• Journal of the Korean Wood Science and Technology
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• 제31권6호
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• pp.31-39
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• 2003

The enzymatic isolation of residual lignins obtained from spruce and beech pulps (obtained by sulfite, kraft, ASAM and soda/AQ/MeOH pulping processes) and their characterization was described in previous publications. Here, the residual lignins have been submitted to potassium permanganate oxidation (KMnO₄ degradation), and 9 aromatic carboxylic acids (3 of them are dimeric) were identified after methylation with diazomethane by GC/MS. The analytical challenge during qantification by the internal standard methods was the partly high protein content of the samples, which resulted in elevated anisic acid yields in the degradation mixture of sulfite residual lignins. The results are compared with the KMnO₄ degradation of the corresponding MWLs and discussed in terms of S/G ratios and degrees of condensation. The latter was calculated as a quotient between the aromatic carboxylic acids derived from condensed and non-condensed lignin structures. Typical degradation patterns for the various processes have been observed. Among other parameter, the relative compositions between iso-hemipinic acid (which is for condensation in pos. 5 of the aromatic ring) and meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (both are for condensation in pos. 6 of the aromatic ring) was found to be process specific. Kraft and soda/AQ/MeOH residual lignins yielded higher amounts of iso-hemipinic acid. In contrast, the relative yields of meta-hemipinic acid and 3,4,5-trimethoxyphthalic acid (the latter in beech lignins) are higher in sulfite and particularly in ASAM residual lignin. In case of beech residual lignins the amount of acids originated from non-condensed syringyl type lignin units was surprisingly high. The condensation degree of residual lignins was shown to be generally higher than that of MWLs. This was especially true for the G units. ASAM residual lignin exhibited very high S/G ratios and degrees of polymerization. Causality between condensation degree and total yield of degradation products was demonstrated.

• Geomechanics and Engineering
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• 제35권6호
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• pp.581-591
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• 2023

North Anatolian Fault Zone is tectonically active with recent earthquakes (Mw7.6 1999-Kocaeli and Mw7.2 1999-Düzce earthquakes) and it passes through Marmara region, which is highly industrialized, densely populated and economically important part of Turkey. Many power plants, located in Marmara region, are exposed to high seismic hazard. In this study, open source OpenQuake software has been used for the probabilistic earthquake hazard analysis of Marmara region and risk assessment for the specified energy facility. The SHARE project seismic zonation model has been used in the analysis with the regional sources, NGA GMPEs and site model logic trees. The earthquake hazard results have been compared with the former and existing earthquake resistant design regulations in Turkey, TSC 2007 and TBSCD 2018. In the scope of the study, the seismic hazard assessment for a typical natural gas combined cycle power plant located in Marmara region has been achieved. The seismic risk assessment has been accomplished for a typical control building located in the power plant using obtained seismic hazard results. The structural and non-structural fragility functions and a consequence model have been used in the seismic risk assessment. Based on the seismic hazard level with a 2% probability of exceedance in 50 years, considered for especially these type of critical structures, the ratios of structural and non-structural loss to the total building cost were obtained as 8.8% and 45.7%, respectively. The results of the study enable the practical seismic risk assessment of the critical facility located on different regions.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1999년도 봄 학술발표회 논문집
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• pp.277-284
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• 1999

This study describes the influence factors related to slope failure pattern and dimension in the southern Kyounggi area. Intrusive and metamorphic rocks are distributed in the study area. Geological condition, rainfall property and slope geometry are influence on slope failure characteristics in the study we& Geological factors related to slope failure are rock type, geological structure and weathering condition. Because of deep soil (RS-CW) depth of granite region, circular failure type is major failure pattern in granite region. Almost granite slopes with circular or surface failure pattern are failed during heavy rainfall season. But typical wedge failure type related to geological structure factor is a main failure pattern of metamorphic rock slope. Additionally failure dimension is influenced by geological factors and several factors, i.e. natural slope condition, failure type, rainfall intensity and etc. failure height/width ratio and thickness/length ratio of granite slope are 0.88 and 0.23. But the ratios of metamorphic rock slope are 1.36 and 0.19.

