• 멤브레인
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• 제22권1호
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• pp.1-7
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• 2012

니오븀 금속을 기반으로 하는 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막의 수소 투과 특성 및 화학적 안정성에 관한 연구를 수행하였다. 이를 위하여 직경 10 mm, 두께 0.5 mm의 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막을 제작하였으며, 2가지 조성($H_2$ 100%, $H_2$ 60% + $CO_2$ 40%)의 공급가스를 $450^{\circ}C$의 온도에서 투과시킬 때 압력에 따른 수소 투과 특성에 관한 실험을 진행하였다. 본 실험에서의 최대 수소 투과량은 순수한 수소를 투과시킬 경우 절대압력 3 bar에서 $5.58mL/min/cm^2$로 나타났다. 또한 공급가스 조성에 따른 각각의 경우 모두 Sievert's law에 잘 부합하였으며, 이산화탄소와의 혼합가스 사용시, 투과량은 수소 분압 감소에 비례하여 감소하였다. 투과 실험 후 XRD 분석을 통하여 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막의 이산화탄소에 대한 화학적 안정성에 대한 실험을 수행하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.16-17
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• 2010

Molecular spintronics has attracted attentions, which combines molecular electronics with the spin degree of freedom in electron transport. Among various molecules as candidates of the molecular spintronics, single molecule magnet (SMM) is one of the most promising material. SMM molecules show a ferromagnetic behavior even as a single molecule and hold the spin information even after the magnetic field is turned off. Here in this report, we show the spin behavior of SMM molecules adsorbed on the Au surface by combining the observation of Kondo peak in the STS and ESR-STM measurement. Kondo resonance state is formed near the Fermi level when degenerated spin state interacts with conduction electrons. ESR-STM detects the Larmor frequency of the spin in the presence of a magnet field. The sample include $MPc_2$ and $M_2Pc_3$ molecules ($M\;=\;Tb^{3+}$, $Dy^{3+}$, and $Y^{3+}$ Pc=phthalocyanine) whose critical temperature as a ferromagnet reaches 40 K. A clear Kondo peak was observed which is originated from an unpaired electron in the ligand of the molecule, which is the first demonstration of the Kondo peak originated from electron observed in the STS measurement. We also observed corresponding peaks in ESR-STM spectra. [1] In addition we found that the Kondo peak intensity shows a clear variation with the conformational change of the molecule; namely the azimuthal rotational angle of the Pc planes. This indicates that the Kondo resonance is correlated with the molecule electronic state. We examined this phenomena by using STM manipulation technique, where pulse bias application can rotate the relative azimuthal angle of the Pc planes. The result indicates that an application of ~1V pulse to the bias voltage can rotate the Pc plane and the Kondo peaks shows a clear variation in intensity by the molecule's conformational change.

• Journal of Photoscience
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• 제12권1호
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• pp.33-39
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• 2005

Plants possess the ability to dissipate the excitation energy for the protection of photosynthetic apparatus from absorbed excess light. Heat dissipation is regulated by xanthophyll cycle in thylakoid membranes of chloroplasts. We investigated the mechanistic aspects of xanthophyll cycle-dependent photoprotection against low-temperature photoinhibition in plants. Using barley and rice as chilling-resistant species and sensitive ones, respectively, chilling-induced chlorophyll fluorescence quenching, composition of xanthophyll cycle pigments and mRNA expression of the zeaxanthin epoxidase were examined. Chilled barley plants exhibited little changes in chlorophyll fluorescence quenching either of photochemical or non-photochemical nature and in the photosynthetic electron transport, indicating low reduction state of PS II primary electron acceptor. In contrast to the barley, chilled rice showed a marked decline in those parameters mentioned above, indicating the increased reduction state of PS II primary electron acceptor. In addition, barley plants were shown to have a higher capacity to elevate the pool size of xanthophyll cycle pigments in response to cold stress compared to rice plants. Such species-dependent regulation of xanthophyll cycle activity was correlated with the gene expression level of cold-induced zeaxanthin epoxidase. Chilled rice plants depressed the gene expression of zeaxanthin epoxidase, whereas barley increased its expression in response to cold stress. We suggest that chilling-induced alterations in the pool size of xanthophyll cycle pigments related to its capacity would play an important role in regulating plant's sensitivity to chilling stress.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 춘계학술발표회 논문집
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• pp.167-168
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• 2012

