• Title/Summary/Keyword: UV Process

Search Result 1,517, Processing Time 0.029 seconds

Effective Treatment of N-Nitrosodimethylamine using Advanced Oxidation Process (UV Process) and Toxicity Evaluation (고도산화공정(UV공정)을 이용한 NDMA의 효율적인 처리와 독성 평가)

  • Song, Won-Yong;Chang, Soon-Woong
    • Journal of Korean Society on Water Environment
    • /
    • v.25 no.1
    • /
    • pp.90-95
    • /
    • 2009
  • This study investigates the oxidative degradation of N-nitrosodimethylamine (NDMA), a probable human carcinogen, by advanced oxidation process (i.e., UV process). The experiments were performed with various pH, initial concentration, UV intensity, and addition of $H_2O_2$ or $TiO_2$ on UV process. The results showed that the direct UV photolysis was the most effective treatment method. The lower pH, intial concentration and higher intensity of UV stimulated higher NDMA removal. However, addition of oxidant ($H_2O_2$, $TiO_2$) slows down photochemical treatment of NDMA since the oxidant can filter out the UV light and block it to reach the NDMA molecules. Dimethylamine (DMA) and nitrite were found to be a major byproduct from NDMA oxidation. To evaluate the chronic toxicity effects of UV-treated NDMA on the growth of microalgae, "Skeletonema costatum", was studied as long term experiments. Results demonstrated that after the 13 days exposure the chronic toxicity was decreased about 15% with application of UV process on NDMA degradation.

The Selection of Optimal Process Variables in UV-Vacuum Casting (UV-Vaccum Casting의 최적 공정 변수 선정)

  • Kim, T. W.;Woo, S. M.;Lee, S.
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2000.11a
    • /
    • pp.453-456
    • /
    • 2000
  • This paper presents experimental results on selecting optimal process parameters for UV-Vaccum casting. The UV-Vacuum casting is a relatively new process that allows very rapid mold preparation and part duplication via UV curing. Effect of various process variables such as pressure and temperature on mold strength and part accuracy was evaluated by using Taguchi method.

  • PDF

Effect of Disinfection Process Combination on E. coli Deactivation and Oxidants Generation (E. coli 불활성화와 산화제 생성에 미치는 소독 공정 결합의 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
    • /
    • v.20 no.7
    • /
    • pp.891-898
    • /
    • 2011
  • The aim of this research was to evaluate the effect of combination of disinfection process (electrolysis, UV process) on Escherichia coli (E. coli) disinfection and oxidants (OH radical, $ClO_2$, HOCl, $H_2O_2$ and $O_3$) generation. The effect of electrolyte type (NaCl, KCl and $Na_2SO_4$) on the E. coli disinfection and oxidants generation were evaluated. The experimental results showed that performance of E. coli disinfection of electrolysis and UV single process was similar. Combination of electrolysis and UV process enhanced the E. coli disinfection and 4-carboxybenzaldehyde (4-CBA, indicator of the generation of OH radical) degradation. It is clearly showed synergy effect on disinfection and OH radical formation. However chlorine ($ClO_2$, HOCl) and oxygen type ($H_2O_2$, $O_3$) oxidants were decreased with the combination of two process. In electrolysis + UV complex process, electro-generated $H_2O_2$ and $O_3$ were reacted with UV light of UV-C lamp and increased 4-CBA degradation(increase OH radical). Disinfection of electrolyte of chlorine type was higher than that of the sulfate type electrolyte due to the higher generation of OH radical and oxidants.

