• Title/Summary/Keyword: UO2

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A study on manufacturing of laser welded tube from 60kgf/$mm^2$Grade Steel Sheet for one-body forming (60kgf/$mm^2$급 일체화 성형용 레이저 용접 튜브 제조에 관한 연구)

  • Seo, Jung;Lee, Je-Hoon;Kim, Jung-Oh;Kang, Hee-Sin;Lee, Mun-Yong;Jung, Byung-Hoon
    • Proceedings of the KWS Conference
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    • 2003.11a
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    • pp.18-20
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    • 2003
  • Optimal processing and system to produce the laser welded tube for one body formed bumper beam are studied. The calculated size of tube is a thickness of 1.4mm, diameter of 105.4mm and length of 2000mm. The tube is shaped from cool rolled high strength steel sheet(tensile strength: 60kgf/$\textrm{mm}^2$ grade). Two roll bending method is the optimal tube shaping process compared to UO-bending, bending on press brake, multi-step continuous roll forming and 3 roll bending methods. Weld quality monitoring and seam tracking along the butt-joint lengthwise to the tube axis are also studied. The longitudinal butt-joint is welded by the $CO_2$ laser welding system equipped with a seam tracker and plasma sensor. The constructed $CO_2$ laser tube welding system can be used for the precision seam tracking and the real-time monitoring of weld quality. Finally, the obtained laser welded tube can be used for one-body formed automobile bumper beam.

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Adsorption Characteristic of U(VI), Cu(II), Dy(III) Ions Utilizing Nitrogen-Donator Synthetic Resin (질소-주게 합성수지를 이용한 U(VI), Cu(II), Dy(III) 이온들의 흡착특성)

  • Rho, Gi-Hwan;Kim, Joon-Tae;Kim, Hee-Joung
    • Journal of environmental and Sanitary engineering
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    • v.21 no.3 s.61
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    • pp.52-60
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    • 2006
  • The ion exchange resins have been synthesized from chlormethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, and 20%-crosslinking and macrocyclic ligand of cryptand 21 by copolymerization method and the adsorption characteristics of uranium(VI), copper(II) and dysprosium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, equilibrium time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium$(UO^{2+}_2)\;>\;copper(Cu^{2+})\;>\;dysprosium(Dy^{3+})$ ion. The adsorption was in order of 1%, 2%, and 20% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Screening and Cultivation Characteristics of Alginate Degrading Bacteria (알긴산 분해 미생물의 탐색 및 생육 특성)

  • Uo, Meung-Hee;Joo, Dong-Sik;Cho, Soon-Yeong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.1
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    • pp.109-114
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    • 2006
  • For the purpose of oligosaccharide production from alginate, the main component in cell walls of brown algae, the alginate degrading bacteria have been screened from the seaweeds and soil. Among the isolated 69 strains, one strain showing the highest degrading activity was selected and identified as Bacillus licheniformis strain. The adequate sodium alginate concentration for growing the Bacillus licheniformis was $2.0\%$. The effective nitrogen source is nutrient broth $(0.1\%)$, and optimum initial pH, NaCl concentration, temperature and incubation time to produce the alginate degrading enzyme were 7.5, $2\%,\;30{\pm}2^{\circ}C$, and 144 hrs, respectively.

Production of Laser Welded Tube for Automobile Bumper Beam from 60kgf/$\textrm{mm}^2$Grade Steel Sheet (60kgf/$\textrm{mm}^2$급 자동차 범퍼빔용 레이저 용접 튜브 제조기술 및 장치연구)

  • Seo, Jung;Lee, Je-Hoon;Kim, Jong-Soo;Kim, Jung-O;Kang, Hee-Sin;Lee, Moon-Yong;Jung, Byung-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.7
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    • pp.136-144
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    • 2004
  • Optimal process and system to produce the laser welded tube for one body formed bumper beam are studied. The calculated size of tube is a thickness of 1.4mm, diameter of 105.4mm and length of 2000mm. The tube is shaped from a cold rolled high strength steel sheet(tensile strength: 60kgf/$\textrm{mm}^2$ grade). Two roll bending method is the optimal tube shaping process compared to UO-bending, bending on press brake, multi-step continuous roll forming and 3 roll bending methods. Weld quality monitoring and seam tracking along the butt-joint lengthwise to the tube axis are also studied. The longitudinal butt-joint is welded by the $CO_2$ laser welding system equipped with a seam tracker and plasma sensor. The constructed $CO_2$laser tube welding system can be used for the precision seam tracking and the real-time monitoring of weld quality. Finally, the obtained laser welded tube can be used for one-body formed automobile bumper beam.

