• Title/Summary/Keyword: UV absorbent

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Photo-sintering of Silaver Nanoparticles using UV-LED

  • Lee, Jaehyeong;Kim, Minha;Kim, Donguk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.88.1-88.1
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    • 2015
  • In recent printed electronics technology, Photo-Sintering, a technique for sintering materials using a light source, has attracted attention as an alternative to time-consuming high-temperature thermal processes. The key principle of this technique is the selective heating of a strongly absorbent thin film, while preventing the heating of the transparent substrate by the light source. Many recent studies have used a flash lamp as the light source, and investigated the material-dependent effect of the width or intensity of the pulsed light. However, the flash lamp for sintering is not suitable for industry yet, because of needing too high power to sinter for a large scale. In energy-saving and large-scale sintering, LED technologies would be very useful in the near future. In this work, we investigated a sintering process for silver nanoparticles using UV-LED array. Silver nanoparticles in ink were inkjet-printed on a $1{\times}1cm$ area of a PET film and photo-sintered by 365 nm UV-LED module. A sheet resistance value as low as $72.6m{\Omega}/sq$ (2.3 - 4.5 times that of bulk silver) was obtained from the UV-LED sintering at 300 mW/cm2 for 50 min.

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Effect of Filler and Additive on Performance of Cycloaliphatic Epoxy used for Outdoor Insulators (싸이클로알리파틱 에폭시 절연재료의 옥외 성능에 미치는 층전재 및 첨가물의 영향)

  • 허창수;연복희;서유진;이기택;김남렬;황명근;김완태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.431-434
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    • 2002
  • This paper reports on the evaluation of weathering resistance, tracking test and salt-fog of various kinds of cycloaliphatic epoxy systems. It was found that UV irradiation induced the loss of hydrophobic level due to the chain scission attack at the surface. It could be seen that samples containing an UV absorbent/antioxidant and a silicone oil additive knave a good performance in weathering ageing, whereas ATH filled ones have high resistance against tracking failure than others. Under salt-fog test, specimens mixed with silicone oil could suppress leakage current development. It was thought that silicone oil mixed into cycloaliphatic epoxy system could lead to lower the surface energy and to retain hydrophobic properties for a long time, which are desirable for outdoor performances.

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Research and Application for Natural Extract That Contain Ultraviolet Rays Absorbent Ingredient (자외선 흡수 활성 성분을 함유한 천연추출물에 대한 연구와 응용)

  • 김경동
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.1
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    • pp.117-122
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    • 2004
  • Exessive UV radiation causes a lot of problems in our skin. In order to find out the alternative UV absorber that can safely be used in cosmetics, we have screened various natural extracts in terms of their UV absorbing effect. Some natural extracts, which possess antioxidative activities, have also been found to retard the oxidation process in our experiment. Natural compound such as 7-hydroxycymopol, baicalein, etc. could be transformed into adjuvant UV absorber by chemical modification. In cosmetics, its chemical stability against UV radiation, exposure to oxygen and other factors could be improved by using the silicone or W/S type emulsion. The values of MED (minimal erythema dose) were improved to 0.10 ${\pm}$ 0.02∼0.11 ${\pm}$ 0.02 by adding this natural extract into the cosmetic formulations. In conclusion, the results of the present study show that natural extracts could be used as an adjuvant UV absorber, if they are stabilized.

New Photochemistry of UV-Absorbing Chemicals in Phase-Controlled Polymer Microspheres (상구조가 조절된 고분자 미립구에서 자외선 흡수제의 거동에 대한 연구)

  • Lee Jong-Suk;Kim Jin-Woong;Kim Junoh;Han Sang-Hoon;Chang Ih-Seop
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.361-367
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    • 2004
  • In this study, a different UV (ultra-violet) ray absorption system is presented in which butyl methoxydiben-zoylmethane (BMDM, a model UV-A absorbent, 320$\~$400 nm) is stabilized in phase-controlled poly(methyl methacrylate) (PMMA) microspheres. The photochemistry of BMDM in the microspheres was investigated considering its phase characteristics therein. The analysis of a differential scanning calorimeter and X-ray diffractometer showed that the BMDM in the microspheres was present with a non-crystalline state. The phase control of BMDM in the polymer microsphere has an excellent ability to protect UV-A with maintaining its photo- and thermal stability. The results obtained in this study illustrate well that the phase control of the UV absorbents in the polymer microspheres is another key factor that de-termines its photochemistry and photostability in the final formulations.