Experiment and Numerical Study on Thermal Characteristics of UV-NIL Process Considering the Cure Kinetics of Photo-polymer (레진의 경화 반응을 고려한 UV-NIL공정의 열특성에 관한 실험 및 수치해석 연구)

  • Kim, Woo-Song;Park, Gyeong-Seo;Nam, Jin-Hyun;Yim, Hong-Jae;Jang, Si-Yeol;Lee, Kee-Sung;Jeong, Jay;Lim, Si-Hyeong;Shin, Dong-Hoon
    • Proceedings of the KSME Conference
    • /
    • 2008.11a
    • /
    • pp.1847-1850
    • /
    • 2008
  • The process conditions during ultraviolet nanoimprint lithography (UV-NIL) process such as temperature, stamping pressure, UV irradiation, etc. are effective factors for successful imprinting of complex and fine patterns. In this study, the effects of aluminum mold on the thermal characteristics of UV-NIL process were investigated through imprinting experiments and numerical simulations. The temperature of polymer resin on mold was measured to study thermal characteristics during UV curing. From the experimental and numerical results, the importance of curing reaction control for UV-NIL process was discussed for deformation characteristics.

  • PDF

Zooplankton Removal in Seawater using UV, Electrolysis and UV+electrolysis Process (UV, 전기분해 및 UV+전기분해 공정을 이용한 해수 중의 동물성 플랑크톤 제거)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
    • /
    • v.30 no.7
    • /
    • pp.597-604
    • /
    • 2021
  • The International Maritime Organization (IMO) ballast water management agreement (International Convention for the Control and Management of Ship's Ballast Water and Sediments) came into force on September 8, 2017. This study evaluated the disinfection performance of electrolysis, UV treatment, and electrolysis + UV combined, to improve the treatment of zooplankton (size ≥ 50 ㎛), which is expected to strengthen the standards for biodegradation efficiency. Among the methods used, the disinfection time leading to 100% death was in the order: electrolysis > electrolysis + UV > UV process. For the same level of disinfection performance, the amount of electricity required for the electrolysis, UV, and electrolysis + UV processes were 1,300 W.s, 8,400 W.S, and 4,500 W.s, respectively. The combination of electrolysis + UV process for inactivation of zooplankton in ballast water did not show a synergic effect owing to the slow disinfection time and high power consumption.

Analysis of the shrinkage and warpage of Wafer lens during UV curing (Lens 성형시 UV경화 반응에 따른 수축 및 변형 대한 해석적 접근)

  • Park, Sihwan;Moon, Jong-Sin
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.11
    • /
    • pp.6464-6471
    • /
    • 2014
  • The UV curing method is a popular process for lens molding on a unit wafer. This process, however, has several drawbacks including wafer adhesion during the ejection process after curing, errors in lens shape and wafer warpage due to material shrinkage during the curing process, and lens centering errors on both sides of a wafer. Among these, the lens shape error and warpage are influenced directly by the UV curing process due to factors including the UV radiation uniformity, the degree of cure according to UV intensity, and the shrinkage characteristics of the material. Therefore, a theory is needed not only to understand the change in the material characteristics, such as the shrinkage rate due to the curing reaction, but also to establish a model. In addition, an analysis system is needed to realize the model. This study proposes a new analysis method for the wafer lens molding process by Comsol modeling. This method was verified by comparing the results with those of the actual process.

Comparison of Acetaminophen Degradation Performance using Advanced Oxidation Process (고급산화공정을 이용한 아세트아미노펜 분해 성능 비교)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
    • /
    • v.31 no.4
    • /
    • pp.319-328
    • /
    • 2022
  • This study investigated the treatment of acetaminophen in municipal wastewater by conventional ozonation, ozone-based advanced oxidation, ozone/UV, and the electro-peroxone process. The ozone/UV process and electro-peroxone process of electric power consumption increased 1.25 and 2.04 times, respectively, compared to the ozone process. The pseudo-steady OH radical concentration was the greatest in the electro-peroxone process and lowest in the ozone process. The specific energy consumption for TOC decomposition of the ozone/UV process and electro-peroxone process were 22.8% and 15.5% of the ozone process, respectively. Results suggest that it is advantageous in terms of degradation performance and energy consumption to use a combination of processes in municipal wastewater treatment, rather than an ozone process alone. In combination with the ozone process, the electrolysis process was found to be more advantageous than the UV process.

