• 제목/요약/키워드: Two temperature model

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투과증발에 의한 Ester 성분의 소수성막의 투과플럭스 (Permeation Flux of Ester Compounds through Hydrophobic Membrane by Pervaporation)

  • 송근호;이광래
    • 멤브레인
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    • 제26권3호
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    • pp.197-204
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    • 2016
  • 에스테르(ester)의 모델 수용액으로부터 에스테르 성분을 회수하기 위한 투과증발 공정에서, 공급액의 농도와 온도 변화에 따른 에스테르와 물의 플럭스를 측정하였다. 공급액의 에스테르 농도가 0.15 wt%에서 0.60 wt%로 증가함에 따라 에틸 아세테이트(EA), 프로필 아세테이트(PA), 에틸 프로피오네이트(EP), 부틸 아세테이트(BA), 그리고 에틸 부티레이트(EB)의 플럭스는 증가하였으며, 공급액의 온도가 $30^{\circ}C$에서 $50^{\circ}C$로 증가함에 따라 플럭스가 증가하였다. 에스테르 플럭스의 크기는 (EA) < (PA, EP) < (BA, EB) 순서이었으며, 이는 에스테르와 막 표면과의 친화도에 크게 의존하는 것을 보여준다. 즉, EA는 분자쇄 내에 소수성 기($-CH_2-$)를 1개, (PA, EP)는 2개를 포함하고 있으나, (BA, EB)는 3개를 가지고 있어 가장 소수성이 크기 때문이다. 이러한 에스테르 분자의 소수성이 에스테르 플럭스에 미치는 영향뿐 아니라 막 표면의 소수성이 에스테르 플럭스에 미치는 영향에 관한 연구가 더 필요할 것이다. 온도가 증가함에 따라, EA, PA, EP, BA, and EB 수용액의 물 플럭스는 증가하였으나, 농도 변화에 따른 물 플럭스는 거의 변화가 없었다. 본 투과증발에 대한 실험결과는 기존의 열을 이용하는 증발공정과 증류공정을 대체할 수 있는 공정으로서 향 성분의 회수공정을 개선하는 기초 자료로 활용할 수 있을 것이다.

겨울철 영동지역 눈 결정 습성과 성상 변화 에피소드 분석 (Episode Analysis of the Habit and Phase Changes of Snow Crystals in the Wintertime Yeongdong Region)

  • 최영길;김병곤;김지윤;김태연;한진헌;이규원;김권일;김기훈;임병환
    • 대기
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    • 제34권2호
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    • pp.139-151
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    • 2024
  • The Yeongdong region has suffered from severe snowstorms and the relevant damage such as traffic accidents on slippery roads, and the collapse of greenhouses and temporary buildings. While a lot of research on snowfall has been conducted, the detailed study of snow crystals' phase and habit through intensive observations and the relevant microphysical analysis is still lacking. Therefore, a snowflake camera, PARSIVEL, and intensive radiosonde soundings were utilized to investigate phase and habit changes in solid precipitation. Two remarkable episodes of phase and habit changes were selected such as 19 March 2022 and 15 February 2023. Both events occurred in the synoptic condition of the High in the north and the Low passing by the south, which was accompanied by rapid temperature cooling below 2.5 km. During the events of a short period between 3 to 6 hours, the temperature at 850 hPa decreased by about 4 to 6℃. This cooling led to a change in the main habit of snow particles from riming to aggregate, identified with both MASC and PARSIVEL. Meanwhile, the LDAPS model analyses do not successively represent the rapid cooling and short-term variations of solid precipitation, probably by virtue of overestimating low-level equivalent potential temperature during these periods. The underlying causes of these the low-level temperature variations within 6 hours, still remain unclear. It might be associated with mesoscale orographic phenomenon due to the mountains and East Sea effects, which certainly needs an intensive and comprehensive observation campaign.

다년도 분광 데이터를 이용한 콩의 생체중, 엽면적 지수 추정 (Estimation of Fresh Weight and Leaf Area Index of Soybean (Glycine max) Using Multi-year Spectral Data)

