• Title/Summary/Keyword: UV$^{254}$

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Degradation of Phenol in Water Using Circulation Dielectric Barrier Plasma Reactors (순환식 유전체 장벽 플라즈마 반응기를 이용한 수중 페놀 처리)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.38 no.3
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    • pp.251-260
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    • 2012
  • Objectives: The purpose of this study was evaluating the applicability of the circulation dielectric barrier plasma process (DBD) for efficiently treating non-biodegradable wastewater, such as phenol. Methods: The DBD plasma reactor system in this study consisted of a plasma reactor (discharge, ground electrode and quartz dielectric tube, external tube), high voltage source, air supply and reservoir. Effects of the operating parameters on the degradation of phenol and $UV_{254}$ absorbance such as first voltage (60-180 V), oxygen supply rate (0.5-3 l/min), liquid circulation rate (1.5-7 l/min), pH (3.02-11.06) and initial phenol concentration (12.5-100 mg/l) were investigated. Results: Experimental results showed that optimum first voltage, oxygen supply rate, and liquid circulation rate on phenol degradation were 160 V, 1 l/min, and 4.5 l/min, respectively. The removal efficiency of phenol increased with the increase in the initial pH of the phenol solution. To obtain a removal efficiency of phenol and COD of phenol of over 97% (initial phenol concentration, 50.0 mg/l), 15 min and 180 minutes was needed, respectively. Conclusions: It was considered that the absorbance of $UV_{254}$ for phenol degradation can be used as an indirect indicator of change in non-biodegradable organic compounds. Mineralization of the phenol solution may take a relatively longer time than that required for phenol degradation.

Inactivation of Microorganisms in Sewage Using a Pilot Plasma Reactor (Pilot 플라즈마 반응기를 이용한 하수 중 미생물의 불활성화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.39 no.3
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    • pp.289-299
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    • 2013
  • Objectives: For the field application of the dielectric barrier discharge plasma reactor, scale-up of the plasma reactor is needed. This study investigated the possibility of inactivation of microorganisms in sewage using pilot multi-plasma reactor. We also considered the possibility of degradation of total organic carbon (TOC) and nonbiodegradable matter ($UV_{254}$) in sewage. Methods: The pilot plasma reactor consists of plasma reactor with three plasma modules (discharge electrode and quartz dielectric tube), liquid-gas mixer, high voltage transformers, gas supply equipment and a liquid circulation system. In order to determine the operating conditions of the pilot plasma reactor, we performed experiments on the operation parameters such as gas and liquid flow rate and electric discharge voltage. Results: The experimental results showed that optimum operation conditions for the pilot plasma reactor in batch experiments were 1 L/min air flow rate), 4 L/min liquid circulation rate, and 13 kV electric discharge voltage, respectively. The main operation factor of the pilot plasma process was the high voltage. In continuous operation of the air plasma process, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal condition of 13 kV were $10^{2.24}$ CFU/mL, 56.5% and 8.6%, respectively, while in oxygen plasma process at 10 kV, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal conditions were $10^{1.0}$ CFU/mL, 73.3% and 24.4%, respectively. Electric power was increased exponentially with the increase in high voltage ($R^2$ = 0.9964). Electric power = $0.0492{\times}\exp^{(0.6027{\times}lectric\;discharge\;voltage)}$ Conclusions: Inactivation of microorganisms in sewage effluent using the pilot plasma process was done. The performance of oxygen plasma process was superior to air plasma process. The power consumption of oxygen plasma process was less than that of air plasma process. However, it was considered that the final evaluation of air and oxygen plasma must be evaluated by considering low power consumption, high process performance, operating costs and facility expenses of an oxygen generator.

