• Economic and Environmental Geology
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• v.28 no.3
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• pp.287-303
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• 1995

Tungsten ore deposits in China show clearly their relationship between granitoids and orebodies. All kinds of different tungsten ore deposits, having the largest ore reserves in the world, occur in China. Major tungsten deposits in 1950'years were locally confined in three provinces such as Jiangxi, Hunan and Guangdong. However, the major tungsten ore deposits are replaced by new tungsten deposits such as Sandahozhuang, Xingluokeng, Shizhuan and Daminghsan deposit which may be larger than the previous major deposits. Tungsten ore deposits of China exhibit obviously the granitoid was the ore-bringer to form tungsten ore deposits. The wolframite-bearing quarz veins in China indicate that tungsten mineralization took place by crystallization of wolframite preferentially unless $Ca^{{+}{+}}$ was introduced from outside into the magma-origin-fluid, since it is understood that the scheelite in the Sangdong ore deposit was preferentially precipitated, because of chemical affinity, from the tungsten fluid in which Fe and Ca ions were as sufficient as to form magnetite, wolframite and scheelite. Tungsten deposits in the world are divided into two systems; W-Mo-Sn system and W-Mo system. Most of tungsten deposits in China dated to about 196-116 Ma belong to the W-Mo-Sn system, while late Cretaceous tungsten deposits such as the Sangdong deposit in Korea belongs to the W-Mo system. The genetic order of tin-tungsten-molybdenum mineralization observed in the Moping tungsten mine in China and the Sangdong in Korea may be attributed to volatile pressures in the same magma chamber. It is assumed from ages of tungsten mineralizations that ore elements such as tin, tungsten and molybdenum might be generated periodically by nuclear fission and fusion in a part of the mantle and the element generated was introduced into the magma chamber. The periodical generation of elements had determined association, depletion and enrichment of tin and molybdenum in tungsten mineralization and it results in little association of cassiterite in tungsten deposit of late Cretaceous ages. Different mechanism of emplacement of the ore-bearing magma has brought various genetic types of tungsten deposits as shown in China and the world.

• Journal of Powder Materials
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• v.28 no.4
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• pp.342-351
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• 2021

Because of its unique properties, tungsten is a strategic and rare metal used in various industrial applications. However, the world's annual production of tungsten is only 84000 t. Ammonium paratungstate (APT), which is used as the main intermediate in industrial tungsten production, is usually obtained from tungsten concentrates of wolframite and scheelite by hydrometallurgical treatment. Intermediates such as tungsten trioxide, tungsten blue oxide, tungstic acid, and ammonium metatungstate can be derived from APT by thermal decomposition or chemical attack. Tungsten metal powder is produced through the hydrogen reduction of high-purity tungsten oxides, and tungsten carbide powder is produced by the reaction of tungsten powder and carbon black powder at 1300-1700℃ in a hydrogen atmosphere. Tungsten scrap can be divided into hard and soft scrap based on shape (bulk or powder). It can also be divided into new scrap generated during the production of tungsten-bearing goods and old scrap collected at the end of life. Recycling technologies for tungsten can be divided into four main groups: direct, chemical, and semi-direct recycling, and melting metallurgy. In this review, the current status of tungsten smelting and recycling technologies is discussed.

• Economic and Environmental Geology
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• v.12 no.3
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• pp.127-146
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• 1979

Though tungsten minerals have been mined for over fifty years in Korea, which has become one of the worlds largest tungsten producers since 1951, knowledge of their mineralogy and geochemistry is somewhat limited to the school of tungsten students. There is a considerable amount of literature throughout the world on the tungsten mineralogy, the geochemical behaviour of tungsten, the nature of tungsten deposits and geological environments for tungsten mineralisation. Commonly known tungsten minerals such as scheelite and wolframite belong to one of two series, the scheelite or the wolframite series, as the primary tungsten minerals. Secondary tungsten minerals are known rather rare, however, some of them plays an important role-of exploration guide in search for tungsten deposits. The geochemistry of tungsten is imperfectly known, and apparently the behaviour of tungsten in geological processes has been the subject of few studies. Recently, some aspects of the fundamental geochemistry of tungsten has been worked out and compiled the data in broad the up to date by many authors. In order to facilitate the better understanding and future exploration of tungsten deposits, an attempt has been made to summarise the existing knowledge of the fundamental geochemistry of tungsten, together with its common geochemical association with various types of tungsten deposits.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.654-655
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• 2006

