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화학적 구조 설계를 통한 수계 Cu-In-S 잉크와 액상셀렌화 법의 개발을 통한 고효율의 CISSe 태양전지 제작

  • O, Yun-Jeong;Yang, U-Seok;Kim, Ji-Min;Mun, Ju-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.428-428
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    • 2016
  • Copper indium sulfide (selenide) (CuIn(S,Se)2,CISSe)는 1.0~1.5 eV의 Direct band gap과 105 cm-1이 넘는 큰 광 흡수 계수를 가지고 있어 박막 태양전지의 흡수층으로써 연구되어 왔다. 최근 대량생산 및 저가 공정에 용이하다는 측면에서 용액 공정 기반 CISSe 태양전지 연구가 크게 주목 받고 있다. 용액공정 기반 중 하이드라진을 사용 한 경우 매우 높은 효율을 기록하였으나, 하이드라진 자체의 유독성과 폭발성 때문에 분위기 제어가 필요하고 여전히 저가화 및 대면적 제작에 한계가 있다. 따라서 알코올 솔젤 기반 CISSe 태양전지 제작 연구가 많이 진행되었으나, 결정립 성장 및 칼코겐 원자를 공급하기 위해 불가피하게 황화/셀렌화 후속 열처리 공정을 요구한다. 후속 열처리 공정은 폭발성의 황화수소/황화셀레늄 기체 분위기 제어와 고가의 장비를 필요로 한다. 본 연구에서는 매우 안정적이며 저가 용매인 물과 아민계 첨가제를 이용하여 Cu, In 전구체와 S, Se 이 포함된 Cu-In-S 잉크와 Se잉크를 제작하였다. 잉크 내에 S, Se을 첨가 함으로써 추가적인 후속공정 없이 비활성 가스 분위기에서 고품질의 CISSe 박막 제작을 가능케 하였다. 또한 Se 잉크 증착 횟수에 따른 결정 구조, 광학적 성질의 차이에 주목하였다. 따라서 수계 잉크를 대기 중에서 스핀코팅으로 박막을 제작한 후, Hot plate에서 건조하여 균일한 박막을 제조하고, 제작된 박막을 tube furnace에서 환원 분위기 및 비활성 가스 분위기에서 열처리 진행하여 $1.3{\mu}m$ 두께의 고품질의 CISSe 흡수층을 제작하였다. 이러한 흡수층에 대해 XRD, SEM, EDS 분석을 진행하여, 결정성, 미세구조, 및 조성을 확인하였으며, 제작된 흡수층 위에 버퍼층/투명전극층을 차례로 증착하여 CISSe 태양전지를 제작하여 셀 성능 및 양자 효율 특성을 파악하였다. 또한 액상 Raman 분석을 통해 결정립 성장 과정 메커니즘을 제시하였다.

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Experimental Study on Regenerator Under Cryogenic Temperature and Pulsating Pressure Conditions (극저온 맥동 압력 조건에서의 재생기에 관한 실험적 연구)

  • Nam, Gwan-U;Jeong, Sang-Gwon;Jeong, Eun-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.8
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    • pp.1095-1101
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    • 2002
  • An experimental apparatus was prepared to investigate thermal and hydrodynamic characteristics of regenerator at cryogenic temperature under pulsating pressure condition. The regenerator was pressurized and depressurized by a compressor with various operating frequencies. Cold end of the regenerator was maintained around 100 K by means of a liquid nitrogen heat exchanger. Instantaneous gas temperature and mass flow rate were measured at both ends of the regenerator during the whole pressure cycle. Pulsating pressure drop across the regenerator was also measured to see if it could be predicted by a friction factor at steady flow condition. The operating frequency of pressure cycle was varied between 3 and 60 Hz, which are typical operating frequencies of Gifford-McMahon, pulse tube, and Stilting cryocoolers. First, the measured friction factor for typical wire screen mesh regenerator was nearly same as steady flow friction factor for maximum oscillating Reynolds number up to 100 at less than 9 Hz. For 60 Hz operations, however, the discrepancy between oscillating flow friction factor and steady flow one was noticeable if Reynolds number was higher than 50. Second, the ineffectiveness of regenerator was directly calculated from experimental data when the cold-end was maintained around 100 K and the warm-end around 293 K, which simulates an actual operating condition of cryogenic regenerator. Influence of the operating frequency on ineffectiveness was discussed at low frequency range.

