• Title/Summary/Keyword: Transport temperature

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Direct Printing and Patterning of Highly Uniform Graphene Nanosheets for Applications in Flexible Electronics

  • Gu, Ja-Hun;Lee, Tae-Yun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.39.2-39.2
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    • 2011
  • With the steady increase in the demand for flexible devices, mainly in display panels, researchers have focused on finding a novel material that have excellent electrical properties even when it is bended or stretched, along with superior mechanical and thermal properties. Graphene, a single-layered two-dimensional carbon lattice, has recently attracted tremendous research interest in this respect. However, the limitations in the growing method of graphene, mainly chemical vapor deposition on transition metal catalysts, has posed severe problems in terms of device integration, due to the laborious transfer process that may damage and contaminate the graphene layer. In addition, to lower the overall cost, a fabrication technique that supports low temperature and low vacuum is required, which is the main reason why solution-based process for graphene layer deposition has become the hot issue. Nonetheless, a direct deposition method of large area, few-layered, and uniform graphene layers has not been reported yet, along with a convenient method of patterning them. Here, we report an evaporation-induced technique for directly depositing few layers of graphene nanosheets with excellent uniformity and thickness controllability on any substrate. The printed graphene nanosheets can be patterned into desired shapes and structures, which can be directly applicable as flexible and transparent electrode. To illustrate such potential, the transport properties and resistivity of the deposited graphene layers have been investigated according to their thickness. The induced internal flow of the graphene solution during tis evaporation allows uniform deposition with which its thickness, and thus resistivity can be tuned by controlling the composition ratio of the solute and solvent.

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Gas Separation of Pyrolyzed Polymeric Membranes: Effect of Polymer Precursor and Pyrolysis Conditions

  • Jung, Chul-Ho;Kim, Gun-Wook;Han, Sang-Hoon;Lee, Young-Moo
    • Macromolecular Research
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    • v.15 no.6
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    • pp.565-574
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    • 2007
  • In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

Microbial production of coenzyme Q10

  • Suh, Jung-Woo
    • 한국약용작물학회:학술대회논문집
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    • 2006.11a
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    • pp.127-130
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    • 2006
  • Coenzyme Q10(CoQ10) is a biological quinine compound that is widely found in living organisms including yeast, plants, and animals. CoQ10 has two major physiological activities:(a)mitochondrial electron-transport activity and (b)antioxidant activity. Various clinical applications are also available : Parkinson's disease, Heart disease, diabetes. Because of its various application filed, the market size of CoQ 10 is continuously expanding all over the world. A Japanese company, Nisshin Pharma Inc. is the first industrial producer of CoQ10(1974). CoQ10 can be produced by fermentation and chemical synthesis. In several companies, these two methods are used for the production of CoQ10:chemical synthesis - Yungjin, Daewoong, Nishin Parma; fermentation - Kaneka, Kyowa, Yungjin, etc. Researchs in microbial production of CoQ10 have several steps: screening of producing microorganisms, strain development, fermentation process, purification process, scale-up process, plant production. Several strategies are available for the strain development : Random mutation and screening, directed metabolic engineering. For the optimization of fermentation process, various conditions (nutrient, aeration, temperature, culture type, etc.) are considered. Purification is one of the most important step because the quality of final products entirely depends on its purity. The production cost will be reduced and the quality of the CoQ10 will be impoved by continuous researches in strain development, fermentation process, purification process.

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Phylogenetic Analysis of Culturable Arctic Bacteria

  • Lee Yoo Kyung;Kim Hyo Won;Kang Sung-Ho;Lee Hong Kum
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2003.05a
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    • pp.26-33
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    • 2003
  • We isolated and identifed culturable Arctic bacteria that have inhabited around Korean Arctic Research Station Dasan located at Ny-Alsund, Svalbard, Norway $(79^{\circ}N,\;12^{\circ}E)$. The pure colonies were inoculated into nutrient liquid media, genomic DNA was extracted, and phylogenetic analysis was performed on the basis of 16S rDNA sequences. Out of total 227 strains, 198 strains were overlapped or unidentified, and 43 bacteria were finally identified: 31 strains belonged to Pseudomonas, 7 strains Arthrobacter, two Flavobacterium sp., an Achromobacter sp., a Pedobacter sp., and a Psychrobacter sp. For isolation of diverse bacteria, we need more effective transport method than 3M petri-films, which were used for convenience of transportation that was restricted by volume. We also need to use other culture media than nutrient media. We expect these Arctic bacteria can be used for screening to develop new antibiotics or industrial enzymes that are active at low temperature.