Width Control in the Photo patterning of PDP Barrier Ribs

  • Kim, Dong-Ju;Kim, Soon-Hak;Hur, Young-June;Kim, Duck-Gon;Lee, Sam-Jong;Jung, Sang-Kwon;Kim, Myeug-Chan;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.910-912
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    • 2006
  • Barrier ribs in plasma display panels (PDPs) function to maintain the discharge space between the glass plates as well as to prevent optical cross-talking. The barrier ribs currently employed are typically $300{\mu}m$ pitch, $110{\sim}120{\mu}m$ in height, with upper and lower widths of $50{\mu}m$ and $80{\mu}m$, respectively. It has been reported that barrier ribs can be fabricated by screen-printing, sand blasting, etching and photolithographic processes. In this study, photosensitive barrier rib pastes were formulated and systematically evaluated in terms of photolithographic process variables such as printing, drying, UV exposure, development and sintering. It was found that the use of UV absorbent, polymerization inhibitor and surfactant were very effective in controlling the width uniformity of barrier ribs in the photolithographic method of barrier rib patterning.

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Thermal and UV Resistance of Polytrimethylene Terephthalate Bulked Continuous Filament (PTT BCF) and The Influence of Additive on Those (PTT BCF의 분산염료 염색에서 첨가제의 내열성 및 내광성 효과)

  • Moon, Chang-Heon;Lee, Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.11
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    • pp.527-536
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    • 2019
  • This study examines the degradation of PTT BCF and fading behavior of disperse dye by heat treatment and UV irradiation. The behavior in strength degradation of PTT BCF after treat treatment was examined by measuring the tensile strength of samples. The strength retention of PTT BCF rapidly decreased with increasing exposure time at 150℃. The K/S value decreased with increasing temperature and its trend accelerated with increasing exposure time on heat. The behavior on strength degradation of PTT BCF and the fading of disperse dye on it were studied under UV irradiation at various temperatures. The tensile strength of PTT BCF and the K/S value of the sample dyed with disperse dye after UV irradiation decreased with increasing temperature and exposure time. PTT BCF exposed under UV irradiation exhibited lower strength and K/S value compared with the sample after heat treatment. Additional study on the effects of additives used to improve the resistance to fading of disperse dye and degradation of PTT BCF revealed that antioxidant and UV absorbent in PTT BCF showed a small improvement in the strength degradation of PTT BCF and the fading of dye.

Effect of Filler and Additive on Performance of Cycloalipatic Epoxy Used for Outdoor Insulators (Cycloaliphatic계 에폭시 절연재료의 옥외성능에 미치는 충전재 및 첨가물의 영향)

  • 연복희;박충렬;허창수;심대섭
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.4
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    • pp.30-37
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    • 2002
  • This paper reports on the results of weathering test, tracking test and salt-fog test of various kinds of cycloaliphatic epoxy systems. UV irradiation dramatically induced the loss of surface hydrophobicity due to the chain scission attack at the surface under UV irradiation. It could be seen that samples containing an UV absorbent/antioxidant and a silicone oil additive have a good performance in weathering test, while ATH(alumina tri-hydrate) filled ones have high resistance against tracking failure than others. Under salt fog chamber test, specimens mixed with silicone oil are able to suppress leakage current development. It was thought that silicone oil mixed into cycloaliphatic epoxy system could lead to lower the surface energy and to retain hydrophobic properties for a long time, which are desirable for outdoor use.

