• Title/Summary/Keyword: UF resin

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Preparation of Si-SiC Composites by Si-Infiltration (Si 침윤에 의한 Si-SiC 복합체 제조)

  • 김인술;장주민;오기동;박홍채
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.750-756
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    • 1992
  • Reaction bonded si-SiC composites were prepared by silicon infiltration technique at temperature of 1$600^{\circ}C$ for 30 minutes in vaccum atmosphere. The microstructure and mechanical properties of Si-SiC composites were investigated and characterized. UF-15 and SE-10 as SiC powders, phenolic resin and carbon black as carbon source, and metallic silicon powder as molten Si source were used as starting materials. New SiC crystallines nucleatd and grown by reaction of Si and C were detected by TEM and SEM-EDS. The bonding between new and original SiC was found to be strong. But the wetting of SiC by unreacted metallic Si and the rapid grain growth of new SiC decreased density and fracture toughness. Fracture toughness and modulus of rupture of Si-SiC composite were about 3.2 MPa.m1/2 and 480 MPa, respectively.

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A STUDY ON TOOTHBRUSH ABRASION OF CERVICAL RESTORATIVE MATERIALS (치경부 심미수복재의 잇솔질 마모에 관한 연구)

  • Baik, Byeong-Ju;Yang, Jeong-Sook;Lee, Doo-Cheol;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.1
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    • pp.118-128
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    • 2001
  • This study was performed to evaluate the toothbrush abrasion characteristics of seven commercially available light-cured cervical restorative materials one resin-modified glass-ionomer material(Fuji II LC) three polyacid-modified composites(Compoglass, Dyract, F2000), and three light-cured composites(Heliomolar, Palpique Estelite, UniFil F). All samples were stored in distilled water at $37^{\circ}C$ for 10 days. 2.0N of weight was loaded during the test and the abraded surfaces were examined with profilometer and SEM after 100,000 cycles. The results obtained were summarized as follows; 1. The highest hardness value of 79.7 was observed in the FT group and the lowest value of 20.0 was observed in the HM group. Results of Tukey test showed that an overall significant difference was indicated except the CG and DR groups(p<0.05). 2. The highest surface roughness was observed in the FL group and the lowest was observed in the UF group. Results of Tukey test showed the significant difference between the FL or FT and UF groups(p<0.05). 3. Statistically higher abrasion and surface roughness were observed for the dentifrice of paste type, Perio A+, than for that of gel paste type, Tom & Jerry. 4. The surface roughness values increased on the abraded surfaces because of the protrusion of filler particles due to selective removal of matrix resin.

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A Study on Plywood Glue Extender from Bark and Particle Board Sander Dust (수피(樹皮) 및 파티클보드 폐기분말(廢棄粉末)을 이용(利用)한 합판(合板)의 증량(增量)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.1
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    • pp.12-17
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    • 1983
  • The shear strength of plywoods using Douglus-fir bark powder and particlebard sander dust(PSD), abandoned materials in plywood and particleboard industries, as extender to UF resin, was compared with that of plywoods using wheat flour. Extenders were mixed at the rate of 0%, 5%, 10%, 20%, and 30% of UF resin weight. In obtained results, the dry shear strength of all extended plywoods was highest at extending ratio 5% and the wet shear strength was highest at no extending and 5%. Douglas-fir bark powder-and PSD-extended plywoods had as high dry and wet shear strength as wheat flour-extended plywoods up to extending ratio 10% and 20% respectively. But at 300%, wheat flour-extended plywoods had higher shear strength. Douglas-fir bark powder and PSD size should have been reduced (enough to pass through 325 mesh screen) in order to develop the satisfactory mixing, spreading and plywood bond quality. But in this study the powders to pass through 100 mesh screen were used.

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A Study on the Taro Extension of UF and PF Resin Bonding Plywoods (요소(尿素) 및 석탄산수지(石炭酸樹脂) 합판(合板)의 토란증량(土卵增量)에 관(關)한 연구(硏究))

  • Lee, Phil Woo;Bae, Young Soo
    • Journal of Korean Society of Forest Science
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    • v.57 no.1
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    • pp.32-38
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    • 1982
  • This study was carried out to examine the possibility to replace imported wheat flour with taro. Taro and wheat flour were used for the extenders after oven drying($100{\pm}3^{\circ}C$)and pulverized into 80-100mesh minute powder by laboratory willey mill. Urea- and phenol-formaldehyde resin adhesives were used for plywood manufacture, and the extending materials mixed with the extension at the ratio of 10, 20, 30, and 50% to each resin solution. The results obtained at this study were summarized as follows; 1) In dry and wet shear strength of urea-formaldehyde resin adhesive, taro showed very excellent bonding strength compared with wheat flour in all extending ratio. Therefore taro showed the possibility that be usable to taro in place of wheat flour. 2) In dry and wet shear strength of phenol-formaldehyde resin adhesive, in general, wheat flour showed higher bonding strength than taro. But in dry shear strength, taro showed higher shear strength than wheat flour in 30 and 50% extension.

