• Title/Summary/Keyword: U-plot

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Determination of Free Acid in U(VI)-Al(III) Solutions by Gran Plot Titration (Gran Plot 적정법을 이용한 U(VI)-AI(III) 용액의 자유산 농도 측정)

  • Suh, Moo-Yul;Lee, Chang-Heon;Sohn, Se-Chul;Kim, Jung-Suk;Kim, Won-Ho;Eom, Tae-Yoon
    • Analytical Science and Technology
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    • v.12 no.3
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    • pp.177-183
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    • 1999
  • The determination method of free acid in spent U-Al nuclear fuel solutions by Gran plot titration was described. Effect of U(VI) and Al(III) on the alkalimetric titration of nitric acid was investigated in oxalate complexing media as well as in noncomplexing media. Positive biases were observed in both titration media when the end-point was estimated by the Gran plot method. It was found that the cause of the bias was U(VI) in the oxalate complexing media, but Al(III) in the noncomplexing media. The relative error was less than 1% in the titration of 0.1 M $HNO_3$ at a U(VI) : Al(III) : $H^+$ mole ratio of up to 2:12:1 as long as the pH of the oxalate titration media was sustained to be below 5.0 at the beginning of titration. The method was successfully applied to the determination of nitric acid in a solution of HANARO reactor fuel with U:Al mole ratio of 1:6.

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The Effect of Gibberellin, Urea and Sucrose on Growth and Some Nutrients in Soybean Sprout (콩나물의 성장(成長) 및 성분(成分)에 미치는 Gibberellin, Urea 및 Sucrose의 영향(影響))

  • Kim, Dong-Yeon
    • Applied Biological Chemistry
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    • v.4
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    • pp.29-32
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    • 1963
  • The Gibberellin is applied to partial fruit trees, vegetables and flowers, but there is only a few information on the components of the effect of Gibberellin on these higher plants. There is no any information on the effect of Gibberellin, Urea and Sucrose mixed liquid on the plant components. So this mixed liquid and gibberellin spraied to the soybean sprout and observed growth velocity variety of some nutrients. Growth velocity, weight, Amino acid contents and fat contents of mixed plot and gibberellin plot are almost same. Mixed liquid plot's sugars and crude proteins contents in a little much than gibberellin plot, but mixed liquid plot's Ascorbic acid contents is a little less than gibberellin plot.

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Effect of Soil Conditioner and Loess on Physio-Chemical Properties of Dredged Soil and Seedling Height Growth of Ulmus davidiana var. japonica (토양개량재와 황토가 준설토의 이화학성과 느릅나무의 초기 생장에 미치는 영향)

  • Lee, Hanna;Park, Chanwoo;Lim, Joo-Hoon;Koo, Namin;Lee, Im Kyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.18 no.3
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    • pp.1-11
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    • 2015
  • This research was conducted to compare the effect of soil amendment and loess on physial and chemical properties of dredged soil and primary height growth of Ulmus davidiana var. japonica. Three types of research plots: control plot (Dredged soil only), DC treatment plot (Dredged soil + soil amendment) and DCL treatment plot (Dredged soil + soil amendment + Loess) were set at Okgu research site in Saemanguem. 32 trees of U. davidiana var. japonica were planted in each plots after 14 months from the construction. Soil texture, pH, electrical conductivity (EC), organic matter (OM), total nitrogen (TN), available P, exchangeable cation ($K^+$, $Na^+$, $Mg^{2+}$, $Ca^{2+}$) and sodium chloride were measured after 3 years from the construction. Also, survival rate and height of U. davidiana var. japonica were measured 22 months after planting, and the correlation between height of trees and the physico-chemical properties of soil were analyzed. Even though pH in both DC and DCL treatment plots are lower than control plot, they are still alkaline (> pH 8). OM, TN and available P in both DC and DCL treatment were higher than the control. Particularly, the content of available P in both DC and DCL treatment plots are 1.4~5.1 times and 2.0~3.1 times higher than the control respectively. The concentration of exchangeable Mg in DCL treatment plot was 1.1~5.5 times higher than the control (p < .05). The survival rate of the species was the highest in DCL treatment plot (98%) followed by DC treatment plot and the control. The average height of the trees in both DC and DCL treatment plots is 1.1m while the control is 0.8m. OM, TN, available P, K+ were significantly related to the height of U. davidiana var. japonica(p < .01). The results indicate that soil amendment affects on soil physial and chemical properties of dredged soil and height growth of U. davidiana var. japonica.

A Study on the Alkalimetric Titration with Gran Plot in Noncomplexing Media for the Determination of Free Acid in Spent Fuel Solutions

  • 서무열;이창헌;손세철;김정숙;엄태윤
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.59-64
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    • 1999
  • Based on the study of hydrolysis behaviour of U(Ⅵ) ion and major fission product metal ions such as Cs(Ⅰ), Ce(Ⅲ), Nd(Ⅲ), Mo(Ⅵ), Ru(Ⅱ), and ZR(Ⅳ) in the titration media, the performance of noncomplexing-alkalimetric titration method for the determination of free acid in the presence of these metal ions was investigated and its results were compared to those from the completing methods. The free acidities could be determined as low as 0.05 meq in uranium solutions in which the molar ratio of U(Ⅵ)/H+ was less than 5, when the end-point of titration was estimated by Gran plot. The biases in the determinations were less than 1% and about +3% respectively for 0.4 meq and 0.05 meq of free acid at the U(Vl)/H+ molar ratio of up to 5. Applicability of this method to the determination of free acid in spent fuel solutions was confirmed by the analysis of nitric acid content in simulated spent fuel solutions and in a real spent fuel solution.

