• Title/Summary/Keyword: Two-phase extraction

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유기물 분리용 투과증발막

  • 박현채
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.03a
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    • pp.69-90
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    • 1996
  • In the chemical industry, in the pharmaceutical industry, and in a number of other industries separation processes are necessary to separate and purify products and raw materials [1,2]. Separation processes are also widely used in other applications such as in recycling valuable materials from waste streams. Unit operations for separation processes can be classified in phase separation techniques and component separation techniques based on the nature of the feed mixtures to be separated. The former techniques are used for the separation of heterogeneous mixtures, in which the feed is already present in two or more separated phases on a micro-scale. The latter are suitable for the separation of homogeneous mixtures such as gaseous mixtures and mixtures of completely miscible liquids. tn these cases the separation into individual components is generally achieved by utilizing the differences in physico-chemical properties of components, and is much more difficult compared to phase separation techniques. Separation processes such as distillation, evaporation, liquid-liquid extraction, and crystallization belong to this class.

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Simultaneous Determination and Optimization Ultrasound-Assisted Extraction of Poncirin and Naringin in Poncirus trifoliata Rafinesqul (지실의 Poncirin, Naringin의 동시분석법 확립과 초음파 추출법 최적화)

  • Lee, Ah Reum;Jang, Seol;Lee, A Yeong;Choi, Goya;Kim, Hyo Seon;Kim, Ho Kyoung
    • Korean Journal of Medicinal Crop Science
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    • v.22 no.2
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    • pp.147-153
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    • 2014
  • The Ponciri fructus immaturus (Poncirus trifoliata Rafinesque) has been used in oriental medicine for uterine contraction, stomachache, abdominal distension and cardiovascular diseases. Two main compounds, poncirin and naringin were successfully analyzed by high performance liquid chromatography (HPLC) and carried out method validation according to ICH guideline. A successful resolution and retention times were obtained with a $C_{18}$ reversed phase column, at an $1m{\ell}min^{-1}$ flow rate, with a gradient elution of a mixture of methanol, water and acetonitrile. Poncirin and naringin showed good linearity ($R^2$ > 0.999) in relatively wide concentration ranged. The recovery of each compound was 95.81 ~ 101.48% with R.S.D. values less than 1.0%. The application of ultrasound-assisted extraction was shown to be more efficient in extracting poncirin and naringin from Ponciri fructus immaturus. The predicted optimal poncirin and naringin yield were poncirin 2.15%, naringin 1.65% under an extraction temperature of $40^{\circ}C$, an extraction time of 10 min in a solvent of 70% methanol.

Comparison of the volatile flavor compounds in different tobacco types by different extraction methods (추출방법에 따른 잎담배 종류별 휘발성 향기성분 특성비교)

  • Lee, Jang-Mi;Lee, Jeong-Min;Lee, Chang-Gook;Bock, Jin-Young;Hwang, Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.32 no.2
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    • pp.77-87
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    • 2010
  • Traditional simultaneous distillation extraction(SDE) and solid-phase micro extraction(SPME) methods using GC/MS were compared for their effectiveness in the extraction of volatile flavor compounds from different tobacco leaves types(flue-cured, burley, oriental). The major volatile flavor compounds of flue-cured and burley tobacco were similar such as neophytadiene, solanone, megastigmatrienone isomers, ${\beta}$-damascenone and ${\beta}$-ionone. On the other hand, volatile flavor compounds such as norambreinolide, sclareolide were specifically identified in oriental tobacco. Each method was used to evaluate the responses of some analytes from real samples and standards in order to provide sensitivity comparisons between two techniques. Among three types of SPME fibers such as PDMS(Polydimethylsiloxane), PA(Polyacrylate) and PDMS/DVB (Polydimethylsiloxane/Divinylbenzene) which were investigated to determine the selectivity and adsorption efficiency, PDMS/DVB fiber was selected for the extractions of the volatile flavor compounds due to its effectiveness. The qualitative analysis showed that the total amount of volatile flavor compounds in SDE method(130 species) was much more than that in SPME method(85 species). SPME method was more efficient for all the highly volatile compounds than SDE method, but on the other hand, low-volatile compounds such as fatty acids or high-molecular hydrocabons were detected in SDE method. SPME method based on a short-time sampling can be adjusted to favor a selected group compounds in tobacco. Furthermore this results could be used to estimate the aroma characteristics of cigarette blending by using a different type of tobacco with more effectiveness and convenience.