Influence of Repeated Loading, Alternation of Temperature and Initial Condition on the Change of Strizctural and Mechanical Characteristics of Alluvial Clayey Soil (반복하중,온도변화 및 초기조건이 충적점토의 구조변화와 역학적 특성에 미치는 영향)

  • 유능구;유영선;최중대;김기성
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.34 no.4
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    • pp.69-79
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    • 1992
  • To estimate soil behavior and structural characteristics under the conditions of cyclic loading, freezing & thawing and initial state, several testing was performed and obtained following results. 1.After repeated freezing and thawing processes, original soil structure was destroyed and changed to globular structure from honeycomb or tube in its structure types. Also above processes resulted increasing the soil compression strain while decreasing the failure stress in stress-strain relationship and reached the soil structure into the mode of brittle fracture. Under cyclic loading conditions, soil cluster which was originally dispersed structure colloided with each other, seperated, and finally the soil failed due to the effect of overcompaction. 2.Through the stabilization processes seperated by four steps, the structure of soil skeleton was changed to quite different globular type. The degree of compressibility of soil was decreased in the normally consolidated zone, while the strength against external load increased due to soil particle stabilization. 3.Soil stress-strain chracteristics were largely influenced by repeated up and down processes of temperature. The maximum deformation was obtained in the case of temperature between 0 10˚C by the reseon of particle cluster reformation. 4.Soil compressibility was largely influenced by the optimum moisture content. Under freezing process, swelling could be found and its magnitude was proportional to the density of soil. 5.Density of soil was decreased as increasing the number or repeated freezing and thawing processes and the largest decreasing rate was found at the first turning point from freezing to thawing cycle.

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Verification of SPACE Code with MSGTR-PAFS Accident Experiment (증기발생기 전열관 다중파단-피동보조급수냉각계통 사고 실험 기반 안전해석코드 SPACE 검증)

  • Nam, Kyung Ho;Kim, Tae Woo
    • Journal of the Korean Society of Safety
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    • v.35 no.4
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    • pp.84-91
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    • 2020
  • The Korean nuclear industry developed the SPACE (Safety and Performance Analysis Code for nuclear power plants) code and this code adpots two-phase flows, two-fluid, three-field models which are comprised of gas, continuous liquid and droplet fields and has a capability to simulate three-dimensional model. According to the revised law by the Nuclear Safety and Security Commission (NSSC) in Korea, the multiple failure accidents that must be considered for accident management plan of nuclear power plant was determined based on the lessons learned from the Fukushima accident. Generally, to improve the reliability of the calculation results of a safety analysis code, verification work for separate and integral effect experiments is required. In this reason, the goal of this work is to verify calculation capability of SPACE code for multiple failure accident. For this purpose, it was selected the experiment which was conducted to simulate a Multiple Steam Generator Tube Rupture(MSGTR) accident with Passive Auxiliary Feedwater System(PAFS) operation by Korea Atomic Energy Research Institute (KAERI) and focused that the comparison between the experiment results and code calculation results to verify the performance of the SPACE code. The MSGR accident has a unique feature of the penetration of the barrier between the Reactor Coolant System (RCS) and the secondary system resulting from multiple failure of steam generator U-tubes. The PAFS is one of the advanced safety features with passive cooling system to replace a conventional active auxiliary feedwater system. This system is passively capable of condensing steam generated in steam generator and feeding the condensed water to the steam generator by gravity. As the results of overall system transient response using SPACE code showed similar trends with the experimental results such as the system pressure, mass flow rate, and collapsed water level in component. In conclusion, it could be concluded that the SPACE code has sufficient capability to simulate a MSGTR accident.