Validation Calculations of Simulated Shipping Container Experiments with Steel, Boral, and Cadmium Plates

  • Kim, Soon-Sam;Lee, Sang-Hee
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05a
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    • pp.33-38
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    • 1997
  • Criticality experiments with fixed neutron poison plates for water moderated and reflected low enriched(2.35 and 4.31 wt%) UO$_2$fuel rod clusters were evaluated to validate calculation techniques employed in analyzing fuel shipping and storage systems having steel, boral, or cadmium shield. Measurements were obtained for both the 2.35 wt% and the 4.31 wt% enriched rods in square pitched, water flooded lattices. The critical experiments with the 2.35 wt% enriched rods consists of three 20$\chi$ 16 or 20$\chi$ 17 fuel cluster. Critical separation were used in the experiments with the 4.31 wt% enriched fuel rods. In the experiments, the poison plates were placed on both sides of the centrally located fuel cluster. Critical separation between the three sub-critical fuel clusters were then measured for varying plate thicknesses and distances of the plates to the center fuel cluster. Calculations were performed for thirty eight critical configuration using KENO-V. a and MCNP. All of the results were within 1.23% in $\Delta$k when individually compared with the critical value of 1.0. Discrepancies of the code results are probably due to uncertainties in experiments and/or analytical modeling experiments. In general, MCNP predictions were observed to be in best agreement with the experiments.

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Spent Fuel Voloxidation Process Analysis (사용후핵연료 Voloxidation 공정 분석)

  • Kang, Jo Hong;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.4 no.2
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    • pp.47-50
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    • 2014
  • Voloxidation is a process for converting $UO_2$ into $U_3O_8$ while removing some volatile products in spent fuels (SF). Various oxidative gas conditions including air and mixture of Ar and $O_2$ could be adopted for the process. The gas flows into a reactor under high temperature ($>500^{\circ}C$) and components of SF are reacted with the gas. SF is composed of various components such as actinides, lanthanides, and alkali metals. Therefore, it is of significance to understand their behavior during the reactions for process development. However, due to the limit of available experiments, phase diagram analysis should be preceded. TPP diagram is constructed with respect to temperature-pressure-pressure. It shows a stable phase depending on partial pressures of gas components as well as temperature. In this work, we investigated TPP diagrams for actinides, lanthanides and other oxides to determine stable oxide forms under different gas conditions. The results would be used to set up a material balance under a pyroprocessing scheme of SF and compare the gas conditions for the optimization of fission products removal.

Uranium tetrafluoride production at pilot scale using a mercury electrode cell

  • Dides, Munir;Hernandez, Jose;Olivares, Luis
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1909-1913
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    • 2022
  • This work shows the technical feasibility to obtain uranium tetrafluoride through an electrochemical mercury cell. This technique represents a custom scaling-up methodology from our previous studies to obtain UF4 using the dropping mercury electrode cell. The UF4 products were obtained from natural UF6 gas, which was hydrolyzed to obtain a 50 g/L UO2F2 solution. The electrolysis cell was made using a mercury reservoir, to reach UF4 production rates of 1 Kg UF4/day. This custom design allowed a stable UF4 production thanks to the mercury cathode, which do not permit the accumulation of solid products in its surface. The cell was tested using current densities from 5.000 to 17.500 A/m2 and temperatures from 25 to 65 ℃. The maximum current efficiency achieved under these conditions was 80%. The UF4 powders possessed spherical morphology, with diameters between 20 and 80 ㎛. Compared to the SnCl2 precipitation, this process did not allow preferential growth of the precipitates. This improved the compaction of the UF4 - Mg powders mixtures, with densities between 3.0 and 3.5 g/cm3. The purity of the UF4 products was over 98%.