This is about the effects deoxidization, carbonization and alloying preparation on fine grain W, WC, and grade YG8 powder reduced by "yellow tungsten oxide" and "blue tungsten oxide". The result indicates that yellow tungsten has single composition and blue tungsten oxide has complex composition. With this feature, yellow tungsten oxide got better uniformity and concentration distribution on fine particle size W and WC powder than blue tungsten oxide's. The grade alloy YG8 that made of this W or WC powder has uniform alloy construction, concentrated WC grain distribution and better alloy properties.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.200.1-200.1
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• 2016

Tungsten coatings on the graphite (CX-2320) were successfully deposited using the vacuum plasma spraying (VPS) method. An optimum coating procedure was developed and coating thicknesses of $409{\mu}m$ (without an interlayer) and $378{\mu}m$ (with an interlayer) were obtained with no cracks and no signs of delamination. The mechanical characteristics and microstructure of the tungsten coating layers were investigated using a Vickers hardness tester, FE-SEM, EDS, and XRD. The effect of a titanium interlayer on the properties of the tungsten coating was investigated. It was shown that the titanium interlayer prevented the diffusion of carbon to the tungsten layer, thereby suppressing the formation of tungsten carbide. Vickers hardness data yielded values that were 62.5 ~ 80.46% of those for bulk tungsten, indicating that tungsten coatings on graphite can be utilized as a plasma-facing material. High heat flux tests were performed by using thermal plasma with a maximum flux of $10MW/^2$. Vickers hardness after the heat flux test is performed to see a change in the mechanical properties. The formationof a tungsten carbide and the effect of the titanium interlayer for the diffusion barrier are investigated by using energy dispersion spectroscopy (EDS).

• Economic and Environmental Geology
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• v.28 no.6
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• pp.613-621
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• 1995

It is understood that many big tungsten deposits such as the Sangdong in Korea, Fugigatami in Japan, Yukon in Canada, Pine Creek in U.S.A and Vostok in Russia were formed at late Cretaceous ages. However, most of tungsten mineralization in China where half the total world tungsten ores is reserved took place in late Jurassic to early Cretaceous ages. While the close association of molybdenum with tungsten mineralization is observed in the deposits related with Cretaceous magma, tungsten deposits in China related with late Jurassic to early Cretaceous show a close association of tin as well as molybdenum mineralization. It is characteristic that tungsten mineralization in China was followed by tin mineralization. The mode of occurrence of tungsten ore deposits in China is various and may represent the origin of tungsten in general, since the larger half of total amount of tungsten ores in the world are reserved in China. In case of Korea, more than 90% of total production of tungsten was occupied by the Sangdong tungsten deposit, which produced molybdenite as a byproduct Even if tin is detected in ppm unit content, no cassiterite is found in the Sangdong tungsten orebody. A similar type of two tungsten deposits is comparatively studied in order to confirm the published data; one is the Moping tungsten deposit in China and the other is the Dehwa tungsten deposit in Korea. Mineral assemblages occurring in quartz veins of both deposits are more or less same except that zinnwaldite and cassiterite occur only in the former deposit Ages of zinnwaldite and muscovite closely with molybdenite in the former deposit are 181.1 Ma and 167.8 Ma respectively, while muscovites associated with molybdenite in the latter deposit show ages of 80.9 Ma and 80.2 Ma. These results may represent deficient supply of tin from the source granitoid from which tungsten was derived in Korean peninsula during Cretaceous period, while tin supplied during tungsten mineralization tended to increase and the active tin mineralization followed the Jurassic tungsten mineralization in China.

