• Title/Summary/Keyword: Tungsten(W)

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Gas Sensing Characteristics of Ru doped-WO3 Micro Gas Sensors (루테늄이 첨가된 텅스텐 산화물을 이용한 마이크로 가스 센서의 암모니아 가스 감지 특성)

  • Lee, Hoi Jung;Yoon, Jin Ho;Kim, Bum Joon;Jang, Hyun Duck;Kim, Jung Sik
    • Korean Journal of Metals and Materials
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    • v.49 no.5
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    • pp.395-399
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    • 2011
  • In this study, micro gas sensors for ammonia gas were prepared by adopting MEMS technology and using a sol-gel process. Three types of sensors were prepared via different synthesis routes starting with W sol and Ru sol mixture. This mixture was deposited on a MEMS platform and the platform was subsegueny heated to a temperature of $350^{\circ}C$. The topography and crystal structure of the sensing film were studied using FE-SEM and XRD. The response of the gas sensor to $NH_3$ gas was examined at various operating temperatures and gas concentrations. The sensor response increased almost linearly with gas concentration and the best sensing response was obtained at $333^{\circ}C$ for 5.0 ppm $NH_3$ for the specimen prepared by coating $WO_3$ powders with the Ru sol mixture.

Electrochemical Behaviors of Bi3+ Ions on Inert Tungsten or on Liquid Bi Pool in the Molten LiCl-KCl Eutectic

  • Kim, Beom Kyu;Park, Byung Gi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.1
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    • pp.33-41
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    • 2022
  • Liquid Bi pool is a candidate electrode for an electrometallurgical process in the molten LiCl-KCl eutectic to treat the spent nuclear fuels from nuclear power plants. The electrochemical behavior of Bi3+ ions and the electrode reaction on liquid Bi pool were investigated with the cyclic voltammetry in an environment with or without BiCl3 in the molten LiCl-KCl eutectic. Experimental results showed that two redox reactions of Bi3+ on inert W electrode and the shift of cathodic peak potentials of Li+ and Bi3+ on liquid Bi pool electrode in molten LiCl-KCl eutectic. It is confirmed that the redox reaction of lithium with respect to the liquid Bi pool electrode would occur in a wide range of potentials in molten LiCl-KCl eutectic. The obtained data will be used to design the electrometallurgical process for treating actinide and lanthanide from the spent nuclear fuels and to understand the electrochemical reactions of actinide and lanthanide at liquid Bi pool electrode in the molten LiCl-KCl eutectic.

Surface grinding of WC-Co with high quality (WC-Co의 고품위 평면 연삭가공)

  • Heo, S.J.;Kang, J.H.;Kim, W.I.
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.5
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    • pp.42-55
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    • 1994
  • Presently, abrasive processing is on eof several methods for cutting and grinding brittle materials, and high quality in dimensional accuracy and surface roughness are often required as a structural components, therefore most of them has to be ground. In manufacturing of tungsten-carbide components, grinding by diamond wheel is usually adopted in order to provide configurational and dimensional accuracy to the components. The present study proposes the experi- mental research of optimum condition to the high quality surface grinding of the WC-Co material using diamond abrasive wheel in order to minimize the damage on the ground surface and to pursue the precise dimension by conventional grinding machine. Brief investigation is carried out to decrease the dressing is constant, theoretical grinding effect such as machining precision is changed according to the speed of workpiece. Accordingly, normal and tangential grinding forces, which are Fn, Ft were analyzed for the machining processes of WC-Co material to obtain optimum grinding conditions, 3-point bending test is carried out to check machining damage on the ground surface layer, which is one of sintered brittle materials.

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Design and optimization of thermal neutron activation device based on 5 MeV electron linear accelerator

  • Mahnoush Masoumi;S. Farhad Masoudi;Faezeh Rahmani
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4246-4251
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    • 2023
  • The optimized design of a Neutron Activation Analysis (NAA) system, including Delayed Gamma NAA (DGNAA) and Prompt Gamma NAA (PGNAA), has been proposed in this research based on Mevex Linac with 5 MeV electron energy and 50 kW power as a neutron source. Based on the MCNPX 2.6 simulation, the optimized configuration contains; tungsten as an electron-photon converter, BeO as a photoneutron target, BeD2 and plexiglass as moderators, and graphite as a reflector and collimator, as well as lead as a gamma shield. The obtained thermal neutron flux at the beam port is equal to 2.06 × 109 (# /cm2.s). In addition, using the optimized neutron beam, the detection limit has been calculated for some elements such as H-1, B-10, Na-23, Al-27, and Ti-48. The HPGe Coaxial detector has been used to measure gamma rays emitted by nuclides in the sample. By the results, the proposed system can be an appropriate solution to measure the concentration and toxicity of elements in different samples such as food, soil, and plant samples.