Designing a Reaction Model for Ozon Contactor in Advanced Water Treatment Systems (고도정수처리설비에서 오존접촉조의 반응 특성에 대한 모델 설계)

  • 박정호;이진락;서종진;이해영
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.1
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    • pp.70-77
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    • 2001
  • This paper present a fuzzy mxlel of describing reacton features for ozon contactor in advanced water treatn-ent systems. Input and output variables are chosen by considenng the object of ozon processing and several parameters related to management of water quahty. Dissolved organic carbon concentration, $UV_{254}$ absorptIon and $KM_NO_4$ consumption are proposed as common variables in input and outp.lt variables. Furthermore own concentration, raw water's temperature and contact time are suggested as input variables, Membership hmctions for input variables have triangular type share and the grades in each lrembership function are determined by investigating process data gathered at pilot planl The decision parts of fuzzy model have linear combination form of input variables and coefficients included in such linear equations are computedd with process clata in the sense of least square error Also fuzzy trodel suggested in this paper is partitioned by 3 independent fuzzy rnxlels using the characteristics of having no interactions armng output variables. As a result, such fuzzy mxlel has rrerits in computation and comprehension. According to simulatIon results, fuzzy moIel's outputs give almost similar data to process output under same input conditions.

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Screening of Phytase Overproducing Strains in Aspergillus spp. by UV Mutagenesis

  • Lee, Eung-Suek;Paik, In-Kee;Hahm, Young-Tae
    • Mycobiology
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    • v.28 no.3
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    • pp.119-122
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    • 2000
  • Phytases (myo-inositol hexakisphosphate phosphohydrolase; EC 3.1.3.8) are enzymes which catalyze the hydrolisys of phytate into myo-inositol and inorganic phosphates. Phytases are found in plants and a variety of microorganisms. Aspergillus species were treated with 254 nm of UV irradiation for the screening of phytase overproducing mutant strains. At 15 minute irradiation, the survivals of population were less than 5%, and UV irradiation time was decided at 20 minute for the isolation of mutant strains. Four UV mutant strains in A. oryzae (YUV-47, -169, -341, -511) and six in A. ficuum (FUV-17, -36, -69, -193, -317, -419) were isolated on PSM media containing ammonium phosphate. The specific enzyme activities of A. ficuum mutants are 110 to 140% higher than that of wild type.

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Color Removal Efficiency for the Effluent of Activated Sludge Process for Pig Wastewater by TiO$_2$ Treatment System (TiO$_2$를 이용한 양돈장의 활성오니처리방류수의 탈색처리에 관한 연구)

  • 최희철;이덕수;권두중;강희설;곽정훈;최동윤;연규영;최영수;양창범
    • Journal of Animal Environmental Science
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    • v.9 no.2
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    • pp.85-92
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    • 2003
  • These experiments were conducted to evaluate the efficiency of the color removal treatment system of pig wastewater by $TiO_2$. The results obtained are summarized as follow : 1 The color removal efficiency of effluent of activated sludge process by $TiO_2$ level were 59.7 and 52.5% for 1.0 and 2.0g/$\ell$ at 360 minute of operation time, respectively. 2. The color of pig wastewater was changed from 655 color unit(cu) to 146cu of the wastewater treatment of pH 5 at 300 minute of operation time. 3. The $H_2O_2$ level for color removal showed at 200mg/$\ell$ and in that level, the color removal efficiency was 52.5%. 4. The color removal efficiency of 365nm UV intensity was 29.4%, but 254nm of UV intensity was higher(50.1%) than 365nm for color removal.

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E. coli Disinfection Using a Multi Plasma Reactor (멀티 플라즈마 반응기를 이용한 E. coli 소독)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.39 no.2
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    • pp.187-195
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    • 2013
  • Objectives: For the practical application of the dielectric barrier discharge plasma reactor, a plasma reactor able to manage large volumes of water is needed. This study investigated the possibility of the practical application of a multi-plasma reactor which is a scaled-up version of a single plasma reactor. Methods: The multi-plasma reactor consists of several high-voltage transformers and plasma modules (discharge, ground electrodes and quartz dielectric tubes). The effects of water characteristics such as voltage (30-120 V), air flow rate (1-5 l/min), number of high-voltage transformers and plasma modules, and water quality on Escherichia coli (E. coli) disinfection and decrease of COD and $UV_{254}$ absorbance were investigated. Results: The experimental results showed that at a voltage of over 80 V, most of the E. coli were disinfected within 90 seconds. E. coli inactivation was not affected by the air flow rate. E. coli disinfection in the multiplasma process showed the traditional log-linear form of the disinfection curve. E. coli inactivation performance by transformer 3-Reactor 5 and transformer 3-Reactor 3 were similar. The disinfection performance of the UV process was affected by artificial sewage water. However, the plasma process was less affected by the artificial sewage within the standards for effluent water quality. Conclusions: Disinfection performance with several low voltages and plasma modules of three to five in number applied to the plasma process was higher than that concentrating a small amount of high voltage through a single plasma reactor. Removal of COD, $UV_{254}$ absorbance, and E. coli disinfection with the plasma process were better than with the UV process.

