• Title/Summary/Keyword: Two temperature model

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A Study on Exothermic Properties of TiO2/Epoxy Nanocomposites (TiO2/Epoxy 나노복합재의 발열 특성에 관한 연구)

  • Ahn, Seok-Hwan;Ha, Yoo-Sung;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.27 no.5
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    • pp.99-104
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    • 2013
  • Recently, various nanoparticles have been used for filler in polymer matrices. The particles of nano size are whether high or not cross-link density in polymer affects the thermal and mechanical properties of one. The properties change as a result of chemical reactions between the nanoparticles and the surface of the polymer. There are two models for nanocomposites: "repulsive interaction" and "attractive interaction" between the nanoparticles and matrix. In this study, the variation in the curing mechanism was examined when nano-size $TiO_2$ was dispersed into an epoxy (Bisphenol A, YD-128) with different curing agents. The results of this study showed that the exothermic temperature and Tg in the case of the nanoparticles used (Jeffamine) (D-180) at room temperature were reduced by an increase in the $TiO_2$ contents because of the "repulsive interaction" between the nanoparticles and the matrix. The tensile strengths were increased by increasing amounts of $TiO_2$ until 3 wt% because of a dispersion strengthening effect caused by the nanoparticles, because of the repulsive interaction. However, such tensile properties decreased at 5 wt% of $TiO_2$, because the $TiO_2$ was agglomerated in the epoxy. In contrast, in the case of the nanoparticles that used NMA and BDMA, the exothermic temperature and Tg tended to rise with increasing amounts of $TiO_2$ as a result of the "attractive interaction." This was because the same amounts of $TiO_2$ were well dispersed in the epoxy. The tensile strength decreased with an increase in the $TiO_2$ contents. In the general attractive interaction model, however, the cross-link density was higher, and tensile strength tended to increase. Therefore, for the nanoparticles that used NMA, it was difficult to conclude that the result was caused by the "attractive model."

Possibilities for Improvement in Long-term Predictions of the Operational Climate Prediction System (GloSea6) for Spring by including Atmospheric Chemistry-Aerosol Interactions over East Asia (대기화학-에어로졸 연동에 따른 기후예측시스템(GloSea6)의 동아시아 봄철 예측 성능 향상 가능성)

  • Hyunggyu Song;Daeok Youn;Johan Lee;Beomcheol Shin
    • Journal of the Korean earth science society
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    • v.45 no.1
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    • pp.19-36
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    • 2024
  • The global seasonal forecasting system version 6 (GloSea6) operated by the Korea Meteorological Administration for 1- and 3-month prediction products does not include complex atmospheric chemistry-aerosol physical processes (UKCA). In this study, low-resolution GloSea6 and GloSea6 coupled with UKCA (GloSea6-UKCA) were installed in a CentOS-based Linux cluster system, and preliminary prediction results for the spring of 2000 were examined. Low-resolution versions of GloSea6 and GloSea6-UKCA are highly needed to examine the effects of atmospheric chemistry-aerosol owing to the huge computational demand of the current high resolution GloSea6. The spatial distributions of the surface temperature and daily precipitation for April 2000 (obtained from the two model runs for the next 75 days, starting from March 1, 2000, 00Z) were compared with the ERA5 reanalysis data. The GloSea6-UKCA results were more similar to the ERA5 reanalysis data than the GloSea6 results. The surface air temperature and daily precipitation prediction results of GloSea6-UKCA for spring, particularly over East Asia, were improved by the inclusion of UKCA. Furthermore, compared with GloSea6, GloSea6-UKCA simulated improved temporal variations in the temperature and precipitation intensity during the model integration period that were more similar to the reanalysis data. This indicates that the coupling of atmospheric chemistry-aerosol processes in GloSea6 is crucial for improving the spring predictions over East Asia.