  • 장시형;유찬석;강예성;박준우;김태양;강경석;박민준;백현찬;박유현;강동우;쩌우쿤옌;김민철;권연주;한승아;전태환
    • 한국농림기상학회지
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    • 제23권4호
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    • pp.329-339
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    • 2021
  • 콩은 논 대표적인 밭작물로써 온도, 수분, 토양과 같은 환경 조건에 민감하기 때문에 재배 시 포장 관리가 매우 중요하다. 작물 상태를 비파괴적, 비접촉적 방법으로 측정할 수 있는 분광 기술을 활용한다면 작황 예측, 작물 스트레스 및 병충해 판별 등 생육 진단 및 처방을 통해 품질과 수확량을 높일 수 있다. 본 연구에서는 회전익 무인기에 탑재된 다중분광 센서를 이용하여 시험 포장에서 콩 생육 추정 모델 개발하고 재현성을 확인하기 위해 농가 포장에 검증을 수행하였다. 분광 데이터로 산출된 정규화 식생지수(NDVI, GNDVI), 단순비 식생지수(RRVI, GRVI)와 콩 생육 데이터(생체중, LAI)를 선형회귀분석을 실시하여 모델을 개발하였으며 괴산에 위치한 농가포장에서 검증을 실시하였다. 그 결과 생체중의 경우 정규화 식생지수를 이용 시 포화되기 때문에 단순비 식생지수 GRVI를 이용한 모델의 성능이 가장 높았다(R2=0.74, RMSE=246 g/m2, RE=34.2%). 괴산 농가 포장에 생체중 모델 검증 결과 RMSE=392 g/m2, RE=32%로 나타났으며 작부 체계별 나누어 검증 결과 단작 포장과 이모작 포장 생체중 모델은 RMSE=315 g/m2, RE=26% 및 RMSE=381 g/m2, RE=31%로 나타났다. 작부 체계별 포장과 적산온도가 유사한 연도별 시험 포장(2018+2020년, 2019년)을 나누어 생체중 모델 개발한 결과 단년도(2019년)의 성능이 높게 나타났다. 작부 체계별 적산온도가 유사한 검증과 기존 검증 간 비교 결과 단작 포장은 RMSE 및 RE를 기준으로 각각 29.1%와 34.3%로 개선되었으나 이모작 포장은 -19.6%, -31.3%로 저하되었다. 적산온도 이외의 환경 요인, 분광 및 생육 데이터 추가 시 다양한 환경 조건에서 재배되는 콩 생육을 추정 가능할 것으로 판단된다.

백서의 가역성 뇌허혈 모형에서 저체온의 효과와 적용시기 (The Time and Effect of Hypothermia in Early Stage of the Reversible Cerebral Focal Ischemic Model of Rat)

  • 최병연;정병우;송광철;박진한;김성호;배장호;김오룡;조수호;김승래
    • Journal of Korean Neurosurgical Society
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    • 제29권2호
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    • pp.167-179
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    • 2000
  • Objective : We studied to clarify the effective time zone of mild hypothermic neural protection during ischemia and/or reperfusion after middle cerebral artery occlusion. Methods : In a reversible cerebral infarct model which maintained reperfusion of blood flow after middle cerebral artery occlusion for two hours, the size of cerebral infarction, cerebral edema and the extent of neurological deficit were observed and analyzed for comparison between the control and the experimental groups under hypothermia($33.5^{\circ}C$). The temporalis muscle temperature was reduced to $33.5^{\circ}C$ by surface cooling for two hours during middle cerebral artery occlusion for study group I. The following groups applied hypothermia for two-hour periods after reperfusion : group II(0-2 hours), group III(2-4 hours), and group IV(4-6 hours). They were rewarmed to $36.5^{\circ}C$ until sacrified at 2, 4, 6, 12, and 24 hours after reperfusion. Control group was maintained at normothermia without hypothermia. Results : In the experimental groups with hypothermia, the average value of the size of cerebral infarction($mean{\pm}SD$) was $1.97{\pm}1.65%$, which was a remarkable reduction over that of the control, $4.93{\pm}3.79%$. In the control, a progressive increase was shown in the size of infarction from point of reperfusion to 6 hours after reperfusion without further changes in size afterward. Intra-ischemic hypothermia(group I) prevented ischemic injury but did not prevent reperfusion injury. Group II examplified the most neural protective effect in comparison to the control group and group IV(p<0.05). The cortex was more vulnerable to reperfusion injury than the subcortex. Mild hypothermia showed more neural protective effects on the cortex than subcortex. Conclusion : The most appropriate time zone for application of mild hypothermia was defined to be within four hours following reperfusion.

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Sintering Mixtures in the Stage of Establishing Chemical Equilibrium

  • Savitskii, A.P.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 1999년도 춘계학술대회 및 발표대회 강연 및 발표논문 초록집
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    • pp.5-5
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    • 1999
  • The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

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The Effect of Turbulence Penetration on the Thermal Stratification Phenomenon Caused by Coolant Leaking in a T-Branch of Square Cross-Section

  • Choi, Young-Don;Hong, Seok-Woo;Park, Min-Soo
    • International Journal of Air-Conditioning and Refrigeration
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    • 제11권2호
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    • pp.51-60
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    • 2003
  • In the nuclear power plant, emergency core coolant system (ECCS) is furnished at reactor coolant system (RCS) in order to cool down high temperature water in case of emergency. However, in this coolant system, thermal stratification phenomenon can occur due to coolant leaking in the check valve. The thermal stratification produces excessive thermal stresses at the pipe wall so as to yield thermal fatigue crack (TFC) accident. In the present study, effects of turbulence penetration on the thermal stratification into T-branches with square cross-section in the modeled ECCS are analysed numerically. Standard k-$\varepsilon$ model is employed to calculate the Reynolds stresses in momentum equations. Results show that the length and strength of thermal stratification are primarily affected by the leak flow rate of coolant and the Reynolds number of duct. Turbulence penetration into the T-branch of ECCS shows two counteracting effects on the thermal stratification. Heat transport by turbulence penetration from main duct to leaking flow region may enhance thermal stratification while the turbulent diffusion may weaken it.

