• Title/Summary/Keyword: Trapped volume

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VOID DEFECTS IN COBALT-DISILICIDE FOR LOGIC DEVICES

  • Song, Ohsung;Ahn, Youngsook
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.389-392
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    • 1999
  • We employed cobalt-disilicide for high-speed logic devices. We prepared stable and low resistant $CoSi_2$ through typical fabrication process including wet cleaning and rapid thermal process (RTP). We sputtered 15nm thick cobalt on the wafer and performed RTP annealing 2 times to obtain 60nm thick $CoSi_2$. We observed spherical shape voids with diameter of 40nm in the surface and inside $CoSi_2$ layers. The voids resulted in taking over abnormal junction leakage current and contact resistance values. We report that the voids in $CoSi_2$ layers are resulted from surface pits during the ion implantation previous to deposit cobalt layer. Silicide reaction rate around pits was enhanced due to Gibbs-Thompson effects and the volume expansion of the silicidation of the flat active regime trapped dimples. We confirmed that keeping the buffer oxide layer during ion implantation and annealing the silicon surface after ion implantation were required to prevent void defects in CoSi$_2$ layers.

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The corrosion of aluminium alloy and release of intermetallic particles in nuclear reactor emergency core coolant: Implications for clogging of sump strainers

  • Huang, Junlin;Lister, Derek;Uchida, Shunsuke;Liu, Lihui
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1345-1354
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    • 2019
  • Clogging of sump strainers that filter the recirculation water in containment after a loss-of-coolant accident (LOCA) seriously impedes the continued cooling of nuclear reactor cores. In experiments examining the corrosion of aluminium alloy 6061, a common material in containment equipment, in borated solutions simulating the water chemistry of sump water after a LOCA, we found that Fe-bearing intermetallic particles, which were initially buried in the Al matrix, were progressively exposed as corrosion continued. Their cathodic nature $vis-{\grave{a}}-vis$ the Al matrix provoked continuous trenching around them until they were finally released into the test solution. Such particles released from Al alloy components in a reactor containment after a LOCA will be transported to the sump entrance with the recirculation flow and trapped by the debris bed that typically forms on the strainer surface, potentially aggravating strainer clogging. These Fe-bearing intermetallic particles, many of which had a rod or thin strip-like geometry, were identified to be mainly the cubic phase ${\alpha}_c-Al(Fe,Mn)Si$ with an average size of about $2.15{\mu}m$; 11.5 g of particles with a volume of about $3.2cm^3$ would be released with the dissolution of every 1 kg 6061 aluminium alloy.

Magnetic separation device for paramagnetic materials operated in a low magnetic field

  • Mishima, F.;Nomura, N.;Nishijima, S.
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.3
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    • pp.19-23
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    • 2022
  • We have been developing a magnetic separation device that can be used in low magnetic fields for paramagnetic materials. Magnetic separation of paramagnetic particles with a small particle size is desired for volume reduction of contaminated soil in Fukushima or separation of iron scale from water supply system in power plants. However, the implementation of the system has been difficult due to the needed magnetic fields is high for paramagnetic materials. This is because there was a problem in installing such a magnet in the site. Therefore, we have developed a magnetic separation system that combines a selection tube and magnetic separation that can separate small sized paramagnetic particles in a low magnetic field. The selection tube is a technique for classifying the suspended particles by utilizing the phenomenon that the suspended particles come to rest when the gravity acting on the particles and the drag force are balanced when the suspension is flowed upward. In the balanced condition, they can be captured with even small magnetic forces. In this study, we calculated the particle size of paramagnetic particles trapped in a selection tube in a high gradient magnetic field. As a result, the combination of the selection tube and HGMS (High Gradient Magnetic Separation-system) can separate small sized paramagnetic particles under low magnetic field with high efficiency, and this paper shows its potential application.

Effect of Ambient Temperature on the Distribution of Atmospheric Concentrations of Polycyclic Aromatic Hydrocarbons in the Vapor and Particulate Phases (대기 중 다환방향족탄화수소의 기체-입자상 농도분포에 미치는 주변 온도의 영향)

  • 백성옥;최진수
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.117-132
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    • 1998
  • The main purposes of this study are to investigate the distributional characteristics of polycyclic aromatic hydrocarbons (PAH) in the vapor and particulate phases in the ambient atmosphere, and to evaluate the effect of ambient temperature on the vapor-particle partitioning during the sampling period. A total of 64 samples were collected during a period of 1995 to 1996, using a medium-volume sampler with XAD-2 adsorbents and quartz fiber filters. Analyses of PAH were carried out using HPLC with UV and Fluorescence detections. In this study, a significant seasonal variation in the distributions was observed, reflecting the effect of ambient temperature on the vapor-particle partitioning of PAH. The relationship between the vapor-particle distributions of the 3 to 5 rings PAH and ambient temperature is considered to be well described using the Langmuir adsorption concept. The estimated empirical constants for each PAH in the relationship, particularly for the more volatile compounds, were also comparable with results from other studies. However, it is still difficult to accurately estimate the initial vapor-particle distribution of PAH in the ambient air, since it is not known to what extent the trapped vapours originated from the particles laden in the filter by being volatilized or from the air samples initially present in the vapour phase. The distribution factors for volatile PAH with 3 to 4 rings appeared to be comparable with those in the literature. It should be noted, however, that these distribution factors give information only about the distribution of PAH between the two phases under a specific sampling condition, and hence may provide only semi -quantitative information on the vapor-particle distributions in the atmosphere.