Development of Concentration Control System for Ni-W Alloy Plating Solution (니켈-텅스텐 합금 도금 공정액 농도 제어 시스템 개발)

  • Kong, Jung-Shik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.7
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    • pp.273-279
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    • 2016
  • This paper deals with a control system with a concentration sensor for Ni-W alloy plating solutions. The printed circuit board market has increased with the development of the electronics industry. Gold consumption has also increased dramatically. Various studies of composite plating solutions have been conducted because of the expense of gold. In comparison, the development of sensors capable of measuring a composite plating solution in real-time is still insufficient. Furthermore, there are few systems that can measure and control the concentration of the solution precisely. This study developed a sensor and system to control the concentration of composite plating solution accurately. The sensors were developed based on a spectrophotometric method and a feedback control method was applied in this system.

Manufacturing Functional Nano-Composites by Using Field-Aided Micro-Tailoring Manipulation (Field-Aided Micro-Tailoring에 의한 기능성 나노복합재 제조)

  • Cho, Hee-Keun;Rhee, Juhun;Sim, Eun-Sup
    • Composites Research
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    • v.25 no.6
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    • pp.178-185
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    • 2012
  • One of a unique technique in manipulating a multifunctional composite is demonstrated in this study. An electric field is applied to a liquid suspension in order to align the inclusions along with the direction electric field. This is called FAiMTa(Field Aided Micro Tailoring). It makes orthotropic polymer composites by arranging the micro and/or nano size particle inclusions in chain-line formation. Several kinds of particles such as $Al_2O_3$, graphite, CNT(Carbon Nano Tube), W(Tungsten) are tested to verify the effectiveness of the FAiMTa. The particles redistributed in an epoxy suspension and their coupons show that mechanical and thermal properties of orthotropic and random composites containing those particles depend on the trend of particles' alignment. The micro-images of the functional composite from FAiMTa have been captures and their physical properties demonstrate their wide-range and state-of-the-art application for advanced multifunctional composites.

Analysis of the Effect on the Performance of Ceramic Metal Halide Lamp by the Loss of Elements that have been Filled in Arc Tube (아크튜브내의 구성물 손실이 세라믹 메탈 핼라이드 램프의 특성에 미치는 영향분석)

  • Jang, Hyeok-Jin;Yang, Jong-Kyung;Park, Dae-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2446-2452
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    • 2009
  • A Ceramic Metal-halide lamp is achieved by adding multiple metals to a basic mercury discharge. Because the vapor pressure of most metals is very much lower than mercury itself, metal-halide salts of the desired metals, having higher vapor pressures, are used to introduce the material into the basic discharge. The metal compounds are usually polyatomic iodides, which vaporize and subsequently dissociate as they diffuse into the bulk plasma. Metals with multiple visible transitions are necessary to achieve high photometric efficiency and good color. Compounds of Sc, Dy, Ho, Tm, Ce, Pr, Yb and Nd are commonly used. The maximum visible efficacy of a Ceramic Metal Halide lamp, under the constant of a white light source, is predicted to be about 450lm/W. This is controlled principally by the chemical fill chosen for a particular lamp. Current these lamps achieve 130lm/W and these life time are the maximum 16,000[hr]. So factors of performance lower are necessary to improve lamp performance. In this paper, we analyzed factors of performance lower by accelerated deterioration test. The lamp was operated with short duration turn-on/turn-off procedure to enhance the effect due to electrode sputtering during lamp ignition. The tested lamp that was operated with a longer turn-on/off(20/20 minutes) showed blackening, changed distance between electrodes and lowered color rendering & color temperature by losses of Dy at 421.18nm, I at 511nm, T1 at 535nm and Na at 588nm compared with the new lamp.