Optimal Supply Scheme of Solar Hot Water Heating Systems for the Apartment Complexes (공동주택용 태양열 급탕시스템 최적공급 방안 해석연구)

  • Lee, Chul-Sung;Park, Ja-Son;Park, Jae-Wan;Shin, U-Cheul;Yoon, Jong-Ho
    • 한국태양에너지학회:학술대회논문집
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    • 2008.11a
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    • pp.245-250
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    • 2008
  • This study is on the availability of solar thermal energy in Korean high-rise apartment complex depending on the installation type of solar collectors to roof or facade of building. Firstly, solar access evaluation on the roof and the facade of apartment buildings was carried out. The total thermal load of each apartment unit and building was investigated and matched with the energy which was produced by solar thermal systems on the facade. The considered layout patterns of apartment buildings were '一type', 'alternative 一type', 'ㄱtype' and 'ㅁtype' and that was analyzed in prior studies. Extensive dynamic hourly energy simulations with the solar thermal system were Performed with the TRNSYS of SEL. We assumed that the apartment complex is composed of 9 buildings and located in Daejeon. The collectors are the heat-pip evacuated tube collectors and the number of collectors are 45 tubes We assumed that the collectors are installed on the balcony of each unit and the angle of incilnation is $90^{\circ}$. As a result, the supply amount of solar thermal systems is about 4,850,086kJ/hr and the solar fraction is about 66%. The solar fraction according to each azimuth is about 66% on the south, 62% on the south-east $30^{\circ}$ and 56% on the south-east $60^{\circ}$. So, we quantitatively got a line on the optimal azimuth for installing the solar thermal systems. The solar fraction has differences from 5% to 15% of each floor, 6th, 12th and 20th and those tendencies are same in analyzed each 4 types of the apartment complexes.

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Effects of Aprotinin on Postoperative Bleeding and Blood Coagulation System in Pediatric Open Heart Surgery (소아개심술시 아프로티닌이 술후 출혈 및 혈액응고계에 미치는 영향)

  • 신윤철;전태국
    • Journal of Chest Surgery
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    • v.29 no.3
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    • pp.303-310
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    • 1996
  • From December of 1994 to April of 1995, we, SHUH Department of Pediatric Thoracic and Cardiovascular Surgery, studied effects of aprotinin. 95 patients were randomly divided into two groups : group I (n=47) with aprotinin and group ll (n=48) without aprotinin. Aprotinin was given as one shot injection to cardiopulmonary bypass perfusion solution with dose of 50,000 KIUikg. Laboratory data such as hemoglobin, hematocrit, BUH, creatinine, fibrinogen, electrolyte concentration, aPTT, PT, and AT R was checked preoperatively, 5 minutes after anesthesia, 5 minutes and 35 minutes after CPB circulation, and 5 minutes, 3 hours, and 24 hours after reperfusion. Also, chest-tube drainage, transfused amount of RBC, platelet concentrate, and fresh frozen plasma within first 24 hours postoperatively were checked and analyzed after transition nn body weight demension. Only RBC transfused postoperatively had statistical significance with P value of less than 0.001. Others had no difference statistical wise. Postoperative side effects of aprotinin was not detected weeks after the surgery and there was no reoperated patient due to postoperative bleeding.

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The Shape and Behavior of Bubbles in the Deep Shaft System (심층포기장치(深層暴氣裝置)에 있어서 기포(氣泡)의 형태(形態)와 거동(擧動))

  • Kim, Whan Ki;Yang, Bong Yong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.9 no.4
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    • pp.135-143
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    • 1989
  • The experimental study on the shape and behavior of bubbles in U-tube deep shaft of 32m has been performed. According to the results in this paper, the equivalent spherical diameter of bubbles was 0.422-0.722cm and the shape of bubbles was almost ellipsoidal for bubbles to be generated ta single-orifice of diameter 0.06cm in the downcomer of the deep shaft system. Gas hold-up and gas-liquid contact area of bubbles in the deep shaft was decreased in accordance with depth, Also downcomer velocity of bubbles was slower than circulation velocity of liquid and riser velocity of bubbles was fast than circulation velocity. The bubble-size-distribution of bubbles in the deep shaft was the logarithmic probability distribution. The number of bubbles in the deep shaft was decreased in accordance with depth and the number of bubbles in the downcomer is more than the bubbles in the riser.

