• Title/Summary/Keyword: Transport temperature

검색결과 1,502건 처리시간 0.036초

Measurement of Electron-neutral Collision Frequency Using Wave-cutoff Method

  • 유광호;나병근;김대웅;이윤성;박기정
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.234-234
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    • 2011
  • Electron-neutral collision frequency is one of the important parameters in the plasma physics and in industrial plasma engineering. We can understand the momentum, energy, and charge transport properties of the plasma using electron-neutral collision frequency.[1] The wave-cutoff method is a diagnostic method for the electron density measurement, but the cutoff peak value depends on gas pressure. The wave-cutoff signal becomes unclear as increasing gas pressure. The reason of pressure dependence is that the electron-neutral collision disturbs electron motion so that microwave can propagate through plasma at plasma frequency.[2] Using the pressure dependence of wave-cutoff method we can find the electron-neutral collision frequency. At first we tried to confirm this method using well known gas such as Ar. The cutoff signal decrease as increasing gas pressure (the simulation result). The wave-cutoff signal is unclear at a gas pressure of 500 mTorr. (electron density $1.0{\times}10^{10}/cm^3$, electron temperature 1.7 eV, electron -neutral collision frequency~1 GHz). In this condition, the electron-neutral collision frequency is closed to the wave-cutoff frequency.

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친환경용매 기반의 술폰화 폴리아릴렌 에테르 술폰 랜덤 공중합체 Thin Film Composite 제조 (Preparation of Disulfonated Poly(arylene ether sulfone) Random Copolymer Thin Film Composite Membranes Using a Benign Solvent)

  • 이창현;제임스 맥그라스;베니프리만
    • 멤브레인
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    • 제24권4호
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    • pp.292-300
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    • 2014
  • 내염소성을 갖는 염제거공정용 술폰화 폴리아릴렌 에테르 술폰 랜덤 공중합체(SPAES) thin film composite (TFC)막이 모노글라임 용매를 이용하여 제조되었다. 모노글라임은 선택층인 SPAES만을 용해시키며, 다공성 폴리술폰(예 : Udel$^{(R)}$)층에 대해 비용해성을 지녀, TFC 제조를 위한 선택적 용매로 사용될 수 있다. 또한 개미산이나 디에틸글리콜과는 달리, 환경적으로 무해하며, 매우 낮은 끊는점을 지녔다는 점이 또 다른 장점이 될 수 있다. 다공성 Udel$^{(R)}$ 지지체 위에 코팅시, 코팅용액이 기공구조에 침투하여 유수량을 감소시키는 기공투과현상이 발생하는데, 이를 최소화하기 위해 지지체를 이소프로필알콜과 글리세린 혼합액에서 전처리 후에, 코팅-건조 공정을 통해 결함이 없는 SPAES TFC로 제조된다. 또한, SPAES 선택층의 술폰화도, 고정이온의 염상태 및 물리-화학적 가교효과를 SPAES TFC막을 통한 투과거동과 관련하여 관찰하였다.

유기금속분해 법에 의한 ITO 박막의 제조 및 특성 (Characterization of ITO Films Prepared by Metal Organic Decomposition)

  • 고성민;이병수
    • 한국재료학회지
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    • 제5권8호
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    • pp.1045-1049
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    • 1995
  • 유기금속분해법(MOD, Metal Organic Decomposition)에 의하여 ITO 박막을 제조하고 SnO$_2$의 조성과 소성온도의 변화에 따른 박막의 특성변화를 고찰하였다. SnO$_2$의 양이 변하여도 ITO는 In$_2$O$_3$의 결정구조를 유지하고 있었으며, 이로부터 Sn이 In자리를 치환하여 고용체를 형성함을 알 수 있었다. SnO$_2$를 9wt.% 첨가 하였을때 비저항이 2.5$\times$$10^{-3}$$\Omega$-cm로 가장 낮은 값을 보였으며, 이는 타 연구자들의 결과치 보다 약 10배정도 큰 값이다. 이러한 비저항값의 차이는 작은 입경으로 인한 이동도의 감소 때문인 것으로 판단되었다. 투광도는 SnO$_2$의 첨가량 및 소성온도에 크게 의존하지 않았으며 가시영역에서 90% 이상을 보였다. 광흡수단으로부터 계산된 optical energy gap은 4.51-4.96eV 이었다.