Weight Reduction and Dyeing Characteristics of Sea-Island Type Ultramicrofiber PET Tricot Fabric with Black Color (해도형 PET 극세사 트리코트 편성물의 감량 가공 및 블랙 색상의 염색성 평가)

  • Kang, Jeong Min;Kim, Min Gu;Lee, Ji Eun;Ko, Jae Wang;Kim, Il Jin;Lee, Jae Yeon;Lee, Dong Jin;Ko, Seong Ik;Jung, Dae Ho;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.9-18
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    • 2020
  • In this study, we conducted alkali hydrolysis on sea-island type PET ultramicrofiber tricot fabric and dyeing according to the various conditions with black disperse dye. Herein, we evaluated the weight loss rate and tensile strength according to the NaOH contents. The optimal alkali hydrolysis treatment conditions were set to 25 %omf NaOH with a treatment time of 60 min at 110 ℃, and average weight loss rate of the PET ultramicrofiber tricot fabric is about 23 %. The dyeing conditions were investigated with different dyeing temperatures(95-135 ℃), dyeing time(20-60 min), dye contents(2-10 %omf), dispersant contents(1-9 g/ℓ), pH buffer solution contents(1-9 g/ℓ), UV-absorbent contents(5-25 %omf) and reduction cleaning process conditions for black color. We obtained the optimum conditions of the dyeing with the dye contents of 8 %omf, the dispersant contents of 1 g/ℓ, the pH buffer solution contents of 1 g/ℓ, the UV-absorbent contents of 10 %omf, the dyeing temperature of 135 ℃ and the dyeing time of 40 min. The light colorfastness of dyed ultramicrofiber PET tricot fabric was good to excellent in the range of 4 to 5.

Evaluation of Sampling and Analytical Methods for the Determination of Polycyclic Aromatic Hydrocarbons in the Ambient Atmosphere (환경대기중 다환방향족탄화수소의 포집과 분석방법에 관한 연구)

  • 백성옥
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.1-16
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    • 1991
  • In this study, sampling and analytical procedures were evaluated for the determination of ambient levels of atmospheric PAH, both in gaseous and particulate phase. The method involves low-volume sampling and Soxhlet extraction of the filters and Tenax absorbent, followed by a clean-up stage using a silica column prior to analysis by reversed-phase HPLC with wavelength programmable fluorescence and UV detection. A total of 18 PAH were identified and quantified, all of which have been of environmental concern. In order to validate the methodology and to ensure compatibility of the results, the analytical method used for the determination of PAH was evaluated with respect to the efficiencies of extraction and clean-up procedure, HPLC separation, and lower limits of detection. In addition, substrate dependency of PAH recovery was investigated for the two types of fiters, i.e. glass fiber and PTFE filters.

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에탄올을 첨가한 reflux법 나노 세리아 합성

  • Jo, Min-Yeong;Lee, Jae-Won;Park, Seon-Min;Choe, Heon-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.162-162
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    • 2008
  • 세리아는 고체 산화물 연료전지(SOFC, solid oxide fuel cell)의 전해질 재료와CMP( chemical mechanical polishing) 슬러리 재료, 자동차의 3원 촉매, gas sensor, UV absorbent등 여러 분야에서 사용되고 있다. 본 연구에서는 세리아의 입자의 크기와 형상을 조절하여 성능 및 물성을 향상시켜 보다 넓은 분야의 활용을 하고자 실험을 실시하였다. 세리아 합성에 사용되는 전구체인 cerium carbonate의 특성이 세리아 분말의 물리화학적 특성에 직접적인 영향을 주기 때문에 전구체의 합성 단계에서 형상과 크기를 조절하고자 하였다. 세륨염으로 cerium nitrate hexahydrate, 균일침전반응을 할 수 있는 urea를 침전제로 사용하였다. 반응 용매의 유전상수를 조절하고 반응의 과포화도 변화를 이용하기 위하여 에탄올을 첨가하여 입자의 크기 및 형상을 조절, cubic형태의 $Ce_2O(CO_3)_2{\cdot}H_2O$ 결정상을 가지는 세리아 전구체를 합성하였다. 이렇게 생성된 전구체를 $1000^{\circ}C$에서 2시간동안 하소하여 세리아를 합성하고 반응시간, 농도, 에탄올의 함량 변화에 대해 XRD, FE-SEM, particle size analyzer, micropore physisorption analyzer 분석을 통하여 입자의 결정상과 형상, 입도 분포 및 기공분포 등을 반응인자의 변화에 따라 비교 및 해석하였다.

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