• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.505-512
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• 2014

A new donor-accepter-donor-accepter-donor (D-A-D-A-D) type 2,1,3-benzothiadiazole-thiophene-based acceptor unit 2,5-di(4-(5-bromo-4-octylthiophen-2-yl)-2,1,3-benzothiadiazol-7-yl)thiophene ($DTBTTBr_2$) was synthesized. Copolymerized with fluorene and indeno[1,2-b]fluorene electron-rich moieties, two alternating narrow band gap (NBG) copolymers PF-DTBTT and PIF-DTBTT were prepared. And two copolymers exhibit broad and strong absorption in the range of 300-700 nm with optical band gap of about 1.75 eV. The highest occupied molecular orbital (HOMO) energy levels vary between -5.43 and -5.52 eV and the lowest unoccupied molecular orbital (LUMO) energy levels range from -3.64 to -3.77 eV. Potential applications of the copolymers as electron donor material and $PC_{71}BM$ ([6,6]-phenyl-$C_{71}$ butyric acid methyl ester) as electron acceptors were investigated for photovoltaic solar cells (PSCs). Photovoltaic performances based on the blend of PF-DTBTT/$PC_{71}BM$ (w:w; 1:2) and PIF-DTBTT/$PC_{71}BM$ (w:w; 1:2) with devices configuration as ITO/PEDOT: PSS/blend/Ca/Al, show an incident photon-to-current conversion efficiency (IPCE) of 2.34% and 2.56% with the open circuit voltage ($V_{oc}$) of 0.87 V and 0.90 V, short circuit current density ($J_{sc}$) of $6.02mA/cm^2$ and $6.12mA/cm^2$ under an AM1.5 simulator ($100mA/cm^2$). The photocurrent responses exhibit the onset wavelength extending up to 720 nm. These results indicate that the resulted narrow band gap copolymers are viable electron donor materials for polymer solar cells.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.65-65
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• 2015

In this talk, I will introduce two topics. The first topic is the polymer light emitting diodes (PLEDs) using graphene oxide quantum dots as emissive center. More specifically, the energy transfer mechanism as well as the origin of white electroluminescence in the PLED were investigated. The second topic is the facile synthesis of eco-friendly III-V colloidal quantum dots and their application to light emitting diodes. Polymer (organic) light emitting diodes (PLEDs) using quantum dots (QDs) as emissive materials have received much attention as promising components for next-generation displays. Despite their outstanding properties, toxic and hazardous nature of QDs is a serious impediment to their use in future eco-friendly opto-electronic device applications. Owing to the desires to develop new types of nanomaterial without health and environmental effects but with strong opto-electrical properties similar to QDs, graphene quantum dots (GQDs) have attracted great interest as promising luminophores. However, the origin of electroluminescence (EL) from GQDs incorporated PLEDs is unclear. Herein, we synthesized graphene oxide quantum dots (GOQDs) using a modified hydrothermal deoxidization method and characterized the PLED performance using GOQDs blended poly(N-vinyl carbazole) (PVK) as emissive layer. Simple device structure was used to reveal the origin of EL by excluding the contribution of and contamination from other layers. The energy transfer and interaction between the PVK host and GOQDs guest were investigated using steady-state PL, time-correlated single photon counting (TCSPC) and density functional theory (DFT) calculations. Experiments revealed that white EL emission from the PLED originated from the hybridized GOQD-PVK complex emission with the contributions from the individual GOQDs and PVK emissions. (Sci Rep., 5, 11032, 2015). New III-V colloidal quantum dots (CQDs) were synthesized using the hot-injection method and the QD-light emitting diodes (QLEDs) using these CQDs as emissive layer were demonstrated for the first time. The band gaps of the III-V CQDs were varied by varying the metal fraction and by particle size control. The X-ray absorption fine structure (XAFS) results show that the crystal states of the III-V CQDs consist of multi-phase states; multi-peak photoluminescence (PL) resulted from these multi-phase states. Inverted structured QLED shows green EL emission and a maximum luminance of ~45 cd/m2. This result shows that III-V CQDs can be a good substitute for conventional cadmium-containing CQDs in various opto-electronic applications, e.g., eco-friendly displays. (Un-published results).

• Journal of Radiation Protection and Research
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• 제29권4호
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• pp.263-268
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• 2004

한국원자력연구소에서 감마선과 전자를 동시측정하기 위한 목적으로 제작된 Prototype phowich를 이용하여 감마선에 대한 섬광체의 비선형성에 대한 연구를 수행하였다. 제작된 Prototype phoswich는 $2'{\times}2'$ CsI(Tl)와 Plastic scintillator 그리고 하나의 PMT로 구성되어 있다. 몬테칼로 방법을 이용하여 $^{137}Cs$과 $^{60}Co$ 선원의 Prototype phoswich 계측기의 반응함수(Detector Response Function, 이하 DRF)를 구하였으며 이를 점증하기 위하여 제작된 Prototype phoswich를 이용, 실험을 통하여 DRF를 구한 뒤 비교하였다. 계측기의 DRF를 정확하게 모사하기 위하여 CsI(Tl) 섬광체의 Electron response와 섬광체 내에서의 광전효과를 고려하는 Simplified elec윤on cascade sequence 정보를 이용하여 CsI(Tl) 섬광체의 감마선에 대한 비선형성을 계산하였다. $^{137}Cs$ 선원의 경우 전산모사를 통하여 구한 DRF 결과는 실험값과 비교적 잘 일치함을 알 수 있었으나 $^{60}Co$의 경우에는 선원의 결과와는 달리 전산모사 결과와 실험값에 약간의 차이가 남을 알 수 있었다. 이는 $^{137}Cs$ 선원과는 달리 $^{90}Co$은 1.17 MeV와 1.13 MeV 두 개의 광자를 동시에 방출하기 때문에 동시효과에 의한 불착실성 등이 그 외 다른 불확실성 등과 함께 증폭되어 나타나기 때문이다. 본 연구를 통해 Phoswich내 CsI(Tl)의 감마선 비선형성에 대한 분석을 수행하였으며 이를 통하여 비선형성이 고려된 개선된 Phoswich DRF를 생산하고 이를 실험값과 비교 검증할 수 있었다. 섬광체의 Electron channel운g effect, Doppler broadening effect 및 Transfer resolution 등과 같은 후속연구가 추가된다면 좀더 정확한 Phoswich의 DRF를 전산 모사하는 것이 가능해질 것이다.