High $f_T$ 30nm Triple-Gate $In_{0.7}GaAs$ HEMTs with Damage-Free $SiO_2/SiN_x$ Sidewall Process and BCB Planarization

  • Kim, Dae-Hyun;Yeon, Seong-Jin;Song, Saegn-Sub;Lee, Jae-Hak;Seo, Kwang-Seok
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.4 no.2
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    • pp.117-123
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    • 2004
  • A 30 nm $In_{0.7}GaAs$ High Electron Mobility Transistor (HEMT) with triple-gate has been successfully fabricated using the $SiO_2/SiN_x$ sidewall process and BCB planarization. The sidewall gate process was used to obtain finer lines, and the width of the initial line could be lessened to half by this process. To fill the Schottky metal effectively to a narrow gate line after applying the developed sidewall process, the sputtered tungsten (W) metal was utilized instead of conventional e-beam evaporated metal. To reduce the parasitic capacitance through dielectric layers and the gate metal resistance ($R_g$), the etchedback BCB with a low dielectric constant was used as the supporting layer of a wide gate head, which also offered extremely low Rg of 1.7 Ohm for a total gate width ($W_g$) of 2x100m. The fabricated 30nm $In_{0.7}GaAs$ HEMTs showed $V_{th}$of -0.4V, $G_{m,max}$ of 1.7S/mm, and $f_T$ of 421GHz. These results indicate that InGaAs nano-HEMT with excellent device performance could be successfully fabricated through a reproducible and damage-free sidewall process without the aid of state-of-the-art lithography equipment. We also believe that the developed process will be directly applicable to the fabrication of deep sub-50nm InGaAs HEMTs if the initial line length can be reduced to below 50nm order.

A Study on the NH3-SCR Activity of the VWSbTi According to the Calcination Temperature of WSbTi (WSbTi의 소성온도에 따른 VWSbTi 촉매의 NH3-SCR 효율 연구)

  • Eo, Eun Gyeom;Shin, Jung Hun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.64-70
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    • 2022
  • In this study, an experiment was performed by adding Sb during NH3-selective catalytic reduction (NH3-SCR) while varying calcination temperatures from 400 to 700 ℃ to improve the low temperature denitrification efficiency of VWTi catalyst. As a result, VWSbTi(500) and VWSbTi(600) catalysts corresponding to Sb calcination temperatures of 500~600 ℃ showed the best denitrification performance at low temperatures below 300 ℃. BET, XRD, Raman, XPS, H2-TPR, and NH3-TPD analyses were performed In order to confirm physicochemical properties according to the calcination temperature. In the case of VWSbTi(500) and VWSbTi(600), an acid site increased with the generation of W=O species, and superb activity at low temperatures was exhibited due to the excellent redox characteristics and increase in electron density of tungsten. Furthermore, in the case of VWSbTi(700), as the crystalline V2O5 structure was formed, the denitrification efficiency decreased. Thus the optimum calcination temperature during Sb addition process was confirmed.

Influence of Substrate Bias Voltage on the Electrical and Optical Properties of IWO Thin Films (기판 인가 전압에 따른 IWO 박막의 전기적, 광학적 특성)

  • Jae-Wook Choi;Yeon-Hak Lee;Min-Sung Park;Young-Min Kong;Daeil Kim
    • Korean Journal of Materials Research
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    • v.33 no.9
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    • pp.372-376
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    • 2023
  • Transparent conductive tungsten (W) doped indium oxide (In2O3; IWO) films were deposited at different substrate bias voltage (-Vb) conditions at room temperature on glass substrates by radio frequency (RF) magnetron sputtering and the influence of the substrate bias voltage on the optical and electrical properties was investigated. As the substrate bias voltage increased to -350 Vb, the IWO films showed a lower resistivity of 2.06 × 10-4 Ωcm. The lowest resistivity observed for the film deposited at -350 Vb could be attributed to its higher mobility, of 31.8 cm2/Vs compared with that (6.2 cm2/Vs) of the films deposited without a substrate bias voltage (0 Vb). The highest visible transmittance of 84.1 % was also observed for the films deposited at the -350 Vb condition. The X-ray diffraction observation indicated the IWO films deposited without substrate bias voltage were amorphous phase without any diffraction peaks, while the films deposited with bias voltage were polycrystalline with a low In2O3 (222) diffraction peak and relatively high intensity (431) and (046) diffraction peaks. From the observed visible transmittance and electrical properties, it is concluded that the opto-electrical performance of the polycrystalline IWO film deposited by RF magnetron sputtering can be enhanced with effective substrate bias voltage conditions.