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An Effect of Aging and Thermocycling on the Tensile Strength of Restorative Composite Resins (시효와 열순환 처리가 수복용 복합레진의 인장강도에 미치는 영향)

  • Lee, Mi-Jeong;Yu, Mi-Kyung;Lee, Kwang-Won
    • Journal of Dental Rehabilitation and Applied Science
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    • v.21 no.1
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    • pp.15-23
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    • 2005
  • The purpose of this study was to evaluate effect of aging and thermocycling on the tensile strength of restorative composite resins. Eight commercially available light-cured restorative composites (Heliomolar: HM, Palfique Estelite: PE, Spectrum: ST, UniFil-F: UF, Z100: ZH, Clearfil AP-X: CA, P60: PS, and Palfique Toughwell: PT) were selected as experimental materials. Rectangular-shaped tensile test specimens were fabricated in a teflon mold giving 5 mm in gauge length and 2 mm in thickness. All samples were stored in distilled water at $37^{\circ}C$ for 100 days. Every 10 days, specimens were thermocycled for 1,000 cycles with 15 seconds of dwelling time in each $5^{\circ}C$ and $55^{\circ}C$ water baths. Tensile testing was carried out at a crosshead speed of 0.5 mm/min and fracture surfaces were observed with a scanning electron microscope. The results obtained were summarized as follows; 1. The strength degradation of thermocycled group was severer than that of the aged group (P<0.01). 2. The tensile strength of the CA and ST groups were significantly higher than that of other groups after thermocycling treatment (P<0.05). 3. Fracture surfaces showed that the composite resin failure developed along the matrix and the filler/resin interface region.

Environmental Assessments of Leachate from Medium Density Fiberboard in a Simulated Landfill

  • Lee, Min;Prewitt, Lynn;Mun, Sung Phil
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.548-557
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    • 2015
  • This study investigated environmental assessments of leachate containing formaldehyde from medium density fiberboard (MDF) disposed in laboratory-scale simulated landfills. Environmental impact assessment of leachate was conducted by measuring formaldehyde, toxicity, biochemical oxygen demand (BOD), chemical oxygen demand (COD), bacterial enumeration, and pH. Amount of formaldehyde in leachate from MDF in soil decreased to the level of soil only treatment by 28 days, and toxicity decreased as the amount of formaldehyde decreased. BOD and COD levels in leachate from the treatments containing MDF exceeded permissible discharge levels of BOD or COD throughout the experimental period. The pH levels of all treatment were within permissible discharge range except on day 0. Fewer bacteria were observed in leachate from MDF in soil treatment than other treatments (MDF only, cured UF resin in soil, and soil only). Consequently, the leachate from disposal of MDF in soil detrimentally affect on environment. However, soil buffered formaldehyde leaching and pH on leachate in this study. Waste MDF may be required the pre-water soaking treatment for leaching formaldehyde to reclaim on land.

Effect of Particle Pre-Treatment on Properties of Jatropha Fruit Hulls Particleboard

