• Title/Summary/Keyword: UV Irradiation

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Relationship between the pretilt angle generation and the polarization component with linearily polarized UV light irradiation on polymer surface. (직선편광된 UV광을 폴리이미드막에 조사한 경우의 프리틸트각의 발생과 편광성분의 상호관계)

  • Seo, Dae-Shik;Park, Doo-Seok;Han, Jeong-Min
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1391-1394
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    • 1998
  • In this paper, we investigated the generation of pretilt for nematic liquid crystal (NLC) in a cell with linearly polarized ultraviolet (UV) light irradiation on polyimide (PI) surface. The pretilt angle of the NLC increases with increasing the incident angle in the cells with S-wave polarized UV light irradiation on PI surface. It is considered that the pretilt angle of the NLC increased due to decreasing the UV light intencity. We suggest that the pretilt angle of the NLC is attributed to asymmetry triangular of the polymer surface with S-wave polarized UV light irradiation on PI surface. Also, we consider that the asymmetry triangular of the Polymer not formed with P-wave polarized UV light irradiation on PI surface. Therefore, the pretilt angle of the NLC is attributed to asymmetry triangular of the polymer surface with UV light irradiation on PI surface.

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UV-induced Crosslinking of Poly(vinyl acetate) Films Containing Benzophenone (벤조페논을 함유한 폴리비닐아세테이트 필름의 자외선 조사에 의한 가교)

  • Sim, Young-Jae;Seo, Eun-Kyo;Choi, Gyong-Jun;Yoon, Sung-Jong;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.33-38
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    • 2009
  • Poly(vinyl acetate) films containing benzophenone were photocrosslinked by continuous UV irradiation.UV irradiation of PVAc film containing 5% benzophenone induced bulk crosslinking of the polymer indicated by 84.1% of gel fraction after ethyl acetate extraction. The crosslinking was attributed to the recombination of tertiary polymer radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of benzophenone. Also the UV irradiation resulted in scission of ester linkage and photooxidation of PVAc surface, which was verified by ATR and zeta potential analysis, implying that the PVAc surface became more polar and hydrophilic. The zeta potential proportionally increased from +4.5mV to -26.8 mV with increasing UV irradiation. Also the surface energy of the PVAc film increased with higher UV irradiation upto 56.5 $mJ/m^2$ by the enhanced Lewis acid/base component with larger contribution of Lewis acid parameter. Accordingly the crosslinked PVAc showed higher thermal stability with increasing UV energy.

The Characteristics of Persimmon Juice Dyeing using Padding and UV Irradiation Method (PartII) - Color and Properties of Persimmon Juice Dyed Silk Fabrics - (패딩과 자외선조사법을 이용한 감즙 염색 특성(제2보) -감즙 염색 견직물의 염색성과 물질-)

  • 이혜자;한영숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.7
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    • pp.882-891
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    • 2004
  • The purpose of this study was to improve dye effect and method in order to facilitate the use of persimmon juice dyeing. Silk fabrics were pad-dyed to 100% pick-up using padding machine after dipping in persimmon juice extracted from unripe persimmons indigenous to Jeju. The color of dyed silk fabrics by padding method was more even and repeatable than that by traditional hand method. Persimmon juice concentrations were 4 types 10, 25, 50 and 100%. The silk fabrics were pad-dyed to 100% pick-up and were repeatedly dyed two times and three times with 100% concentration. The higher the concentration, the more color deepened. UV Irradiation instead of sunlight was applied to color developing. Irradiation times were shortened to 1-8hrs. Color values which reguired 30-50 hrs. in sunlight irradiation. were obtained in 3-5 hrs. with UV irradiation. Tensile strengths of silk fabrics in UV irradiation decreased but not decreased in sunlight irradiation. Elongations of silk fabrics in sunlight irradiation increased but decreased in W irradiation. Drape stiffness increased up to three times.

Effect of Ultraviolet (UV-B) on Antioxidants and Antioxidative Enzymes in Garden Balsam(Impatiens balsamina L.) (자외선(UV-B)이 봉선화(Impatiens balsamina L.)의 항산화제 및 항산화 효소에 미치는 영향)

  • Kim, Hak-Yoon
    • Korean Journal of Weed Science
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    • v.30 no.2
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    • pp.135-142
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    • 2010
  • To investigate the effects of ultraviolet(UV-B) on growth and biochemical defense responses of plant, garden balsam (Impatiens balsamina L.) was subjected to enhanced UV-B irradiation [daily dose: 0.02 (No UV-B) and 11.34 (enhanced UV-B) kJ $m^{-2}$ ; $UV-B_{BE}$] for 3 weeks. Enhanced UV-B drastically inhibited leaf area as well as dry weight of garden balsam. The content of malondialdehyde was significantly increased by about 50% after 3 weeks of UV-B irradiation. The ratios of dehydroascorbate/ascorbate and oxidized glutathione/reduced glutathione were also considerably increased by UV-B irradiation. Three major polyamines of garden balsam leaves: putrescine, spermidine and spermine were observed. All polyamine contents were increased with UV-B irradiation. The enzyme (superoxide dismutase, ascorbate peroxidase etc.) activities of garden balsam were increased by the UV-B enhancement. Based on the results, enhanced UV-B caused oxidative stress in garden balsam and biochemical protection responses might be activated to prevent from damaging effects of oxidative stress generated by UV-B irradiation.