Analysis the Effects of Curtain Weir on the Control of Algal Bloom according to Installation Location in Daecheong Reservoir (대청호 수류차단막 설치 위치에 따른 녹조제어 효과 분석)

  • Lee, Heung Soo;Chung, Se Woong;Jeong, Hee Young;Min, Byeong Hwan
    • Journal of Korean Society on Water Environment
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    • v.26 no.2
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    • pp.231-242
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    • 2010
  • The objective of study was to determine an optimal location of a float-type curtain weir in Daecheong Reservoir and to assess its effectiveness for the control of algal blooms in the reservoir. CE-QUAL-W2, a laterally averaged two-dimensional hydrodynamic and eutrophication model, was modified to accommodate vertical displacement of the weir according to water surface fluctuation and applied to simulate the reservoir hydrodynamics and water quality changes for the reservoir. The model calibrated in a previous study was updated and validated for different hydrological conditions representing drought year (2008) and normal year (2006) for the study, and adequately simulated the temporal and spatial variations of water temperature, nutrients and algal (Chl-a) concentrations. The effectiveness of curtain weir on the control of algal bloom was evaluated by applying the validated model to 2001 and 2006 assuming 9 scenarios for different installation locations. The reduction rates of algal concentration were placed in the range of 11.2~40.3% and 20.3~56.7% for 2001 and 2006, respectively. Although, the performance of curtain weir was slightly varied for different locations and different hydrological years, overall, the performance was improved as the weir was installed further downstream.

IDENTIFICATION OF FALSIFIED DRUGS USING NEAR-INFRARED SPECTROSCOPY

  • Scafi, Sergio H.F.;Pasquini, Celio
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.3112-3112
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    • 2001
  • Near-Infrared Spectroscopy (NIRS) was investigated aiming at the identification of falsified drugs. The identification is based on comparison of the NIR spectrum of a sample with a typical spectra of an authentic drug using multivariate modelling and classification algorithms (PCA/SIMCA). Two spectrophotometers (Brimrose - Luminar 2000 and 2030), based on acoustic-optical filter (AOTF) technology, sharing the same controlling computer, software (Brimrose - Snap 2.03) and the data acquisition electronics, were employed. The Luminar 2000 scans the range 850 1800 nm and was employed for transmitance/absorbance measurements of liquids with a transflectance optical bundle probe with total optical path of 5 mm and a circular area of 0.5 $\textrm{cm}^2$. Model 2030 scans the rage 1100 2400 nm and was employed for reflectance measurement of solids drugs. 300 spectra, acquired in about 20 s, were averaged for each sample. Chemometric treatment of the spectral data, modelling and classification were performed by using the Unscrambler 7.5 software (CAMO Norway). This package provides the Principal Component Analysis (PCA) and SIMCA algorithms, used for modelling and classification, respectively. Initially, NIRS was evaluated for spectrum acquisition of various drugs, selected in order to accomplish the diversity of physico-chemical characteristics found among commercial products. Parameters which could affect the spectra of a given drug (especially if presented as solid tablets) were investigated and the results showed that the first derivative can minimize spectral changes associated with tablet geometry, physical differences in their faces and position in relation to the probe beam. The effect of ambient humidity and temperature were also investigated. The first factor needs to be controlled for model construction because the ambient humidity can cause spectral alterations that should cause the wrong classification of a real drug if the factor is not considered by the model.

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Heat transfer analysis of closed-loop vertical ground heat exchangers using 3-D fluid flow and heat transfer numerical model (3차원 열유체 수치해석을 통한 현장 시공된 수직 밀폐형 지중열교환기의 열전달 거동 평가)

