

• Journal of the Korean Applied Science and Technology
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• v.26 no.4
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• pp.467-472
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• 2009

Ultraviolet curable coating solution was prepared with poly(ethylene glycol) acrylate oligomer and various mono and multi-functional acrylate monomers. The optical properties of UV cured coating layer on PET film with acrylate coating solution containing metal oxides, such as fumed silica and alumina, were also investigated to reduce light reflection on films. Poly(ethylene glycol) diacrylate which has 575 of average molecular weight was used as oligomer acrylate, and pentaerythritol triacrylate and dipentaerythritolpenta-/hexa acrylate were used as multi-functional acrylate monomers. Also, butyl acrylate was used to improve the adhesion as well as to reduce glass transition temperature to give a better flexability. 1-hydroxy cyclohexyl phenyl ketone was used as photoinitiator. We found out the metal oxides in acrylate coating solution showed a homogeneous dispersion from energy dispersive spectroscopy data. Transmittance and light reflection of coated PET film was measured with UV/vis spectrometer and gloss meter, respectively. When 1.00 g of both metal oxides was added into coating solution, the transmittance and the glossiness were reduced from 90% to 30% and from 190 GU to 35 GU, respectively. However, adding up to 1.00 g of the metal oxide into coating solution did not affect on the hardness of coating layer and adhesion between coated layer and PET film. Conclusively, we can control transmittance and light reflection of coated film by adjusting the amounts of metal oxide in coating solution.

• Journal of the Korean Graphic Arts Communication Society
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• v.18 no.2
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• pp.13-27
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• 2000

The UV curing industry is one of the most wide application fields in the coating and printing inks industry. Applications extend to general coating for paper, board, wood tapes, compact discs and holograms, ink, photoresists for imaging processes and adhesives for welding and sealing in circuit boards. The UV-curing resins have advantages of quick set, space saving, clean environment and efficient use of energy. The purpose of this study has been to control of morphology structures consist of UV-curing resins and alkyd resins. Therefore, we are investigated with regard to rheology properties on the exposure to UV-curing, structures and mechanical properties for curing films.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.2
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• pp.608-613
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• 2010

This study is on development of UV-cured water soluble coating composition which have more improved anti-cigar burning to prevent a surface of PVC tile from damage of heat. To make an anti-cigar burning coating solution, thermostable agent that synthesize main materials phosphorus compound, guanidine and ammonium phosphate dibasic used temporary flame retardants, changing their contents from 10 to 30wt% against quantities of resin and compounded. After coating PVC tiles using bar-coating method that can adjust a thickness, we estimated surface properties of coated layer such as anti-cigar burning, adhesive power, chemical resistance, thickness of coating, and so on. Results showed that a coating composition added 30 wt% of phosphorus compound and coated with No.12 bar-coater had the best optimized surface property in anti-cigar burning effect, adhesive power and chemical resistance. Also, we could find anti-cigar burning effect was improved as thermostable agents content and coating thickness increased.