Symmetric dimethylarginine correlates with the urea, creatinine, potassium, and clinical scores in feline urethral obstructions

  • Jessica Cavalcante da Nobrega;Heloise Rangel Dinallo;Silvano Salgueiro Geraldes;Maria Gabriela Picelli de Azevedo;Reiner Silveira de Moraes;Suellen Rodrigues Maia;Fabiana Ferreira de Souza;Alessandra Melchert ;Henry David Mogollon Garcia;Raphael Lucio Andreatti Filho;Adriano Sakai Okamoto;Priscylla Tatiana Chalfun Guimaraes Okamoto
    • Journal of Veterinary Science
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    • v.25 no.2
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    • pp.27.1-27.12
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    • 2024
  • Background: A urethral obstruction (UO) is an emergency commonly observed in male cats, which can result in significant clinical and laboratory alterations, leading to complications and death. Objectives: This study aimed to correlate symmetric dimethylarginine (SDMA) with the urea, creatinine, potassium, and bicarbonate levels in cats with UO. In addition, the correlation between clinical score and time of obstruction was evaluated. Methods: Thirty male cats were selected and allocated into a control group (CG, n = 13) and an obstruction group (OG, n = 17). The laboratory analyses were conducted before treatment (M0) and at different times after treatment (12 h [M12], 24 h [M24], and 48 h [M48]). Correlations were established between SDMA and creatinine, urea, bicarbonate, potassium, time of obstruction, and the clinical score. Results: A strong correlation (r > 0.6) was observed between SDMA and creatinine, urea, and potassium in the OG. Furthermore, there was substantial agreement (kappa value) between SDMA and creatinine at M24. A higher clinical score was associated with a longer time of obstruction. In the OG, at M48, the SDMA and creatinine levels were 50% and 41.2% higher, respectively. Conclusions: A correlation was observed between SDMA and creatinine in obstructed cats, and significant agreement between these values was observed 24 h after the unblocking treatment. A correlation among SDMA, urea, and potassium was observed. Approximately 9% more cats continued to have elevated SDMA levels after 48 h of treatment compared to creatinine. This suggests a slightly lower sensitivity of the latter biomarker but does not exclude the possibility of congruent and normalized values after a longer evaluation period.

DISCUSSION ABOUT HBS TRANSFORMATION IN HIGH BURN-UP FUELS

  • Baron, Daniel;Kinoshita, Motoyasu;Thevenin, Philippe;Largenton, Rodrigue
    • Nuclear Engineering and Technology
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    • v.41 no.2
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    • pp.199-214
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    • 2009
  • High burn-up transformation process in low temperature nuclear fuel oxides material was observed in the early sixties in LWR $UO_2$ fuels, but not studied in depth. Increasing progressively the fuel discharge burn-up in PWR power plants, this material transformation was again observed in 1985 and identified as an important process to be accounted for in the fuel simulations due to its expected consequence on fuel heat transfer and therefore on the fission gas release. Fission gas release was one of the major concerns in PWR fuels, mainly during transient or accidents events. The behaviour of such a material in case of rod failure was also an important aspect to analyse. Therefore several national and international programs were launched during the last 25 years to understand the mechanisms leading to the high burn-up structure formation and to evaluate the physical properties of the final material. A large observations database has been acquired, using the more sophisticated techniques available in hot cells. This large database is discussed in this paper, providing basis to build an engineering-model, which is based on phenomenological description data and information accumulated. In addition this paper has the ambition to construct the best logical model to understand restructuring.

Oxidation Behavior of U-0.75 wt% Ti Chips in Air at 250-50$0^{\circ}C$

  • Kang, Kweon-Ho;Shin, Hyun-Kyoo;Kim, Chul;Park, Young-Moo
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.193-197
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    • 1996
  • A study was conducted on the oxidation behavior of U-0.75 wt% Ti chips (Depleted Uranium, DU chips) using an XRD and a thermogravimetric analyzer in the temperature range from 250 to 500$^{\circ}C$ in air. At the temperature lower than 400$^{\circ}C$, DU chips were converted to UO$_2$, U$_3$O$\_$7/, and U$_3$O$\_$8/ whereas at the temperature higher than 400$^{\circ}C$, DU chips were completely converted to U$_3$O$\_$8/, the most stable form of uranium oxide. The activation energy for the oxidation of DU chips is found, 44.9 kJ/mol and the oxidation rate in terms of weight gain (%) can be expressed as; dW/dt8.4${\times}$10$^2$e(equation omitted) wt%/min (250$\leq$T($^{\circ}C$) $\leq$ 500) where W=weight gain (%), t=time and T=temperature.

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