Films of CrN, $Cr_{40}Zr_9N$, and $Cr_{31}Zr_{16}N$ were deposited on a steel substrate by closed field unbalanced magnetron sputtering, and their oxidation behaviors at $700^{\circ}C$ and $800^{\circ}C$ for up to 60h in air were investigated. All the deposited films were composed of the CrN phase. Zirconium atoms in $Cr_{40}Zr_9N$ and $Cr_{31}Zr_{16}N$ films partially dissolved in the CrN phase. They advantageously refined the columnar structure, reduced the surface roughness, and increased the microhardness. The CrN film displayed relatively good oxidation resistance, owing to the formation of the highly protective $Cr_2O_3$ on its surface. The $Cr_{40}Zr_9N$ and $Cr_{31}Zr_{16}N$ films oxidized to $Cr_2O_3$ as the major phase and ${\alpha}-ZrO_2$ as the minor one. They oxidized primarily by the inward transport of oxygen. The addition of Zr could not increase the oxidation resistance of the CrN film, because the formed $ZrO_2$ that was intermixed in the $Cr_2O_3$-rich oxide layer was oxygen permeable, and developed the compressive stress in the oxide scale owing to the volume expansion during its formation.

• 한국응용과학기술학회지
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• 제31권3호
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• pp.453-465
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• 2014

본 논문에서는 바이오매스로부터 급속열분해를 통해 난방용, 발전용 및 수송용 연료로 사용하기 위해 바이오오일을 생산하는 기술개발 현황을 나타내었다. 바이오매스를 작은 규모의 액체연료로 전환하기 위해 가장 효율적인 방법 중 하나는 급속열분해이다. 급속열분해를 통한 바이오오일은 $450^{\circ}C{\sim}600^{\circ}C$ 온도에서 바이오매스가 신속히 열분해 되어 증기 급냉를 위해 외부 산소가 없는 조건에서 생산된다. 이 바이오오일은 최초 건조 바이오매스 기준 최대 75 무게%까지 생산할 수 있지만, 일반적으로 60-75 무게% 수준이 적합하다. 본 연구에서는 바이오매스의 원료특성, 바이오오일 생산원리, 바이오오일의 특성 및 활용분야에 대한 최근의 개발현황을 살펴보았다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.145-145
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• 2010

In this paper, we report that the effects of hydrogen doping on the electrical and optical properties of typical transparent conducting oxide films such as ZnO and $SnO_2$ prepared by magnetron sputtering. Recently, density functional theory (DFT) calculations have shown strong evidence that hydrogen acts as a source of n-type conductivity in ZnO. In this work, the beneficial effect of hydrogen incorporation on Ga-doped ZnO thin films was demonstrated. It was found that hydrogen doping results a noticeable improvement of the conductivity mainly due to the increases in carrier concentration. Extent of the improvement was found to be quite dependent on the deposition temperature. A low resistivity of $4.0{\times}10^{-4}\;{\Omega}{\cdot}cm$ was obtained for the film grown at $160^{\circ}C$ with $H_2$ 10% in sputtering gas. However, the beneficial effect of hydrogen doping was not observed for the films deposited at $270^{\circ}C$. Variations of the electrical transport properties upon vacuum annealing showed that the difference is attributed to the thermal stability of interstitial hydrogen atoms in the films. Theoretical calculations also suggested that hydrogen forms a shallow-donor state in $SnO_2$, even though no experimental determination has yet been performed. We prepared undoped $SnO_2$ thin films by RF magnetron sputtering under various hydrogen contents in sputtering ambient and then exposed them to H-plasma. Our results clearly showed that the hydrogen incorporation in $SnO_2$ leads to the increase in carrier concentration. Our experimental observation supports the fact that hydrogen acting as a shallow donor seems to be a general feature of the TCOs.