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Physical Environment Changes in the Keum River Estuary Due to Dike Gate Operation: III. Tidal Modulation of Low-salinity Water (하구언 수문 작동으로 인한 금강 하구역의 물리적 환경변화: III. 저염수의 조석동조)

  • Choi, Hyun-Yong;Kwon, Hyo-Keun;Lee, Sang-Ho
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.3
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    • pp.115-125
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    • 2001
  • To examine the movement of the freshwater discharged artificially into the estuary during ebbing period in the Keum River dike we observed surface salinity variations in three stations along the estuary channel in May 1998 and July 1997 and surface temperature and salinity along the ferry-route between Kunsan and Changhang during eighteen days in July 1999. Based upon the typical features of observed salinity variation, we analyzed the excursion and decay processes of the discharged water. When freshwater is discharged, the low-salinity water forms strong salinity front over the entire estuary width, which basically moves forth and back by tidal modulation along the channel, producing the sudden change of surface salinity with the front passage. Salinity distribution along the channel, which is deduced from time variation of mean salinity over the estuary width, after one tidal period from gate operation suggests that diluted low-salinity water is trapped to the front and surface salinity increases gradually toward the upstream region. This frontal distribution of salinity is interpreted to be produced by the sudden gate operation supplying and stopping of freshwater within about two hours. Daily repeat of freshwater discharge produces separation (double front) or merge between decaying and new-generated fronts depending on dike-gate opening time, and the front decays with salinity increasing if the freshwater supply is stopped more than two days. In addition, the observed fluctuations and deviations in surface salinity variation is explained in terms of the differences of fronts intensity, their transition time and temporal salinity front running along the channel, which can be generated due to artificial gate-operation for the discharging time and water volume in the estuary dike.

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Superconducting Properties of Large Single Grain Gd1.5Ba2Cu3O7-y Bulk Superconductors (대면적 단결정 Gd1.5Ba2Cu3O7-y 벌크 초전도체의 초전도 특성)

  • Kim, Chan-Joong;Park, Seung Yeon;Kim, Kwang-Mo;Park, Soon-Dong;Jun, Byung-Hyuk
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.569-574
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    • 2012
  • Large single grain $Gd_{1.5}Ba_2Cu_3O_{7-y}$ (Gd1.5) bulk superconductors were fabricated by a top-seeded melt growth (TSMG) process using an $NdBa_2Cu_3O_{7-y}$ seed. The seeded Gd1.5 powder compacts with a diameter of 50 mm were subjected to the heating cycles of a TSMG process. After the TSMG process, the diameter of the single grain Gd1.5 compact was reduced to 43 mm owing to the volume contraction during the heat treatment. The superconducting transition temperature ($T_c$) of the top surface of the single grain Gd1.5 sample was as high as 93.5 K. The critical current densities ($J_cs$) at 77 K and 1T and 1.5 T were in ranges of 25,200-43,900 $A/cm^2$ and 10,000-23,000 $A/cm^2$, respectively. The maximum attractive force at 77 K of the sample field-cooled using an Nd-B-Fe permanent magnet (surface magnetic field of 0. 527 T) was 108.3 N; the maximum repulsive force of the zero field-cooled sample was 262 N. The magnetic flux density of the sample field-cooled at 77 K was 0.311T, which is approximately 85% of the applied magnetic field of 0.375 T. Microstructure investigation showed that many $Gd_2BaCuO_5$ (Gd211) particles of a few ${\mu}m$ in size, which are flux pinning sites of Gd123, were trapped within the $GdBa_2Cu_3O_{7-y}$ (Gd123) grain; unreacted $Ba_3Cu_5O_8$ liquid and Gd211 particles were present near the edge regions of the single grain Gd1.5 bulk compact.

Comparative assessment of urban stormwater low impact strategies equipped with pre-treatment zones (침강지 시설이 조성된 LID 시설의 환경적 영향평가)

  • Yano, K.A.V.;Reyes, N.J.D.G.;Jeon, M.S.;Kim, L.H.
    • Journal of Wetlands Research
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    • v.21 no.2
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    • pp.181-190
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    • 2019
  • Recently, Low impact development techniques, a form of nature-based solutions (NBS), were seen cost-efficient alternatives that can be utilized as alternatives for conventional stormwater management practices. This study evaluated the effectiveness of an infiltration trench (IT) and a small constructed wetland (SCW) in treating urban stormwater runoff. Long-term monitoring data were observed to assess the seasonal performance and cite the advantages and disadvantages of utilizing the facilities. Analyses revealed that the IT has reduced performance during the summer season due to higher runoff volumes that exceeded the facility's storage volume capacity and caused the facility to overflow. On the other hand, the pollutant removal efficiency of the SCW was impacted by the winter season as a result of dormant biological activities. Sediment data also indicated that fine and medium sand particles mostly constituted the trapped sediments in the pretreatment and media zones. Sediments in SCW exhibited a lower COD and TN load due to the phytoremediation and microbiological degradation capabilities of the system. This study presented brief comparison LID facilities equipped with pre-treatment zones. The identified factors that can potentially affect the performance of the systems were also beneficial in establishing metrics on the utilization of similar types of nature-based stormwater management practices.