Identification of Green Alga Chlorella vulgaris Isolated from Freshwater and Improvement Biodiesel Productivity via UV Irradiation

  • Gomaa, Mohamed A.;Refaat, Mohamed H.;Salim, Tamer M.;El-Sayed, Abo El-Khair B.;Bekhit, Makhlouf M.
    • Microbiology and Biotechnology Letters
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    • v.47 no.3
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    • pp.381-389
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    • 2019
  • Chlorella vulgaris was isolated from the Nile River, Qalubia Governorate, Egypt, for possible use in biodiesel production. BG-II nutrient growth media was used for isolation and laboratory growth. Identification was performed via 18S rRNA gene amplification, followed by sequencing. The alga was exposed to UV-C (254 nm) for 15, 30, and 45 s to improve dry weight accumulation and to increase the oil production. Daily measurements of dry weight ($g{\cdot}l^{-1}$) were performed; oil content and volumetric lipid productivity were also determined. UV-C exposure led to an increase in the volumetric lipid productivity by 27, 27.3, and $32.4mg{\cdot}l^{-1}{\cdot}d^{-1}$ with 15, 30, and 45 s, respectively, as compared with the control, which resulted in $18mg{\cdot}l^{-1}{\cdot}d^{-1}$. Of the examined mutants, the one with the highest productivity was re-irradiated by UV-C (254 nm) for 15, 30, 45, and 60 s. For 15 s of exposure time, the oil content increased to 34%, while it was 31% at 30 s; further, it decreased to 22% at 45 and 60 s exposures. The fatty acid methyl ester profile was 82.22% in the first mutant at 45 s, compared with the wild strain that contained a total of 66.01% of FAs. Furthermore, the highest levels of polyunsaturated fatty acid methyl ester were observed in the mutant exposed for 45 s, and it reached 11.41%, which reduced the cetane number to 71.3.

Characteristics of Degradation of Humic Acid in GAC Adsorption, Ozone Alone, and Ozone/GAC Hybrid Process (활성탄 흡착, 오존 단독, 그리고 오존/활성탄 혼합공정에서 부식산의 분해 특성)

  • Choi, Eun-Hye;Kim, Kei-Woul;Kim, Seog-Ku;Rhee, Dong-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.989-994
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    • 2005
  • The treatment efficiency and the degradation characteristics of humic acid were investigated in three processes-GAC adsorption, Ozone alone and Ozone/GAC hybrid process, in which $UV_{254}$, DOC, molecular size distribution and surface change of GAC were evaluated. DOC removal rate in Ozone/GAC hybrid profess(ca. 80%) was higher than the arithmetic sum of Ozone alone(38%) and GAC adsorption(19%). This result approves that the combined Ozone/GAC hybrid process brings synergistic effects on DOC removal from the HA containing water. $UV_{254}$ decrease rate was also at the highest in Ozone/GAC hybrid process from the three processes. It may be interpreted that the granular activated carbon in Ozone/GAC hybrid process acts as not only an adsorbent but also a catalyst for ozonation, and futhermore offers an additional reaction site between adsorbed organic matter and ozone. In the study of molecular sire distribution, there was no significant change of molecular size distribution in the GAC adsorption process during the reaction time of 120 min. In Ozone alone process, the fraction of molecular size over 30 kDa was decreased a little at the beginning and left constant after 10 min. But in Ozone/GAC hybrid process, the molecules size over 30 kDa of HA was significantly decreased from 36.3% to 3.9%. And also the fraction of smaller molecular size below 0.5 kDa was increased from 4.8%(untreated HA) to 12.3%(in Ozone alone) and 40.1%(in Ozone/GAC) respectively at the reaction time of 120 min.

