• Title/Summary/Keyword: Tridentate

Search Result 62, Processing Time 0.025 seconds

Coordination Polymers Consisting of Unusual Motifs. Synthesis and Properties of Silver(I) and Copper(II) Complexes of Triethanolaminetriisonicotinate

  • Noh, Tae-Hwan;Lee, Jung-Woon;Lee, Young-A;Lee, Ji-Eun;Lee, Shim-Sung;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
    • /
    • v.29 no.3
    • /
    • pp.562-566
    • /
    • 2008
  • Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO3)3 and the same treatment of Cu(NO3)2 with L gives 1D coordination polymer of [Cu(L)2](NO3)2. The nonrigid triethanolaminetriisonicotinate acts as a m 3-bridged tridentate for [Ag3(L)2](NO3)3 and a m 2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3- anions can be smoothly exchanged by PF6- anions in an aqueous suspension without destruction of the skeletal structure.

Manipulation of Absorption Maxima by Controlling Oxidation Potentials in Bis(tridentate) Ru(II) N-Heterocyclic Carbene Complexes

  • Kim, Hyeong-Mook;Jeong, Daero;Noh, Hee Chang;Kang, Youn K.;Chung, Young Keun
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.2
    • /
    • pp.448-456
    • /
    • 2014
  • A series of seven Ru(II) complexes bearing NHC ligands have been synthesized. The electronic structures of these complexes were analysed by spectroscopic and electrochemical methods and further examined by theoretical calculations. Data show that absorption maxima are dependent on the HOMO level rather than the HOMO-LUMO gaps.

Synthesis, Characterization and Spectrophotometric Studies of Seven Novel Antibacterial Hydrophilic Iron(II) Schiff Base Amino Acid Complexes

  • Shaker, Ali M.;Nassr, Lobna A.E.;Adam, Mohamed S.S.;Mohamed, Ibrahim M.A.
    • Journal of the Korean Chemical Society
    • /
    • v.57 no.5
    • /
    • pp.560-567
    • /
    • 2013
  • A series of new Iron(II) Schiff base amino acid complexes derived from the condensation of amino acid and sodium 2-hydroxybenzaldehyde-5-sulfonate have been synthesized. The complexes were characterized by elemental, electronic, IR spectral analyses and conductance measurements. The stability and solubility of the prepared complexes were determined. Two spectral methods used to determine the stoichiometry of the prepared complexes which exhibited divalent tridentate coordination and formed chelates of octahedral structures. The antibacterial activity of the prepared complexes has been tested against Bacillus cereus, Pseudomonas aeruginosa and Micrococcus bacteria. The effect of HCl on investigated complexes studied spectrophotometrically.

Copper(II), Nickel(II) and Palladium(II) Complexes of 2-Oximino-3-thiosemicarbazone-2,3-butanedione

  • Al-Kubaisi, Abdulla H.
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.1
    • /
    • pp.37-41
    • /
    • 2004
  • A new tridentate ligand incorporating a monoxime and thiosemi-carbozone moieties has been synthesized. Its copper(II), nickel(II) and palladium(II) complexes have been prepared and characteirzed by physical and spectral methods. Elemental analyses and spectroscopic data of the metal complexes are consistent with the formation of a mononuclear copper(II) complex and binuclear complex with both nickel(II) and palladium(II). In the copper(II) complex the fourth coordination site is occupied by nitrate ion. In the binculear complexes the fourth coordination site is occupied by the deprotonated oxime oxygen of the ligand coordinated to the other metal.

Synthesis and Characterization of Volatile and Thermally Stable Europium β-Diketonate Complexes

  • 강성주;정영숙
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.1
    • /
    • pp.75-80
    • /
    • 1997
  • Preparation and properties of Eu(hfa)3·L (Hhfa = hexafluoroacetylacetone, L = bis(2-methoxyethyl)ether, diglyme, and 2, 2':6', 2"-terpyridine, tpy), which are potential CVD precursors for europium, were investigated. The reaction of the Eu2O3 with Hhfa in the presence of tridentate neutral ligand yielded the nine-coordinated Eu(hfa)3·L. Eu(hfa)3·diglyme is air- and moisture-stable and most importantly has good volatility and thermal stability. Eu(hfa)3·tpy shows no sublime intact. The complex Eu(hfa)3·diglyme has been characterized by an X-ray structure determination; monoclinic P21/n, a=10.252(1), b=16.051(6), c=19.392(8) Å, β=96.10(2)°, V=3173(2) Å3. The europium atom in Eu(hfa)3·diglyme adopts a square-antiprismatic geometry with the ninth coordinating oxygen atom capping one of the square faces. All the adducts have been characterized by IR, TGA/DTA.