Size, Scale and Rotation Invariant Proposed Feature vectors for Trademark Recognition

  • Faisal zafa, Muhammad;Mohamad, Dzulkifli
    • Proceedings of the IEEK Conference
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    • 2002.07c
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    • pp.1420-1423
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    • 2002
  • The classification and recognition of two-dimensional trademark patterns independently of their position, orientation, size and scale by proposing two feature vectors has been discussed. The paper presents experimentation on two feature vectors showing size- invariance and scale-invariance respectively. Both feature vectors are equally invariant to rotation as well. The feature extraction is based on local as well as global statistics of the image. These feature vectors have appealing mathematical simplicity and are versatile. The results so far have shown the best performance of the developed system based on these unique sets of feature. The goal has been achieved by segmenting the image using connected-component (nearest neighbours) algorithm. Second part of this work considers the possibility of using back propagation neural networks (BPN) for the learning and matching tasks, by simply feeding the feature vectosr. The effectiveness of the proposed feature vectors is tested with various trademarks, not used in learning phase.

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Volatile Flavor Compounds of Olive Flounder (Paralichthys olivaceus) Fed Diets Supplemented with Yuza (Citrus junos Sieb ex Tanaka) (유자 첨가 사료로 사용된 넙치의 휘발성 향미 성분)

  • Kim, Heung-Yun;Shin, Tai-Sun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.42 no.3
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    • pp.224-231
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    • 2009
  • Volatile components in Olive Flounder fed diets containing 0, 2,5, 5.0, and 7.5% yuza (Citrus junas Sieb ex Tanaka) for 4 months were investigated. Samples were extracted by solid-phase micro extraction and analyzed by gas chromatography/mass spectrometry. Among 89 compounds detected, 82 were positively identified. Volatile compounds of Olive Flounder fed the unsupplemented diet comprised 12 acids, 10 alcohols, eight aldehydes, five aromatic compounds, nine esters, 12 hydrocarbons, four ketones, two monoterpenes, and one miscellaneous compound. Compounds identified in Olive Flounder fed the yuza-supplemented diets consisted of 10 esters, 11 monoterpenes, 13 sesquiterpenes, and two miscellaneous compounds, with the other compounds being the same as in the control. The most abundant class of compounds in flounders fed the yuza-supplemented diet was the monoterpenes, which included limonene, $\beta$-terpinene, $\beta$-trans-ocimene, and $\alpha$-terpinolene. Of the 13 sesquiterpenes identified in flounder fed the yuza-supplemented diet, bicyclogermacrene was the major volatile compound followed by allo-aromadendrene, trans-caryophyllene, and $\delta$-cadinene. Bicyclogermacrene and germacrene D content increased significantly as the yuza supplementation increased.

A Study on the Fluid Mixing Analysis for Proving Shell Wall Thinning of a Feedwater Heater (급수가열기 동체 감육 현상 규명을 위한 유동해석 연구)

  • Shin, Min-Ho;Hwang, Kyeong-Mo;Kim, Kyung-Hoon
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2017-2022
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    • 2004
  • There are multistage preheaters in the power generation plan to improve the thermal efficiency of the plant and to prevent the components from the thermal shock. The energy source of these heaters comes from the extracted two phase fluid of working system. These two-phase fluid can cause the so-called Flow Accelerated Corrosion(FAC) in the extracting piping and the bubble plate of the heater for example, in case of point Beach Nuclear Power Plant and in the Wolsung Nuclear Power Plant. The FAC is due to the mass transport of the thin oxide layer by the convection. FAC is dependent on many parameters such as the operation temperature, void fraction, the fluid velocity and pH of fluid and so on. Therefore, in this paper velocity was calculated by FLUENT code in order to find out the root cause of the wall thinning of the feedwater heaters. It also includeed in the fluid mixing analysis model are around the number 5A feedwater heater shell including the extraction pipeline. To identify the relation between the local velocities and wall thinning, the local velocities according to the analysis results were compared with distribution of the shell wall thicknes by ultrasonic test.

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Extracting Fuzzy Rules for Classifying Ventricular Tachycardia/Ventricular Fibrillation Based on NEWFM (심실빈맥/심실세동 분류를 위한 NEWFM 기반의 퍼지규칙 추출)

  • Shin, Dong-Kun;Lee, Sang-Hong;Lim, Joon-S.
    • Journal of Internet Computing and Services
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    • v.10 no.2
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    • pp.179-186
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    • 2009
  • This paper presents an approach to classify normal and Ventricular Tachycardia/Ventricular Fibrillation(VT/VF) from the Creighton University Ventricular Tachyarrhythmia DataBase(CUDB) using the neural network with weighted fuzzy membership functions(NEWFM). In the first step, wavelet transform is used for producing input values which are used in the next step. In the second step, two numbers of input features are extracted by phase space reconstruction method and peak extraction method using coefficients produced by wavelet transform in the previous step. NEWFM classifies normal and VT/VF beats using two numbers of input features, and then the accuracy rate is 90.13%.