Kinetics on the Specificity of Enzymatic Hydrolysis of Chitin (Chitin의 효소적 가수분해 특성에 대한 속도론적 연구)

  • Lee, Eun-Young;Kim, Kwang
    • KSBB Journal
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    • v.13 no.1
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    • pp.44-51
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    • 1998
  • Hydrolysis and adsorption reversibility experiments were run for initial enzyme activity of 4.48, 9.65, 11.19 and 17.14U/mL at a temperature 30$^\circ C$. The chitin particle size corresponded to a mean particle diameter of 0.127mm, and the initial concentration of chitin was 10mg/mL. After approximately 2hrs, the enzyme activity remained constant in a speudo-steady state. The amounts in the bulk [E] and the amounts of enzyme adsorbed on the chitin surface [E] are plotted on Lineweaver-Burk plot to yield a linear relationship with a correlation coefficient of 0.99, a slope of 2.79cm$^-1$ and an intercept of 0.08$\textrm{cm}^2$/U. From this parameters, the values of [E$_T$] and $K_E$ were calculated to be 12.5U/cm$^2$ and 34.88U/mL. respectively, Adsorption isotherm of the enzyme on the particles showed a well developed plateau of 1.35$\times$10$^-3$, 4.72$\times$10$^-3$, 4.42$\times$10$^-3$, 8.58$\times$10$^-3$U/cm$^2$ at 30$^\circ C$. To determine the specificity of chitinase for crystalline chitin, the free energy of adsorption was measured, and its was determined as about -14.62~-18.8kJ/mol.

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The National Forest Inventory of the United States of America

  • McRoberts, Ronald E.
    • Journal of Forest and Environmental Science
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    • v.24 no.3
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    • pp.127-135
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    • 2008
  • The mission of the Forest Inventory and Analyis (FIA) program of the Forest Service, U.S. Department of Agriculture, is to conduct the national forest inventory of the United States of America for purposes of estimating the area of forest land; the volume, growth, and removal of forest resources; and the health of the forest. Users of FIA data, estimates, and related products include land managers, policy and decision-makers, forest industry, environmental organizations, and university researchers. To accomplish its mission, the FIA program has established a sampling design with an intensity of approximately one permanent plot per 2,400 ha across the entire country. Depending on the region of the country, each plot is remeasured at intervals of five or 10 years. The program releases data annually and reports estimates at the county level for each state every five years. Due to budgetary constraints and natural variability among plot observations, sufficient numbers of plots cannot be measured to satisfy precision guidelines for the estimates of many variables unless the estimation process is enhanced using ancillary data. Classified satellite imagery has been demonstrated to be a source of ancillary data that can be used with stratified estimation techniques to increase the precision of estimates with little corresponding increase in costs. A crucial factor restricting the utility of FIA data is that the exact locations of inventory plots cannot be released to the public. Thus, users are generally not able to obtain estimates for small areas or for their own areas of interest if exact plot locations are required. To compensate, satellite imagery, inventory plot data, and the k-Nearest Neighbors technique are being used to construct Internet-based maps of forest attributes from which estimates for arbitrary user-defined areas of interest may be obtained.

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Two model comparisons of software reliability analysis for Burr type XII distribution

  • An, Jeong-Hyang
    • Journal of the Korean Data and Information Science Society
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    • v.23 no.4
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    • pp.815-823
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    • 2012
  • In this paper reliability growth model in which the operating time between successive failure is a continuous random variable is proposed. This model is for Burr type XII distribution with two parameters which is discussed in two versions: the order statistics and non-homogeneous Poisson process. The two software reliability measures are obtained. The performance for two versions of the suggested model is tested on real data set by U-plot and Y-plot using Kolmogorov distance.

Fatigue crack growth and crack closure in 2017-T3 Aluminum alloy (2017 - T 3 알미늄 合金 의 勞龜裂進展 과 龜裂닫힘現象)

  • 송지호;김일현;신용승
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.4 no.2
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    • pp.47-53
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    • 1980
  • Kikukawa-Compliance method using a conventional clip-on gauge was employed to investigate fatigue crack growth and crack closure in 2017-T3 aluminum alloy. The crack growth rate plot against stress intensity range .DELTA.K on a log-log diagram exhibits a bilinear form with a transition at the growth rate of 10$\^$-4/ mm/cycle. The bilinear form appears still in the plot of growth rate versus effective stress intensity range .DELTA.K$\_$eff/. Fatigue crack growth rate could be well represented by .DELTA.K$\_$eff. The experimental results indicate that the effective stress intensity range ratio U depends on the maximum stress intensity factor K$\_$max/, but the stress ratio R does not affect U. The crack opening stress intensity factor K$\_$op/ tends to increase with increasing K$\_$max/ and decrease with increasing .DELTA.K.

Software Reliability for Order Statistic of Burr XII Distribution

  • Lee, Jae-Un;Yoon, Sang-Chul
    • Journal of the Korean Data and Information Science Society
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    • v.19 no.4
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    • pp.1361-1369
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    • 2008
  • The analysis of software reliability model provides the means to analysts, software engineers, and systems analysts and developers who want to predict, estimate, and measure failure rate of occurrences in software. In this paper, reliability growth model, in which the operating time between successive failure is a continuous random variable, is proposed. This model is based on order statistics of two parameters Burr type XII distribution. We propose the measure based on U-plot. Also the performance of the suggested model is tested on real data set.

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