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Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구 (A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR)

  • 신종국;윤천석;김홍석
    • 한국자동차공학회논문집
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    • 제23권2호
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    • pp.199-207
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    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

고방사성 산화물핵연료의 해외수송방안 분석 (The Option Study of Oversea Shipment of DUPIC Fuel Elements to Canada)

  • 이호희;박장진;양명승;서기석
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.614-620
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    • 2003
  • 원자력연구소에서는 국내 원전에서 배출된 사용후핵연료를 IMEF M6 핫셀에서 건식 재가공하여 건식공정 산화물핵연료를 개발하였다. 개발된 핵연료의 성능을 검증하기 위해서는 실제 상용로와 동일한 고온고압 조건하에서 조사시험이 필요하나 국내에는 이러한 조사시설을 갖추지 못하고 있으므로 핵연료 성능의 검증이 어렵던 차에 한$\cdot$$\cdot$미 IAEA간의 국제공동연구 과제진도회의에서 AECL측은 중성자비를 받지 않고 캐나다 NRU에서 건식공정 산화물핵연료를 조사시험을 할 수 있다고 제안하였다. NRU 조사시험을 하고자 하는 핵연료는 건식공정 산화물핵연료봉 10개(약 6kgU)이며 운반물 분류등급에 따라 제7종 위험물로 핵분열성물질에 해당한다. 일반적으로 소량의 방사성물질을 운반할 경우에는 비용뿐 아니라 수송기간 측면에서 항공수송이 선박수송에 비해 유리한 것으로 알려져 있어 항공기를 이용한 건식공정 산화물핵연료의 해외 수송방안을 검토하였다. 검토결과, 현재 건식공정 산화물핵연료봉 10개를 운반할 수 있는 적절한 항공수송용 수송용기가 없어 항공수송이 불가능한 것으로 조사되었다. 선박을 이용한 해외 수송방안은 가능하나 이 경우에는 전용선박을 사용해야 함으로 비용이 많이 수요되는 것으로 분석되었다.

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기능성 무기물과 폴리올레핀계 수지의 정량적 혼합시스템에 의한 환경대응형 포장소재 개발 (Environment Corresponding Package by Quantitative Mixing System with Functional Inorganic Material and Polyolefin Resin)

  • 김희삼;임현주;박영미
    • 한국염색가공학회지
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    • 제21권1호
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    • pp.1-9
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    • 2009
  • A lot of research has been made over the recent decade to develop testing packages with antimicrobial properties to improve food safety. In this study, a new method, experimental device and technology for environmental corresponding packages of polypropylene (PP) film has been developed to provide effective temperature buffering during the transport/long-term storage of grains or foodstuffs from the supplier to the market. This quantitatively optimized mixing system enabled to produce PP films with the 700$\sim$1,400d (width;1.5$\sim$3mm, thickness;0.01$\sim$0.5mm). In the whole mixing systems, the finely-granulated inorganic illite and PP virgin chip for master batch (M/B) chip was calculated by digital measurement methods, and then the M/B chip for PP film was adapted through a air jet and PP grinding method. The prepared PP film was characterized with tensile strength and elongation, far infrared radiation (FIR) emissivity, antimicrobial activity and deodorization properties. The results revealed that the two differently grain-sized illite could be show homogeneously dispersed on PP chip surface, and as the increasing of illite content, the FIR emissivity and the anion emission rate of film was increasingly improved. In both of 325 and 1,500 mesh-sized illite contained PP chip, of course the antimicrobial activity was good. But the ultimate deodorization rate for ammonia gas of PP film were found to be approximately the same.

남극 크릴새우의 고액분리 기술개발 (Development of Solid/Liquid Separation Technique for Krill (Eupausia superba))

  • 오인환;장철환;김운걸;양상엽
    • 한국축산시설환경학회지
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    • 제17권1호
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    • pp.33-38
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    • 2011
  • 크릴새우의 고액분리효율을 규명하기 위하여 크릴새우를 해빙시킨 다음 고액분리기만 사용하였을 경우, 솔 (Brush) 분쇄기 또는 날 분쇄기로 크릴새우를 분쇄한 후 고액분리기를 사용하여 효율을 측정하였을 경우로 나누어 수행하였다. 고액분리기만으로 분리한 경우와 솔분쇄기와 날분쇄기로 분쇄한 후 고액 분리기를 적용한 결과 3차 시험에서 분리효율은 각각 46.2%, 60.2%, 60.4%를 나타내었다. 고액분리기만을 사용하였을 경우보다 날 분쇄기와의 조합에서 분리효율의 증가는 2차 시험에서 10.1%, 3차 시험에서 14.2%로 각각 나타났고, 처리용량은 4.2kg/min으로 되었다. 고액분리 전에 날분쇄기로 분쇄한 후 고액분리기로 분리하는 것이 이상적이라 판단된다.