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Experimental Study of Boundary Layer Transition on an Airfoil Induced by Periodically Passing Wake (II) -A Phase-Averaged Characteristic- (주기적 후류 내의 익형 위 천이경계층에 관한 실험적 연구(II) -위상평균된 유동특성-)

  • Park, Tae-Chun;Jeon, U-Pyeong;Gang, Sin-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.6
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    • pp.786-798
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    • 2001
  • This paper describes the phenomena of wake-induced transition of the boundary layers on a NACA0012 airfoil using measured phase-averaged data. Especially, the phase-averaged wall shear stresses are reasonably evaluated using the principle of Computational Preston Tube Method. Due to the passing wake, the turbulent patch is generated in the laminar boundary layer on the airfoil and the boundary layer becomes temporarily transitional. The patches propagate downstream with less speed than free-stream velocity and merge with each other at further down stream station, and the boundary layer becomes more transitional. The generation of turbulent patch at the leading edge of the airfoil mainly depends on velocity defects and turbulent intensity profiles of passing wakes. However, the growth and merging of turbulent patches depend on local streamwise pressure gradients as well as characteristics of turbulent patches. In this transition process, the present experimental data show very similar features to the previous numerical and experimental studies. It is confirmed that the two phase-averaged mean velocity dips appear in the outer region of transitional boundary layer for each passing cycle. Relatively high values of the phase-averaged turbulent fluctuations in the outer region indicate the possibility that breakdown occurs in the outer layer not near the wall.

An Experimental Study on the Cooling and Heating Performance of a Residential Ground Source Heat Pump System (가정용 지열원 열펌프 시스템의 냉난방 성능 특성 연구)

  • Kong, Hyoung Jin;Kang, Sung Jae;Yun, Kyoung Sik;Lim, Hyo Jae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.3
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    • pp.156-163
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    • 2013
  • Ground Source Heat Pump (GSHP) systems utilize geothermal energy as a thermal source or sink, for heating, cooling and domestic hot water. It is well known that GSHP is environmentally friendly, and saves energy dramatically. For this reason, many investigative researches have been conducted on commercial and governmental buildings. However, studies on residential GSHP are few, because of the small capacity and cost. In this study, we experimented with the characteristic performance of heating, cooling and seasonal performance factor for a residential GSHP system, which consisted of two 180 m deep u-tube ground heat exchangers, a heat pump and measurement instruments. The installed capacity of the heat pump was 5RT, and the conditioning area was $62.23m^2$. From the experimental results, the cooling COP of the heat pump was 4.13, and the system COP was 3.51, while the CSPF was 3.32. On the other hand, the heating COP of the heat pump was 3.87, and the system COP was 3.39, while the HSPF was 3.39. Also, in-situ cooling COP and capacity were 93.7% and 96.4% compared with the EWT certification data, respectively, and that of heating were 98.3% and 95.7%, respectively.

Development of Blood Pressure Simulator for Test of the Arm-type Automatic Blood Pressure Monitor (팔뚝형 자동혈압계 평가용 혈압 시뮬레이터 개발)

  • Kim, S.H.;Yun, S.U.;Cho, M.H.;Lee, S.J.;Lim, M.H.;Seo, S.Y.;Jeon, G.R.
    • Journal of Sensor Science and Technology
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    • v.24 no.4
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    • pp.239-246
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    • 2015
  • Blood pressure is possible to diagnose a disease associated with blood pressure and judgment the current health of patients. Automatic blood pressure monitor capable of measuring a blood pressure easily in hospital and at home have become spread. In this study, we developed the blood pressure simulator (BPS) that can test the arm-type automatic blood pressure monitor that is commonly used in hospital. BPS is to produce a pressure similar to the pressure wave generated in the human blood using a servo disk motor. Then, using the silicon tube, it implements the situations such as human blood vessels, and to output the generated pressure waveform. Simply the BPS's phantom put on the cuff and it is able to simulate blood pressure. So anyone can quickly test the blood pressure monitor within one minute and it is possible to shorten the test time required for the automatic blood pressure monitor. In Performance test, the trends and the standard deviation of the values measured in the BPS is similar to the value of the measured pressure from people with normal blood pressure. Thus, the development BPS showed a possibility of taking into account the actual blood pressure measurement environment simulator.