  • Park, Moon-Seo;Lee, Chul-Ho;Min, Sun-Hong;Kang, Shin-Hyung;Choi, Hang-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.800-807
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    • 2010
  • In this study, a series of numerical analyses has been performed in order to evaluate the performance of a full-scale closed-loop vertical ground heat exchanger constructed in Wonju. The circulation pipe HDPE, borehole and surrounding ground were modeled using FLUENT, a finite-volume method (FVM) program, for analyzing the heat transfer process of the system. Two user-defined functions (UDFs) accounting for the difference in the temperatures of the circulating inflow and outflow water and the change of the surrounding ground temperature with depth were adopted in the FLUENT model. The thermal properties of materials estimated in laboratory were used in the numerical analyses to compare the thermal efficiency of the cement grout with that of the bentonite grout used in the construction. The results of the simulation provide a verification of the in situ thermal response test data. The numerical model with the ground thermal conductivity of 4W/mK yielded the simulation result closer to the in-situ thermal response test than with the ground thermal conductivity of 3W/mK. From the results of the numerical analyses, the effective thermal conductivities of the cement and bentonite grouts were obtained to be 3.32W/mK and 2.99 W/mK, respectively.

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Variation of Density Stratification due to Fresh Water Discharge in the Kwangyang Bay and Jinju Bay (광양만과 진주만 해역에서 담수 유입으로 인한 밀도성층 변화)

  • Kang, Young-Seung;Chae, Yeong-Ki;Lee, Hyung-Rae
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.23 no.1
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    • pp.126-137
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    • 2011
  • This study simulate three-dimensional ocean circulation patterns using the EFDC model in the Kwangyang Bay and Jinju Bay, considering tide, water temperature and salinity. The numerical model results were verified using observed data. The model results well reproduced the observed data. As a result, ocean circulation patterns in the study area show convergence and divergence in the middle area of Noryang waterway and Daebang waterway, the residual flow patterns show typical two-layer circulation. According to the change of the density stratification in the Kwangyang Bay and Jinju Bay, the effect of fresh water is dominant in study area. In the case of Jinju Bay, although it is strongly influenced by the Namgang fresh water, also it is affected by Seomjin River when there is no discharge by Namgang Dam. On the other hand, the stratification of the Kwangyang Bay is relatively enhanced by the discharge of Namgang Dam.

Numerical Model of Heat Diffusion and Evaporation by LNG Leakage at Membrane Insulation (LNG 화물창 방열재 균열에 따른 액화천연가스의 확산 및 온도 예측을 위한 수치 모델)

  • Lee, Jang Hyun;Kim, YoonJo;Hwang, Se Yun
    • Journal of Ocean Engineering and Technology
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    • v.28 no.6
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    • pp.517-526
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    • 2014
  • The leakage of cryogenic LNG through cracks in the insulation membrane of an LNG carrier causes the hull structure to experience a cold spot as a result of the heat transfer from the LNG. The hull structure will become brittle at this cold spot and the evaporated natural gas may potentially lead to a hazard because of its flammability. This paper presents a computational model for the LNG flow and heat diffusion in an LNG insulation panel subject to leakage. The temperature distribution in the insulation panel and the speed of gas diffusion through it are simulated to assess the safety level of an LNG carrier subject that experiences a leak. The behavior of the leaked LNG is modeled using a multiphase flow that considers the mixture of liquid and gas. The simulation model considers the phase change of the LNG, gas-liquid multiphase interactions in the porous media, and accompanying rates of heat transfer. It is assumed that the NO96-GW membrane storage is composed of glass wool and plywood for the numerical simulation. In the numerical simulation, the seepage, heat diffusion, and evaporation of the LNG are investigated. It is found that the diffusion speed of the leakage is very high to accelerate the evaporation of the LNG.

STUDY ON A EFFECTIVE THERMAL CONDUCTIVITY OF THE CFRP COMPOSITE STRUCTURE BY A SIMPLIFIED MODEL (모델 단순화에 의한 CFRP 복합 구조물의 유효 열전도율 추출 방법 연구)