비정질 산화물 반도체의 열전특성 (Transparent Amorphous Oxide Semiconductor as Excellent Thermoelectric Materials)

  • 김서한;박철홍;송풍근
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.52-52
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    • 2018
  • Only approximately 30% of fossil fuel energy is used; therefore, it is desirable to utilize the huge amounts of waste energy. Thermoelectric (TE) materials that convert heat into electrical power are a promising energy technology. The TE materials can be formed either as thin films or as bulk semiconductors. Generally, thin-film TE materials have low energy conversion rates due to their thinness compared to that in bulk. However, an advantage of a thin-film TE material is that the efficiency can be smartly engineered by controlling the nanostructure and composition. Especially nanostructured TE thin films are useful for mitigating heating problems in highly integrated microelectronic devices by accurately controlling the temperature. Hence, there is a rising interest in thin-film TE devices. These devices have been extensively investigated. It is demonstrated that transparent amorphous oxide semiconductors (TAOS) can be excellent thermoelectric (TE) materials, since their thermal conductivity (${\kappa}$) through a randomly disordered structure is quite low, while their electrical conductivity and carrier mobility (${\mu}$) are high, compared to crystalline semiconductors through the first-principles calculations and the various measurements for the amorphous In-Zn-O (a-IZO) thin film. The calculated phonon dispersion in a-IZO shows non-linear phonon instability, which can prevent the transport of phonon. The a-IZO was measured to have poor ${\kappa}$ and high electrical conductivity compared to crystalline $In_2O_3:Sn$ (c-ITO). These properties show that the TAOS can be an excellent thin-film transparent TE material. It is suggested that the TAOS can be employed to mitigate the heating problem in the transparent display devices.

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디젤엔진의 $NO_X$ 저감을 위한 SCR $DeNO_X$ 촉매의 모델링 및 성능해석 (Modeling and Performance Analysis of SCR $DeNO_X$ Catalyst for Reducing $NO_X$ Emissions in Diesel Engine)

  • 김영득;김우승;이천환
    • 한국자동차공학회논문집
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    • 제17권1호
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    • pp.137-145
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    • 2009
  • The steady-state kinetics of the selective catalytic reduction (SCR) of $NO_X$ with $NH_3$ has been investigated over a commercial ${V_2}{O_5}/TiO_2$ catalyst. In order to account for the influence of transport effects the kinetics are coupled with a fully transient two-phase 1D+1D monolith channel model. The Langmuir-Hinshelwood (L-H) mechanism is adopted to describe the steady-state kinetic behavior of the ${V_2}{O_5}/TiO_2$ catalyst. The reaction rate expressions are based on previously reported papers and are modified to fit the experimental data. The steady-state chemical reaction scheme used in the present mathematical model has been validated extensively with experimental data of selective $NO_X$ reduction efficiency for a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration, and $NO_2/NO$ ratio. The parametric investigations are performed to examine how the $NH_3$ slip from a SCR $DeNO_X$ catalyst and the conversion of $NO_X$ are affected by the reaction temperature, $NH_3/NO_X$ feed ratio, and space velocity for feed gas compositions with $NO_2/NO_X$ ratios of 0 and 0.5.

Changes in Cell Ca2+ Distribution in Loquat Leaves and Its Effects on Cold Tolerance

  • Zheng, Guohua;Pan, Dongming;Niu, Xianqian;Wu, Hanwen;Zhang, Jinbiao
    • 원예과학기술지
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    • 제32권5호
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    • pp.607-613
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    • 2014
  • Calcium has been associated with improved cold tolerance in many crops. The aim of this study was to investigate the changes in leaf cell $Ca^{2+}$ distribution and cell organelle ultrastructure of loquat (Eriobotrya japonica Lindl.) plants in response to cold stress at $-3^{\circ}C$, using transmission electron microscopy (TEM). Two loquat accessions, Zaozhong 6 (a commercial cultivar) and oakleaf loquat (a wild relative) were used. Cold tolerance, as measured by leaf browning rate, was higher in oakleaf plants, and calcium treatment improved cold tolerance in both species. Cold stress first induced inward transport of $Ca^{2+}$ from the intracellular space. Then, the imported $Ca^{2+}$ was aggregated around the chloroplast membrane, finally entering the chloroplast. This pattern of $Ca^{2+}$ distribution in leaf cells occurred earlier in Zaozhong 6 than in the wild loquat. With increasing time of cold exposure, the chloroplast membranes of Zaozhong 6 leaves were damaged, blurred and even disappeared, while those of wild oakleaf loquat leaves maintained their structure longer. In Zaozhong 6, cold stress induced a clear cavity between poorly structured granal thylakoids and vesicles appearing inside the chloroplast, while in oakleaf leaves cold stress had little effect on the ultrastructure of chloroplasts (although chloroplast membranes looked blurred). Loquat leaves accumulated free calcium ions around chloroplasts in response to cold stress, with earlier calcium accumulation occurring in the cold-sensitive cultivar Zaozhong 6 than in wild oakleaf loquat. These results demonstrate that these two loquat species have differences in both cold tolerance and calcium accumulation dynamics.