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The Extraction of Ca in Electric arc Furnace Slag for CO2 Sequestration (CO2고정화(固定化)를 위한 전기로제강(電氣爐製鋼)슬래그의 칼슘성분(成分) 침출(浸出))

  • Youn, Ki-Byoung
    • Resources Recycling
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    • v.22 no.1
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    • pp.64-71
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    • 2013
  • Mineral carbonation has been proposed as a possible way for $CO_2$ sequestration. The electric arc furnace slags consist of calcium, magnesium and aluminum silicates in various combinations. If they could be used instead of natural mineral silicates for carbonation, considerable energy savings and $CO_2$ emissions reductions could be achieved. Indirect aqueous carbonation of the slags consists of two steps, extraction of calcium and carbonation. Acetic acid leaching of electric arc furnace slags had been already studied to extract Ca in them, but it was reported that the carbonation of the extracted $Ca^{2+}$ in the leached solution would suffer from too slow kinetics, even at high pressure of $CO_2$. In this work, to develop more efficient extraction of the electric arc furnace slags, hydrochloric acid leaching to separate calcium from them was studied, and the results were compared with the acetic acid ones. The phase boundary between $Ca^{2+}$ and $CaCO_3$ in the solution with pH was determined by thermodynamic calculations. Hydrochloric acid was more effective than acetic acid for the extraction of Ca in electric arc furnace slag, and there is a possibility to recycle an unreacted hydrochloric acid in the leached solution by electrolysis or evaporation.

Automatic Recognition and Normalization System of Korean Time Expression using the individual time units (시간의 단위별 처리를 이용한 자동화된 한국어 시간 표현 인식 및 정규화 시스템)

  • Seon, Choong-Nyoung;Kang, Sang-Woo;Seo, Jung-Yun
    • Korean Journal of Cognitive Science
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    • v.21 no.4
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    • pp.447-458
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    • 2010
  • Time expressions are a very important form of information in different types of data. Thus, the recognition of a time expression is an important factor in the field of information extraction. However, most previously designed systems consider only a specific domain, because time expressions do not have a regular form and frequently include different ellipsis phenomena. We present a two-level recognition method consisting of extraction and transformation phases to achieve generality and portability. In the extraction phase, time expressions are extracted by atomic time units for extensibility. Then, in the transformation phase, omitted information is restored using basis time and prior knowledge. Finally, every complete atomic time unit is transformed into a normalized form. The proposed system can be used as a general-purpose system, because it has a language- and domain-independent architecture. In addition, this system performs robustly in noisy data like SMS data, which include various errors. For SMS data, the accuracies of time-expression extraction and time-expression normalization by using the proposed system are 93.8% and 93.2%, respectively. On the basis of these experimental results, we conclude that the proposed system shows high performance in noisy data.

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Optimization of Headspace Sampling Using Solid Phase Microextraction For Volatile Organic Acids in Different Tobacco Types

  • Lee, Jang-Mi;Lee, Jeong-Min;Son, Seong-Ae;Kwon, Young-Ju;Jang, Gi-Chui;Kim, Young-Ho
    • Journal of the Korean Society of Tobacco Science
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    • v.35 no.1
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    • pp.7-12
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    • 2013
  • A Solid-phase micro extraction(SPME) was evaluated as a tool for headspace sampling of tobacco samples. Several experimental parameters (sampling temperature, pH, and type of SPME fibers) were optimized to improve sampling efficiency in two aspects ; maximum adsorption and selective adsorption of volatile organic acids onto SPME fibers. Among four types of SPME fibers such as PDMS(Polydimethylsiloxane), PA(Polyacrylate), Car/PDMS (Carboxen/Polydimethylsiioxane) and PDMS/DVB(Polydimethylsiioxane/Divinylbenzene) which were investigated to determine the selectivity and adsorption efficiency. A variety of tobacco samples such as flue cured, burley and oriental were used in this study. The effect of these parameters was often dominated by the physical and chemical nature (volatility, polarity) of target compounds. This method allowed us to make important improvements in selectivity and sensitivity. The Car/PDMS fiber was shown to be the most efficient at extracting the 10 selected volatile organic acids. The parameters were optimized: $80^{\circ}C$ adsorption temperature, 30 min of adsorption time, $240^{\circ}C$ desorption temperature, 1 min of adsorption time.