Development of Continuous UV Nano Imprinting Process Using Pattern Roll Stamper (패턴 롤 스템퍼를 이용한 연속 UV 나노 임프린팅 공정기술 개발)

  • Cha, J.;Ahn, S.;Han, J.;Bae, H.;Myoung, B.;Kang, S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2006.05a
    • /
    • pp.105-108
    • /
    • 2006
  • It has been issued to fabricate nano-scale patterns with large-scale in the field of digital display. Also, large-scale fabrication technology of nano pattern is very important not only for the field of digital display but also for the most of applications of the nano-scale patterns in the view of the productivity. Among the fabrication technologies, UV nano imprinting process is suitable for replicating polymeric nano-scale patterns. However, in case of conventional UV nano imprinting process using flat mold, it is not easy to replicate large areal nano patterns. Because there are several problems such as releasing, uniformity of the replica, mold fabrication and so on. In this study, to overcome the limitation of the conventional UV nano imprinting process, we proposed a continuous UV nano imprinting process using a pattern roll stamper. A pattern roll stamper that has nano-scale patterns was fabricated by attaching thin metal stamper to a roll base. A continuous UV nano imprinting system was designed and constructed. As practical examples of the process, various nano patterns with pattern size of 500, 150 and 50nm were fabricated. Finally, geometrical properties of imprinted nano patterns were measured and analyzed.

  • PDF

Removal of microorganic pollutants based on reaction model of UV/chlorine process (자외선/염소 반응해석 모델에 의한 미량유기물질 제거에 관한 연구)

  • Hwang, Tae-Mun;Nam, Sookhyun;Kwon, Minhwan;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.31 no.1
    • /
    • pp.73-81
    • /
    • 2017
  • The UV/chlorine process is a UV-based advanced oxidation process for removing various organic pollutants in water. The process is becoming increasingly popular because of its effectiveness in practice. It is important to the safe and efficient operation of a UV/chlorine process that the optimal operating conditions for both target removal objective and saving energy are determined. Treatment efficiency of target compounds in UV/chlorine process was mainly affected by pH and scavenging factor. In this study, kinetic based mathematical model considering water characteristics and electrical energy dose calculations model was developed to predict of treatment efficiency and optimal operating conditions. The model equation was validated for the UV/chlorine process at the laboratory scale and in pilot tests at water treatment plants.

Characterization of Diethyl Phthalate(DEP) Removal using Ozone, UV, and Ozone/UV Combined Processes (오존, UV, 오존/UV 혼합 공정을 이용한 Diethyl Phthalate(DEP)의 제거특성 연구)

  • Jung, Yeon-Jung;Oh, Byung-Soo;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.2
    • /
    • pp.137-143
    • /
    • 2006
  • Three candidate processes(ozone alone, UV alone and ozone/UV combined processes) were evaluated for the removal of diethyl phthalate(DEP). Of the candidates, the ozone/UV process showed the highest removal efficiency of DEP. To elucidate a major oxidant for DEP oxidation in the ozone/UV process, the effects of pH and hydroxyl radical($OH^{\circ}$) scavenger were investigated. As a result, it was found that $OH^{\circ}$ plays a important role for DEP elimination. Meanwhile, the direct reaction between ozone and DEP was negligible. Observing the pseudo first-order rate of DEP removal in ozone alone and ozone/UV processes, the different pattern was obtained from two processes. The ozone/UV process was well plotted following the pseudo first-order. but in the ozone alone process the rate was divided into fast and slow phases. DEP degradation characteristics in ozone alone and ozone/UV was also investigated by observing the HPLC spectrum. We detected unknown compounds that were guessed to DEP byproducts and observed the formation and disappearance of the unknown compounds according to reaction time. Observing of high removal of TOC in ozone/UV combined process, it was found that DEP and DEP byproducts are completely oxidized by ozone/UV combined process.