TSC 합성보의 내화성능에 관한 연구 (Study on the Fire Resistance Performance of the TSC Beam)

  • 김성배;최승관;이창남;김상섭
    • 한국강구조학회 논문집
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    • 제18권1호
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    • pp.113-122
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    • 2006
  • 복합 구조 시스템은 강재와 콘크리트의 합성으로 내화성능이 우수할 것으로 판단된다. 그러나 복합구조의 내화성능에 대한 연구는 아직 초기 단계로 기둥과 보 등의 부재에 대한 내화실험 결과가 일부 발표 되었으나 합성보에 대한 자료는 거의 없다. 이에 본 연구에서는 TSC 합성보의 내화성능 평가를 위해 내화실험과 수학적 및 수치 해석적인 방법을 통해 평가하였다. 내화실험은 형상의 종류와 가력 하중, 내화피복재 보강방법 등을 변수로 실험을 실시하였다. 또한 수치 해석 중 강재와 콘크리트의 재료특성은 Eurocode에 준하였으며 온도의 변화는 열전도 FE 해석과 수학적인 방법을 사용하였다.

콘크리트 내부의 수분함유량 측정에 관한 실험적연구 (An Experimental Study on Measure to Moisture Contents of Concrete)

  • 박원섭;김흥열;김형준
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 2008년도 추계학술논문발표회 논문집
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    • pp.428-433
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    • 2008
  • The strength capacity properties of concrete are much influenced by water content which has a significant effect on concrete spalling, especially, in high temperature areas. Therefore, the properties of the material's shall be closely examined first by measuring the water content in each material in order to analyze Concrete Fire Characteristics, and a reliable measuring method shall be presented in order to derive the following influence. The method used to measure the water content within concrete is mainly divided into 4 types; ASTM method, Nuclear Magnetic method, Ultrasonic measurement method, Radio Wave method, etc. It is essential to use a reliable measuring method for each experiment. In this experiment, we measured the water content and humidity of concrete by two methods; Relative/Absolute humidity method using VISALA HM44 measuring equipment which is easily measurable compared with other methods regardless of the shape of the experimental model, and a water content measuring experiment using ASTM C 566. If the aggregates are under the condition that their surface is dry but in saturation, there is no change of water content according to concrete curing methods. However if the aggregates are absolutely dry, the water content is significantly changed according to concrete curing methods.

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Flow and Convective Heat Transfer Analysis Using RANS for A Wire-Wrapped Fuel Assembly

  • Ahmad, Imteyaz;Kim, Kwang-Yong
    • Journal of Mechanical Science and Technology
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    • 제20권9호
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    • pp.1514-1524
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    • 2006
  • This work presents the three-dimensional analysis of flow and heat transfer performed for a wire-wrapped fuel assembly of liquid metal reactor using Reynolds-averaged Wavier-Stokes analysis in conjunction with 557 model as a turbulence closure. The whole fuel assembly has been analyzed for one period of the wire-spacer using periodic boundary conditions at inlet and outlet of the calculation domain. Three different assemblies, two 7-pin wire-spacer fuel assemblies and one bare rod bundle, apart from the pressure drop calculations for a 19-pin case, have been analyzed. Individual as well as a comparative analysis of the flow field and heat transfer have been discussed. Also, discussed is the position of hot spots observed in the wire-spacer fuel assembly. The flow field in the subchannels of a bare rod bundle and a wire-spacer fuel assembly is found to be different. A directional temperature gradient is found to exist in the subchannels of a wire-spacer fuel assembly Local Nusselt number in the subchannels of wire-spacer fuel assemblies is found to vary according to the wire-wrap position while in case of bare rod bundle, it's found to be constant.

저수지 모델의 지형정보 엽력자료가 수리결과에 미치는 영향 분석 - 대청호를 대상으로 - (Analysis of the Effects of Bathymetry Data on Hydraulic Results - Daecheong Reservoir -)

  • 이재일;서세덕;하성룡
    • 환경영향평가
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    • 제18권4호
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    • pp.229-234
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    • 2009
  • A lot of research on the application of GIS has been conducted in the field of water quality management. The function of a geometric data acquisition for reservoir and river models, however, is not enough to satisfy multiuser' convenience. CE-QUAL-W2 is a two-dimensional(2D) longitudinal/vertical hydrodynamic and water quality model for surface water bodies, modeling eutrophication processes such as temperature-nutrient-algae and sediment relationships. The purpose of this study is to analyzing which bathymetry information affects hydraulic results. There are consisted of three scenarios under consideration. The first scenario takes into account only tribatary type data such as Heoin and Okchen river. The second scenario, Heoin river constructs to tributary and Okchen river constructs by branch. Last scenario constructs Heoin and Okchen river by branch. The RMSE error results for the first, second and third scenarios are 0.61, 0.36 and 0.28 respectively.