• 한국잠사곤충학회지
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• 제39권2호
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• pp.134-139
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• 1997

To elucidate genetical and biochemical characters of the white egg strains preserved in National Sericultural and Entomology Research Institute(NSERI), RDA of Korea, the genetic segregation ratios in egg colours were investigated by crossing test, and egg pigment precursors were also analyzed by paper chromatography and UV-spectrophotometer scanning. The result obtained by crossing test between the white egg strains and normal one illustrated that the most of white egg strains showed typical segregation ratio of white egg-2(w-2), while maternal inheritance which can be seen in white egg-1(w-1) was not found in any white egg strains. Paper chromatographic analysis showed that egg extracts of all the white egg strains contained 3OH-kynurenine, while kynurenine which is known to existed in white egg-1(w-1) could not be detected at all. From the results of these experiments, it was found that all the white egg strains preserved in NSERI were classified as the white egg-2(w-2) strain.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.123-128
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• 2001

The Purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effect of the monomer ratio on the typical properties of polymer-modified mortars with methyl methacrylate-butyl acrylate latexes. The polymer latex-modified mortars are prepared with 5, 10, IS and 20% of polymer cement ratio respectively, and properties of modified mortars such as water absorption, compressive and flexural strengths, chloride-ion penetration depth are tested. The test results indicate that the monomer ratio is very important factors to characterize the strength properties of polymer-modified mortars, but the water absorption and chloride-ion penetration depth are influenced by polymer-cement ratio rather than monomer ratios.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.87-92
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• 2002

At present, the polymer-modified mortars are used as high-performance as well as multi-functional materials in the construction industry. The purpose of this study is to synthesize polymer to modify in cement mortars and make test samples to understand pore size distribution. This paper deals with the effect of monomer ratio on the typical properties of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate(MMA/BA) latexes synthesized through emulsion polymerization. From the results, we knew that the pore volume of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate latexes at bound MMA contents of 70 and 60 percent is 7.5-75cm$^3$/g and the fine pore volume is increased with an increase in the polymer-cement ratio. The total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio.

• 한국자동차공학회논문집
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• 제4권2호
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• pp.50-59
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• 1996

The computer simulation program that calculates the transient heat load transferred to a passenger vehicle has been developed. Method for modeling mathematically various kinds of the heat load was presented and the derived equations were solved numerically. To find out the accuracy of the simulation program, the correlation of experimental and analytical results was demonstrated. By using this program, the typical characteristics about temperature distribution and instantaneous or of vehicle body color, material of glass, air-conditioning capacity, driving direction, and speed. Under a steady-state condition, the ratios of the heat load, resulting form vehicle body, glass, and interior part, were 35%, 29%, and 36%, respectively.

• 한국지진공학회:학술대회논문집
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• 한국지진공학회 2001년도 춘계학술대회 논문집
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• pp.379-386
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• 2001

Fluid viscous dampers have been used as energy dissipators or STU's (Shock Transmission Unit) in earthquake resistant designs for bridges. Viscous dampers have many advantages compared to other friction type or visco-elastic type of dampers. They do neither increase internal pier forces due to their out of phase response, nor produce reaction forces at the low velocities associated with thermal movements. Therefore, they anable the super structure to restore itself perfectly after a severe movement dut to seismic excitations. This paper investigates the response of bridges designed with viscous dampers in regard to damping coefficients, properties of dampers, and arrangements of dampers. For this purpose, time-history dynamic analyses have been performed using a very simple model relevant to a typical bridge example. Based on the results, it presents some design duidelines on how to determine a proper damping ratio and on how to arrange dampers. In usual cases, damping coefficients corresponding to about 0.2-0.3 of damping ratios seem to be very effective in bridge designs.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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• pp.312-316
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• 1995

Flat-plate buildings are commonly modeled as two-dimensional frames to calculate lateral drift, unbalanced moments, and shear at slab-column connections. For gravity loads. the slab-column frames are analyzed using equivalent column approach, while equivalent beam approach is typical for lateral loads. The equivalent beam approach is convenient for computer analysis, but no rational procedure exists for determining the effective width of foor slabs. At present, the determination of the equivalent slab width and its stiffness is a matter of engineering judgement. To account for cracking, overly conservative assumptions are made regarding the stiffness of the slab. A rational approach is therefore needed to realistically estimate the equivalent slab width and its stiffness for unbalanced moment and lateral drift calculations. Based on the test results of 8 interior slab-column connections, an equivalent beam model is proposed in which columns are modeled conventionally as a function of column and slab aspect ratios and the magnitude of the gravity load. the proposed approach is verified with selected experimental results and is founded to be practical and convenient for analyzing flat-plate buildings subjected to gravity and lateral loading.

• 한국산업융합학회 논문집
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• 제13권1호
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• pp.31-39
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• 2010

An exergy analysis is carried out for the regenerative gas turbine cycle which has a potential of enhanced thermal efficiency and specific power owing to the more possible water injection than that of inlet fogging under the ambient conditions. Using the analysis model in the view of the second law of thermodynamics, the effects of pressure ratio, water injection ratio and ambient temperature are investigated on the performance of the system such as exergetic efficiency, heat recovery ratio of recuperator, exergy destruction or loss ratios, and on the optimal conditions for maximum exergy efficiency. The results of computation for the typical cases show that the regenerative gas turbine system with afterfogging can make a notable enhancement of exergy efficiency.