Two Newly Recorded Spionid Species (Polychaeta: Spionidae) in Korean Fauna, with New Record of the Genus Malacoceros

  • Lee, Geon Hyeok;Choi, Hyun Ki;Yoon, Seong Myeong
    • Animal Systematics, Evolution and Diversity
    • /
    • v.35 no.4
    • /
    • pp.161-167
    • /
    • 2019
  • Two new records of spionid polychaetes, Malacoceros reductus Blake & Kudenov, 1978 and Pseudopolydora cf. kempi (Southern, 1921), collected from Korean waters are reported here with detailed descriptions and illustrations. Malacoceros reductus, only reported in New South Wales, Australia, is distinguishable from its relatives by a prostomium with lateral horns, reduction of chaetiger 1, and the presence of the tridentate hooded hooks. Pseudopolydora cf. kempi, which has been known to have a wide geographical distribution, is characterized by a prostomium incised anteriorly, the presence of the occipital antenna, and two rows of black spots on the dorsal side. In this paper, photographs of scanning electron microscopy for characteristic features of each species are presented.

First Record of Magelona parochilis (Annelida: Magelonidae) in South Korea

  • Lee, Ha-Eun;Lee, Geon Hyeok;Min, Gi-Sik
    • Animal Systematics, Evolution and Diversity
    • /
    • v.38 no.4
    • /
    • pp.149-156
    • /
    • 2022
  • The magelonid polychaete Magelona parochilis Zhou and Mortimer, 2013 is newly reported from South Korea. The Korean specimens correspond well to the original description of M. parochilis in having prostomium without horn, mucronate chaetae on chaetiger 9, superior dorsal lobes on chaetigers 1-8, ventral neuropodial lobes on chaetiger 9, smooth edged thoracic notopodial lamellae, and unidirectional tridentate hooded hooks on abdominal chaetigers. Partial sequences of cytochrome c oxidase I (COI) and 16S ribosomal DNA (16S rDNA) of the species were determined from Korean specimens. The detailed description and illustrations are provided with partial sequences of COI and 16S rDNA as molecular markers for species identification.

A New Report of Prionospio kirrae (Annelida: Spionidae) from Korea

  • Lee, Geon Hyeok;Min, Gi-Sik
    • Animal Systematics, Evolution and Diversity
    • /
    • v.38 no.2
    • /
    • pp.91-97
    • /
    • 2022
  • Spionid polychaete Prionospio kirrae Wilson, 1990 is newly reported from the Yellow Sea in Korea. This species is characterized by four pairs of branchiae, which are apinnate on chaetigers 2-4 and pinnate on chaetiger 5, a caruncle extending to the posterior end of chaetiger 1, the presence of a distinctly high dorsal crest on chaetiger 11, and the presence of tridentate hooded hooks with rounded apical teeth. Sequences of partial mitochondrial cytochrome c oxidase subunit I (COI), 16S ribosomal DNA(16S rDNA), and the nuclear 18S ribosomal DNA(18S rDNA) of the species are determined from Korean specimens.

A newly recorded sea urchin, Araeosoma owstoni Mortensen, 1904 (Echinoidea; Echinothurioida; Echinothuriidae), from the Korea Strait

  • Lee, Taekjun;Shin, Sook
    • Journal of Species Research
    • /
    • v.11 no.3
    • /
    • pp.188-193
    • /
    • 2022
  • Araeosoma owstoni Mortensen, 1904, a newly recorded sea urchin, was collected from the Korea Strait by trawling during a research expedition in April 2017. The specimen was damaged and was severely peeled off on the aboral side during trawling. However, a test and the surface of the oral side of the sample were well preserved, allowing us to successfully identify it. The species was distinguished by the large and flexible test, the tiny apical section, and the interambulacra width which is twice of the ambulacra. Pedicellaria tridentate and triphyllous were presents, but tetradactyle pedicellaria was absent due to severe peeling on the aboral side. Moreover, a length of 1,212 bp sequence from mitochondrial COI gene was obtained and this sequence covered the general DNA barcoding region. The mean of interspecific divergence within A. owstoni from Korea and other eight species of Araeosoma from the GenBank was 6.8%. This value indicated that our species was clearly distinguishable from the others. Thus, the first Araeosoma species occurring in South Korea is presented in this study.