Effect of Drinking Water Treatment by DOF(Dissolved Ozone Flotation) System (DOF 공정에 의한 정수처리 효과)

  • Lee, Byoung-Ho;Song, Won-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.743-750
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    • 2008
  • In water treatment plant the Dissolved Ozone Flotation(DOF) System may be employed because this system has various abilities, such that it can remove SS using microbubbles, and it can exert strong oxidation power in removing taste and odor, color, and microbial agents. In order to investigate effectiveness of the DOF system in water treatment, removal characteristics of various water quality parameters were observed depending on the different levels of ozone concentrations. Removal efficiencies of water quality parameters in DOF system were compared with those in DAF(Dissolved Air Flotation) system and in CGS(Conventional Gravity Settling) system. Optimum ozone dose obtained in the pilot experiments was 2.7 mg/L. With increasing ozone dose higher than 2.7 mg/L, removal rates of turbidity, KMnO$_4$ consumption, UV$_{254}$ absorbance, and TOC were reversely lowered. High concentration of ozone dissociate organic matter in water, so that increasing dissolved organic level in effluent. Removal rates of water quality parameters at optimum ozone dose were obtained, such that removal rates of turbidity, KMnO$_4$ consumption, TOC, and UV$_{254}$ asorbance were 88.9%, 62.9%, 47%, and 77.3% respectively. Removal rate of THMFP was 51.6%. For all the parameters listed above, the DOF system was more effective than the DAF system or the CGS system. It is found that the DOF system may be used in advanced water treatment not only because the DOF system is more efficient in removing water quality parameters than the existing systems, but because the DOF system is also required smaller area than the CGS system for the treatment plant.

Predictive Model Selection of Disinfection by-products (DBPs) in D Water Treatment Plant (D 정수장 소독부산물 예측모델 선정)

  • Kim, Sung-Joon;Lee, Hyeong-Won;Hwang, Jeong-Seok;Won, Chan-Hee
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.460-467
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    • 2010
  • For D-WTP's sedimentation basin and distribution reservoir, and water tap the predictive models proposed tentatively herein included the models for estimating TTHM concentration in precipitated water, for treated water and for tap water, and the estimated correlation formula between treated water's TTHM concentration and tap water. As for TTHM-concentration predictive model in sedimentation water, the coefficient of determination is 0.866 for best-fitted short-term $DOC{\times}UV_{254}$ based Model (TTHM). As for $HAA_5$-concentration predictive model in sedimentation water, the coefficient of determination is 0.947 for the suitable $UV_{254}$-based model ($HAA_5$). In case of the predictive model in treated water, the coefficient of determination is 0.980 for best-fitted $DOC{\times}UV_{254}$ based model (TTHM) using coagulated waters, while the coefficient of determination is 0.983 for best-fitted $DOC{\times}UV_{254}$ based model ($HAA_5$) using coagulated waters, which described the $HAA_5$ concentration well. However, the predictive model for tap water could not be compatible with the one for treated water, only except for possibility inducing correlation formula for prediction, [i.e., the correlation formula between TTHM concentration and tap water was verified as TTHM (tap water) = $1.162{\times}TTHM$ (treated water), while $HAA_5$ (tap water) = $0.965{\times}HAA_5$ (treated water).] The correlation analysis between DOC and $KMnO_4$ consumption by process resulted in higher relationship with filtrated water, showing that its regression is $DOC=0.669{\times}KMnO_4$ consumption - 0.166 with 0.689 of determination coefficient. By substituting it to the existing DOC-based model ($HAA_5$) for treated water, the consequential model formula was made as follows; $HAA_5=8.35(KMnO_4\;consumption{\times}0.669-0.166)^{0.701}(Cl_2)^{0.577}t^{0.150}0.9216^{(pH-7.5)}1.022^{(Temp-20^{\circ}C)}$