  • Iswanto, Apri Heri;Febrianto, Fauzi;Hadi, Yusuf Sudo;Ruhendi, Surdiding;Hermawan, Dede;Fatriasari, Widya
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.2
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    • pp.155-165
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    • 2018
  • The objective of the research was to evaluate the effect of particle pre-treatment on physical, mechanical, and durability of jatropha fruit hulls (JFH) particleboard. The pre-treatments included were immersing in cold water, hot water, and acetic acid solution. After each treatment, the particles were dried up to 3% moisture content. Urea-formaldehyde (UF) resin was used to fabricate particleboards with board size, thickness and density target of 25 cm by 25 cm, 0.80 cm, and $0.70g/cm^3$, respectively. Board pressed at $130^{\circ}C$ for 10 minutes, and $25kg/cm^2$ pressure. The evaluation of particleboard followed the JIS A 5908-2003. Whilist their resistance to subterranean termite test (mass loss, mortality, antifeedant value and feeding rate) refers to the Indonesian standard (SNI 01.7207-2006). The physical and mechanical properties of particleboards showed that all pre-treatments decreased the pH of particles. Overall, all particle immersing treatments resulted of better physical and mechanical properties of particleboard than those of untreated ones. The acetic acid treatment resulted the best physical and mechanical properties of particleboard. Based on the mass loss of JFH particleboard, hot water and acetic acid treated particleboards were classified into weak resistance to subterranean attack. The other two treatments were classified into very weak resistance. Hot water treated particleboard provided the highest mortality and antifeedant as much as 87.40% and 34.20%, respectively. Based on antifeedant classification, hot water treated particleboards were classified into moderately strong resistance, while other treatments were categorized into weak resistance. The lowest feeding rate value ($45.30{\mu}g/termite/day$) was attained by hot water treatment.

Physico-mechanical Properties and Formaldehyde/TVOC Emission of Particleboards with Volcanic Pozzolan

  • Kim, Sumin;An, Jae-Yoon;Kim, Jin-A;Kim, Hee-Soo;Kim, Hyun-Joong;Kim, Hak-Gyeom
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.2
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    • pp.39-50
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    • 2007
  • The purpose of this study was to investigate the physico-mechanical properties and characteristics on reduction of formaldehyde and total volatile organic compound (TVOC) emission from particleboard (PB) with added volcanic pozzolan. Pozzolan was added as a scavenger at the level of 1, 3, 5, and 10 wt.% of urea formaldehyde (UF) resin for PB manufacture. The moisture content, density, thickness swelling, water absorption and physical properties of PBs were examined. Three-point bending strength and internal bond strength were determined using a universal testing machine. Formaldehyde and TVOC were determined by desiccator and 20L small chamber methods. With increasing pozzolan content the physical and mechanical properties of the PBs were not significantly changed, but formaldehyde and TVOC emissions were decreased. Because pozzolan has a rough and irregular surface with porous form, it can be used as a scavenger for PBs at a content up to 10 wt.% without any detrimental effect on the physical and mechanical properties.

Study on the Physical and Mechanical Properties of Particleboard and Oriented Strandboard Manufactured by Tulliptree (Liriodendron tulipifera L.) (백합나무를 이용하여 제조한 3층 파티클보드와 배향성 스트랜드보드(OSB)의 물성에 관한 연구)

  • Seo, Jun won;Gang, Gil woo;Jo, Gun hee;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.1
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    • pp.67-72
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    • 2018
  • This study was conducted to investigate a potential of Yellow poplar (Liriodendron tulipifera L.) as a raw material for the manufacturing of particleboard (PB) and oriented strandboard (OSB). PB panels were prepared at the parameters of $0.7g/cm^3$ density, 15 mm thickness, three-layer, $E_1$ grade urea-formaldehyde (UF) resin, emulsion wax, and hardener. OSB panels were manufactured with a density of $0.65g/cm^3$, thickness of 10 mm, and $E_1$ grade of UF resin. Particle size of the face layer of PB was 20~80 mesh with 7~9% moisture content (MC), while that of core-layer was 3~20 mesh with 3~5% MC, which was similar to the production condition of commercial PB. As a result, the manufactured PB panels with 15.8 mm thickness, $0.7g/cm^3$ density, and 5.8% MC satisfied the requirement of bending strength of 15 type PB of Korean Industrial Standard (KS F 3104). Both internal bonding (IB) strength and surface screw withdrawal resistance also satisfied the requirement of 18 type PB of the standard. But, the edge screw withdrawal resistance satisfied the requirement of 15 type PB of the standard. These differences in properties could be due to the slenderness ratio of raw particles. In case of OSB panels with 10.7 mm thickness, $0.68g/cm^3$ density, and 5.8% MC satisfied all the requirements of bending strength, screw withdrawal resistance, and IB strength of 18 type PB of the standard. These results suggest that Yellow poplar wood has a good potential as a raw material for the production of PB and OSB.