  • Kim, D.G.;Han, K.I.;Choi, J.H.;Lee, J.J.;Kim, T.K.
    • Journal of computational fluids engineering
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    • v.20 no.4
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    • pp.63-69
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    • 2015
  • The thermal balance test in vacuum chamber for satellite structures is an essential step in the process of satellite development. However, it is technically and economically difficult to fully replicate the space environment by using the vacuum chamber. To overcome these limitations, the thermal analysis through a computer simulation technique has been conducted. The CFRP composite material has attracted attention as satellite structures since it has advantages of excellent mechanical properties and light weight. However, the nonuniform nature of the thermal conductivity of the CFRP structure should be noted at the step of thermal analysis of the satellite. Two different approaches are studied for the thermal analyses; a detailed numerical modeling and a simplified model expressed by an effective thermal conductivity. In this paper, the effective thermal conductivities of the CFRP composite structures are extracted from the detailed numerical results to provide a practical thermal design data for the satellite fabricated with the CFRP composite structure. Calculation results of the surface temperature and the thermal conductivities along x, y, z directions show fairly good agreements between the detailed modeling and the simplified model for all the cases studied here.

Prediction of the Spawning Ground of Todarodes pacificus under IPCC Climate A1B Scenario (IPCC 기후변화 시나리오(A1B)에 따른 살오징어(Todarodes pacificus) 산란장의 변동 예측)

  • Kim, Jung-Jin;Min, Hong-Sik;Kim, Cheol-Ho;Yoon, Jin-Hee;Kim, Su-Am
    • Ocean and Polar Research
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    • v.34 no.2
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    • pp.253-264
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    • 2012
  • In the northwestern Pacific, spawning of the common squid, Todarodes pacificus, occurs at continental shelf and slope areas of 100-500 m, and the optimum temperature for the spawning and survival of paralarvae is assumed to be $18-23^{\circ}C$. To predict the spawning ground of Todarodes pacificus under future climate conditions, we simulated the present and future ocean circulations, using an East Asia regional ocean model (Modular Ocean Model, MOM version3), projected by two different global climate models (MPI_echam5, MIROC_hires), under an IPCC SRES A1B emission scenario. Mean climate states for 1990-1999 and 2030-2039 from 20th and 21th Century Climate Change model simulation (from the IPCC 4th Assessment Report) were used as surface conditions for simulations, and we examined changes in spawning ground between the 1990s and 2030s. The results revealed that the distribution of spawning ground in the 2030s in both climate models shifted northward in the East China Sea and East Sea, for both autumn and winter populations, compared to that of the 1990s. Also, the spawning area (with $1/6^{\circ}{\times}1/6^{\circ}$ grid) in the 2030s of the autumn and winter populations will decline by 11.6% (MPI_echam5) to 30.8% (MIROC_hires) and 3.0% (MPI_echam5) to 18.2% (MIROC_hires), respectively, from those of the 1990s.

Evaluation of Water Quality Prediction Models at Intake Station by Data Mining Techniques (데이터마이닝 기법을 적용한 취수원 수질예측모형 평가)

  • Kim, Ju-Hwan;Chae, Soo-Kwon;Kim, Byung-Sik
    • Journal of Environmental Impact Assessment
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    • v.20 no.5
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    • pp.705-716
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    • 2011
  • For the efficient discovery of knowledge and information from the observed systems, data mining techniques can be an useful tool for the prediction of water quality at intake station in rivers. Deterioration of water quality can be caused at intake station in dry season due to insufficient flow. This demands additional outflow from dam since some extent of deterioration can be attenuated by dam reservoir operation to control outflow considering predicted water quality. A seasonal occurrence of high ammonia nitrogen ($NH_3$-N) concentrations has hampered chemical treatment processes of a water plant in Geum river. Monthly flow allocation from upstream dam is important for downstream $NH_3$-N control. In this study, prediction models of water quality based on multiple regression (MR), artificial neural network and data mining methods were developed to understand water quality variation and to support dam operations through providing predicted $NH_3$-N concentrations at intake station. The models were calibrated with eight years of monthly data and verified with another two years of independent data. In those models, the $NH_3$-N concentration for next time step is dependent on dam outflow, river water quality such as alkalinity, temperature, and $NH_3$-N of previous time step. The model performances are compared and evaluated by error analysis and statistical characteristics like correlation and determination coefficients between the observed and the predicted water quality. It is expected that these data mining techniques can present more efficient data-driven tools in modelling stage and it is found that those models can be applied well to predict water quality in stream river systems.