A Study on Alignment of Nematic Liquid Crystal by Using Slanted Non-polarized Ultraviolet Light Irradiation on Polyimide Film (폴리이미드막표면위에 경사진 자외선 조사를 이용한 네마틱 액정의 배향에 관한 연구)

  • 서대식;황율연;이보호
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.461-466
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    • 1997
  • In this paper, we developed the new non-rubbing liquid crystal (LC) alignment techniques in the cell with slanted non-polarized ultraviolet (UV) light irradiation on polyimide (PI) film. It is shown that the uniform alignment for nematic (N) LC is obtained by using slanted non-polarized UV light irradiation on PI surface. We successfully obtained that the pretilt angle of NLC is generated about 3.3 degree in the cell with slanted non-polarized UV light irradiation with 70 degree on PI surface, for the first time. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecular and the PI, which is broken the polymer by slanted non-polarized UV irradiation. Therefore, we concluded that the uniform LC alignment is attributed to anisotropic dispersion force due to photo depolymerization with slanted non-polarized UV light irradiation on PI surface.

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Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

LOW TEMPERATURE DEPOSITION OF SILICON OXIDE FILMS BY UV-ASSOSTED RF PLASMA-ENHANCED CVD

  • Hozumi, Atsushi;Sugimoto, Nobuhisa;Sekoguchi, Hiroki;Takai, Osamu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.773-780
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    • 1996
  • Silicon oxide films were prepared by using five kinds of organosilicon compound as gas sources without oxygen by rf plasma-enhanced CVD (PECVD). UV light was irradiated on a substrate vertically during deposition to enhance film oxidation and ablation of carbon contamination in a deposited films. Films prepared with UV irradiation contained less carbon than those prepared without UV irradiation. The oxidation of the films was improved by UN irradiation. The effect of UV irradiation was, however, not observed when the films were prepared with tetramethy lsilane (TMS) which contained no oxygen atom. Dissociated oxygen atoms from an organosilicon compound were excited in the plasma with UV irradiation around the substrate surface and affected the enhancement of film oxidation and ablation of carbon in the films.

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Synthesis of Allylthiopyridazine Derivatives and their Protective Effects of W-C Irradiation (알릴티오피리다진 유도체 합성 및 UV-C조사에 대한 방어효과)

  • 권순경;현진원
    • YAKHAK HOEJI
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    • v.44 no.1
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    • pp.9-15
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    • 2000
  • Four 3-alkoxy-6-allylthiopyridazines and 3-chloro-6-allylthiopyridazine were synthesized and their protective effects against oxidative stress and UV-C irradiation were tested. 3-Methoxy-6-allylthiopyridazine and 3-ethoxy-6-allylthiopyridazine did not show protective effect on the oxidative stress but showed the strongest protective effect on UV-C irradiation among the tested compounds. Especially 500 $\mu\textrm{g}$/$m\ell$ of the two compounds was the most effective concentration.

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Effect of UV-C Irradiation on the Inactivation of Listeria monocytogenes and Lipid Oxidation in Hamburger Patties during Storage (UV-C 조사가 햄버거 패티 저장 중 Listeria monocytogenes의 생육저해 및 지질산화에 미치는 영향)

  • Kim, Hyun-Jin;Kim, Seul-Ki;Chun, Ho-Hyun;Song, Kyung-Bin
    • Food Science and Preservation
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    • v.17 no.3
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    • pp.425-429
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    • 2010
  • Inactivation by UV-C irradiation of Listeria monocytogenes cocktail inoculated on hamburger patties was examined. Hamburger patty samples were inoculated with 6-7 log CFU/mL of L. monocytogenes cocktail, and then exposed to doses of 0, 1, 5, or $10kJ/m^2$ of UV-C light, followed by storage at $4{\pm}1^{\circ}C$ for 7 d. Microbiological evaluation indicated that the populations of L. monocytogenes decreased significantly (p<0.05) as irradiation dose increased. In particular, L. monocytogenes populations decreased by 2.03 log CFU/g after exposure to 10 $kJ/m^2$, compared with control samples. The thiobarbituric acid-reactive substance levels of hamburger patty samples increased during storage, regardless of UV-C irradiation status. These results indicate that UV-C irradiation may be useful in improving the microbial safety of hamburger patties during storage.

Isolation and Characterization of UV-inducible gene in Eukaryotic cells

  • Choi, In-Soon
    • Journal of Life Science
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    • v.11 no.1
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    • pp.52-56
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    • 2001
  • The present study intends to characterize the DNA damage-inducible responses in eukaryotic cells. The fission yeast, S. pombe, which displays efficient DNA repair systems, was used in this study as a model system for higher eukaryotes. To study UV-inducible responses in S. pombe, five UV-inducible cDNA clones were isolated from S. pombe by using subtration hybridization method. To investigate the expression of isolated genes, the cellular levels of the transcripts of these genes were determined by Northern blot analysis after UV-irradiation. The transcripts of isolated gene (UV130) increased rapidly and reached maximum accumulation after UV-irradiation. Compared to the message levels of control, the levels of maximal increase were approximately 5 fold to UV-irradiation. In order to investigation whether the increase of UV130 transcripts was a specific results of UV-irradiation, UV130 transcript levels were examined after treating the cells to Methylmethane sulfonate (MMS). The transcripts of UV130 were not induced by treatment of 0.25% MMS. These results implied that the effects of damaging agents are complex and different regulatory pathways exist for the induction of these genes. To characterize the structure of UV130 gene, nucleotide sequences were analyzed. The nucleotide sequence of 1,340 nucleotide excluding poly(A) tail contains one open reading frame, which encodes a protein of 270 amino acids. The predicted amino acid sequences of UV130 do not exhibit any significant similarity to ther known sequences in the database.

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