A STUDY ON THE GALVANIC CORROSION OF TITANIUM USING THE IMMERSION AND ELECTROCHEMICAL METHOD (침적법과 전기화학법을 이용한 티타늄의 갈바닉 부식에 관한 연구)

  • Kay, Kee-Sung;Chung, Chae-Heon;Kang, Dong-Wan;Kim, Byeong-Ok;Hwang, Ho-Gil;Ko, Yeong-Mu
    • The Journal of Korean Academy of Prosthodontics
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    • v.33 no.3
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    • pp.584-609
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    • 1995
  • The purpose of this study was to evaluate the difference of the galvanic corrosion behaviour of the titanium in contact with gold alloy, silva-palladium alloy, and nickel-chromium alloy using the immersion and electrochemical method. And the effects of galvallit couples between titanium and the dental alloys were assessed for their usefulness as materials for superstructure. The immersion method was performed by measuring the amount of metal elementsreleased by Inductivey coupled plasma emission spectroscopy(ICPES) The specimen of fifteen titanium plates, the five gold alloy, five silver-palladium, five nickel-chromium plates, and twenty acrylic resin plates ware fabricated, and also the specimen of sixty titanium plugs, the thirty gold alloy, thirty silver-palladium, and nickelc-hromium plugs were made. Thereafter, each plug of gold alloy, silver-palladium, and nickel-chromium inserted into the the titanium and acrylic resin plate, and also titanium plug inserted into the acrylic resin plate. The combination specimens uf galvanic couples immersed in 70m1 artificial saliva solution, and also specimens of four type alloy(that is, titanium, gold, silver-palladium and nickel-chromium alloy) plugs were immersed solely in 70m1 artificial sativa solution. The amount of metal elements released was observed during 21 weeks in the interval of each seven week. The electrochemical method was performed using computer-controlled potentiosta(Autostat 251. Sycopel Sicentific Ltd., U.K). The wax patterns(diameter 11.0mm, thickness,in 1.5mm) of four dental casting alloys were casted by centrifugal method and embedded in self-curing acrylic resin to be about $1.0cm^2$ of exposed surface area. Embedded specimens were polished with silicone carbide paper to #2,000, and ultrasonically cleaned. The working electrode is the specimen of four dental casting alloys, the reference electrode is a saturated calmel electrode(SCE) and the ounter electrode is made of platinum plate. In the artificial saliva solution, the potential scanning was carried out starting from-700mV(SCE) TO +1,000mV(SCE) and the scan rate was 75mV/min. Each polarization curve of alloy was recorded automatically on a logrithmic graphic paper by XY recorder. From the polarization curves of each galvanic couple, corrosion potential and corrosion rates, that is, corrosion density were compared and order of corrosion tendency was determined. From the experiments, the following results were obtained : 1. In the case of immersing titanium, gold alloy, silver-palladium alloy, and nickel-chromium alloysolely in the artificial saliva solution(group 1, 2, 3, and 4), the total amount of metal elements released was that group 4 was greater about 2, 3 times than group 3, and about 7.8 times than group 2. In the case of group 1, the amount of titanium released was not found after 8 week(p<0.001). 2. In the case of galvanic couples of titanium in contact with alloy(group 5, 6), the total amount of metal elements released of group 5 and 6 was less than that of group 7, 8, 9, and 10(p<0.05). 3. In the case of galvanic couples of titanium in contact with silver-palladium alloy(group 7, 8), the total amount of metal elements released of group 7 was greater about twice than that of group 5, and that of group 8 was about 14 times than that of group 6(p<0.05). 4. In the case of galvanic couples of titanium in contact with nickel-chromium alloy(group 9, 10), the total amount of metal elements released of group 9 and 10 was greater about 1.8-3.2 times than that of group 7 and 8, and was greater about 4.3~25 times than that of group 5 and 6(p<0.05). 5. In the effect of galvanic corrosion according to the difference of the area ratio of cathode and anode, the total amount of metal elements released was that group 5 was greater about 4 times than group 6, group 8 was greater about twice than group 7, and group 10 was greater about 1.5 times than group 9(p<0.05). 6. In the effect of galvanic corrosion according to the elasped time during 21 week in the interval of each 7 week, the amount of metal elements released was decreased markedly in the case of galvanic couples of the titanium in contact with gold alloy and silver-palladium alloy but the total amount of nickel and beryllium released was not decreased markedly in the case of galvanic couples of the titanium in contact with nickel-chromium alloy(p<0.05). 7. In the case of galvanic couples of titanium in contact with gold alloy, galvanic current was lower than any other galvanic couple. 8. In the case of galvanic couples of titanium in contact with nickel-chromium alloy, galvanic current was highest among other galvanic couples.

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