• Journal of Powder Materials
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• v.23 no.5
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• pp.372-378
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• 2016

This study focuses on the development of an alkaline leaching hydrometallurgy process for the recovery of tungsten from WC/Co hardmetal sludge, and an examination of the effect of the process parameters on tungsten recovery. The alkaline leaching hydrometallurgy process has four stages, i.e., oxidation of the sludge, leaching of tungsten by NaOH, refinement of the leaching solution, and precipitation of tungsten. The WC/Co hardmetal sludge oxide consists of $WO_3$ and $CoWO_4$. The leaching of tungsten is most affected by the leaching temperature, followed by the NaOH concentration and the leaching time. About 99% of tungsten in the WC/Co hardmetal sludge is leached at temperatures above $90^{\circ}C$ and a NaOH concentration above 15%. For refinement of the leaching solution, pH control of the solution using HCl is more effective than the addition of $Na_2S{\cdot}9H_2O$. The tungsten is precipitated as high-purity $H_2WO_4{\cdot}H_2O$ by pH control using HCl. With decreasing pH of the solution, the tungsten recovery rate increases and then decrease. About 93% of tungsten in the WC/Co hardmetal sludge is recovered by the alkaline leaching hydrometallurgy process.

• Journal of the Korean Ceramic Society
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• v.34 no.6
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• pp.601-610
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• 1997

In cofiring of multilayered alumina with tungsten, the change of camber with lamination condition was experimented and the effect of sintering shrinkage of alumina and tungsten was investigated. From the exact measurement of sintering shrinkage of tungsten thick film, as lamination pressure increased, the sintering shrinkage of alumina decreased but that of tungsten thick film was not changed. So it was though that the main factor which induced the sintering shrinkage difference between ceramics and metal with lamination condition was the change of sintering shrinkage of ceramics. In case of high lamination pressure, high green sheet density, the cofired specimen showed low camber due to low shrinkage difference between alumina and tungsten and there was a linear relation between camber and shrinkage difference. It was found that this shrinkage difference could change the thickness of tungsten film and the microstructure within via hole during cofiring.

• Tribology and Lubricants
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• v.30 no.4
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• pp.218-223
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• 2014

This paper presents a method of controlling the stiffness of a tungsten probe for an atomic force microscope (AFM) in order to provide high-quality phase contrast images in accordance with sample characteristics. While inducing sufficient deformation on sample surfaces with commercial Si or $Si_3N_4$ probes is difficult because of their low stiffness, a tungsten probe fabricated by electrochemical etching with appropriately high stiffness can generate relatively large elastic deformation without damaging sample surfaces. The fabrication of the tungsten probe involves two separate procedures. The first procedure involves immersing a tungsten wire with both ends bent parallel to the surface of an electrolyte and controlling the stiffness of the tungsten cantilever by decreasing its diameter using electrochemical etching in the direction of the central axis. The second procedure involves immersing the end of the etched tungsten cantilever in the direction perpendicular to the surface of the electrolyte and fabricating a tungsten tip with a tip radius of 20-50 nm via the necking phenomenon. The latter etching process applies pulse waves every 0.25 seconds to the manufactured tip to improve its yield. Finite element analysis (FEA) of the stiffness of the tungsten probe as a function of its diameter showed that the stiffness of the tungsten probes greatly varies from 56 N/m to 3501 N/m according to the cantilever diameters from $30{\mu}m$ to $100{\mu}m$, respectively. Thus, the proposed etching method is effective for producing a tungsten probe having specific stiffness for optimal use with an AFM and certain samples.

• Journal of the Korea Convergence Society
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• v.12 no.10
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• pp.129-136
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• 2021

Radiation shields used in medical institutions mainly use lead to manufacture products and fitments. Although lead has excellent processability and economic efficiency, its use is being reduced due to environmental issues when it is disposed of. In addition, when used for a long time, there is a limit to using it as a shielding film, shielding wall, medical device parts, etc. due to cracking and sagging due to gravity. To solve this problem, copper, tin, etc. are used, but tungsten is mostly used because there is a difficulty in the manufacturing process to control the shielding performance. However, it is difficult to compare with other shielding materials because the characteristics according to the type of tungsten are not well presented. Therefore, in this study, a medical radiation shielding sheet was manufactured in the same process using pure tungsten, tungsten carbide, and tungsten oxide, and the particle composition and shielding performance of the sheet cross-section were compared.As a result of comparison, it was found that the shielding performance was excellent in the order of pure tungsten, tungsten carbide, and tungsten oxide.