• 대한원격탐사학회지
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• 제14권4호
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• pp.315-324
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• 1998

TOVS에 탑재된 마이크로파 센서(MSU)와 고감도 적외복사계(HIRS)로부터 도출한 총가강수량과 SSM/I 관측으로 계산한 총가강수량으로 일본에 상륙 후, 한일해협에서 열대성 저기압으로 약화된 태풍 월트(9407)와 1995년 처음 태풍으로 발달한 태풍 페이(9503)의 운동기간 중의 수증기장 변화를 조사하는데 사용하였는데, 이들로 태풍의 운동변화에 따른 수증기장 변화를 나타낼 수 있었다. 태풍 월트와 페이의 전가강수량장은 주로 한국과 일본을 향하여 다가옴에 따라, 그들의 강도를 유지하고 강화하는데 아주 중요한 역할을 하는 북서태평양 상에 수증기의 수평수송에 주로 좌우된다. 도출된 수증기장은 두 주요구름대가 월트와 페이가 다가오고 지나가는 동안 한반도와 일본상공의 강우대 임을 나타내는 두터운 대류운 형태와 유사함을 보였다. 그러나 도출된 TOVS 전가강수량의 값은 SSM/I 값과 비교할 때 상대적으로 과소평가되었음을 나타내었다.

• 대한원격탐사학회지
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• 제9권1호
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• pp.79-93
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• 1993

NOAA AVHRR의 MCSST를 이용하여 지형류의 상대속도를 추정하였으며 이것을 대한 해협에 적용하였다. 원격탐사는 관측시에 광범위한 지역에 대해서 동시성 및 반복성이 유지되기 때문에 해양현상을 연구하는 데 있어서 훌륭한 도구로써 쓰일 수 있다. 특히 AVHRR 자료는 높 은 분해능으로 인해서 선상관측 자료보다도 지형류를 더욱 정밀하게 구할 수 있다. 연구 결과에 의하면 1992년 4월에 대한해협 서수도에서의 상대속도는 골이 있는 해역에서 가장 크며 이때 유 속의 크기는 약 23.8cm/sec로 나타났다. 그러나 이 결과는 geopotential anomaly를 계산할 때 염 분의 효과를 무시한 만큼의 오류를 포함하고 있다. 또한 대한해협 서수도에서 지형류의 수송량은 약 0.3Sv이며 쓰시마와 골이 있는 해역 사이에서 수송량이 가장 큰 것으로 나타났다.

• 품질경영학회지
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• 제47권3호
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• pp.437-451
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• 2019

Purpose: The purpose of this study is to improve the quality of the PGM system by improving the structure and production process of slip-ring rotary joint for radar. Methods: The improvement measures for each cause are established through failure analysis of broken items. Specifically, changing in the housing to improve the heating system. Changing the transportation method to prevent damage to equipment during transport. Changing work process of the attenuator ring to prevent damage. etc. Results: The results of this study are as follows; improving the heating system reduces heat generated by the attenuator by about 7 degrees and obtain additional temperature margins. Reduction of defect rate because of adding X-band rotary joint run-out measurement test, ESS of slip-ring rotary joint and Transportation improvement(reinforced flight boxes, tube protection, etc). Getting stable VSWR values by improving work process of attenuator overheating due to a bad bonding process. Conclusion: Through this study, improvements were made to slip-ring rotary joint that failed repeatedly for various reasons. As a result of the application of the improvements, the same fault does not occur until now, so we can see that the quality of PGM has improved.

• 한국포장학회지
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• 제27권2호
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• pp.91-100
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• 2021

Agricultural corrugated fiberboard packaging boxes frequently experience damage due to loading and unloading, vibration during transport, and shock by dynamic distribution condition change. This study was carried out to estimate effect of vibration during distribution process on compression strength of corrugated fiberboard boxes for agricultural products. In order to identify the degradation caused by vibration, after box packaging the agricultural products(tangerine or cucumber), the natural frequencies of the packaging boxes were measured by varying the relative humidity(50, 70 and 90%) at 25℃ temperature. Various types of corrugated fiberboard boxes were packed with tangerines and cucumbers, and the PSD plot vibration tests were conducted by utilizing the actual vibration recording results of the Gyeongbu Expressway section between Seoul and Gimcheon. As a result of the experiment, the decrease in compression strength of the box was relatively low in DW-AB, and the decrease in compression strength of the SW-A 0201(RSC) type box was the highest at 20.49%. In particular, both SW-A and DW-AB showed low compression strength degradation rates for open folder type boxes. The moisture content varies depending on the type of the box or agricultural products, and the enclosed 0201(RSC) type box was generally higher than the open folder or bliss type box, which is believed to be the reason for the decrease in compression strength of RSC type box due to humidity. By the agricultural product, the percentage of decrease in compression strength of box packed with cucumbers was especially high.