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Performance Test of an Oxidizer Tunnel-Type Pipe for Launch Vehicle (발사체 산화제 터널형 배관 성능시험)

  • Kil, Gyoung-Sub;Han, Sang-Yeop;Kho, Hyeon-Seok;Shin, Dong-Sun;Cho, In-Hyun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.273-277
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    • 2009
  • An oxidizer tunnel-type pipe, which shall transport oxidizer from an oxidizer tank to a turbo-pump of an engine, studied is installed through a fuel tank located under an oxidizer tank. A tunnel-type pipe can save weight compared to a detour-type pipe, however may vary the temperature of fuel stored in a fuel tank because of a broad heat transfer area. Hence in this study the characteristics of main oxidizer pipe and thermal propagation from oxidizer to a fuel tank are monitored by a cryogenic performance test with a tunnel-type pipe. In addition, the possibility of adaptation of an oxidizer tunnel-type pipe to launcher system is also analyzed.

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Preparation of TiO2 Photocatalysts by Diffusion Flame Reactor and Its Application on Photo-degradation of Phenol and Toluene (확산화염 반응기를 이용한 TiO2 광촉매 제조 및 페놀 및 톨루엔 광분해 응용)

  • Choi, Sang-Keun;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.22 no.B
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    • pp.117-124
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    • 2002
  • We prepared the nano-sized $TiO_2$ particles by the diffusion flame reactor and investigated the effects of several process variables on the generation and transport properties of $TiO_2$ particle. As the length from the tip of diffusion flame reactor increases, the size of $TiO_2$ particle increases by the coagulation between particles. The structure of $TiO_2$ particles prepared is almost found to be anatase. It was found that the $TiO_2$ particle size depends more largely on the change of reactor temperature than on the change of inlet $TiCl_4$ concentration. By the photo-degradation experiment of phenol and toluene with the prepared $TiO_2$ particles, we found that the photo-degradation efficiencies of phenol and toluene change, depending on the process variables such as size of $TiO_2$ photocatlysts, concentration of phenol or toluene. Degradation efficiencies of phenol and toluene was above 90% in our experiments in 60 minutes.

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The Characteristics of Turbulent Diffusion Flame Impinging on the Wall (벽면 충돌 난류 확산화염의 특성)

  • Park, Yong Youl;Kim, Ho Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.175-184
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    • 1999
  • A theoretical study on the turbulent round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of Impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation and eddy dissipation model was adopted as a combustion model, and the Favre averaging and $k-{\varepsilon}$ model were Introduced In the theoretical modeling. The SIMPLE algorithm was applied to the calculation. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to impinging wall and Reynolds number at nozzle exit were chosen 88 the major parameters. As the results of the present study, the characteristics of flow fields, the distributions of main variables and each chemical species and the flame shapes were obtained. The heat transfer rate from the flame to the wall and the effective heating area were calculated to investigate the Influences of the major parameters on the heat transfer characteristics.

A Study on Characteristic of the Bio-ethanol Produced on Fruit Wastes for Direct Ethanol Fuel Cell (DEFC) (과일폐기물을 이용한 DEFC용 바이오에탄올 제조 및 특성에 관한 연구)

  • Lee, Nam-Jin;Kim, Hyun-Soo;Cha, In-Su;Choi, Jeong-Sik
    • Journal of Hydrogen and New Energy
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    • v.22 no.2
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    • pp.257-264
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    • 2011
  • This study discribes performance of DEFC (Direct Ethanol Fuel Cell) utilized bio-ethanol based on fruit wastes. To produce the bio-ethanol, fruit wastes were treated at temperature $120^{\circ}C$ and 90minutes in acid pre-treatment. After pre-treatment was done, alcohol fermentation process was running. Initial alcohol concentration was 5%. Using the multi coloumn distillation system, more than 95% ethanol was distilled and each component of bio-ethanol was analyzed. In DEFC performance test, it was revealed that cell performance was much higher than that of ethanol. Comparing ethanol with mixed fuel (bio-ethanol (10%) + ethanol (90%)), the performance of ethanol was higher than that of mixed fuel. Even though the bio-ethanol from the fruit wastes is corresponded with transport ethanol standards, it thought that organic matter in bio-ethanol could be negative effect on fuel cell.

Superconducting properties of SiC-buffered-MgB2 tapes

  • Putri, W.B.K.;Kang, B.;Duong, P.V.;Kang, W.N.
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.3
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    • pp.1-4
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    • 2015
  • Production of $MgB_2$ film on metallic Hastelloy with SiC as the buffer layer was achieved by means of hybrid physical-chemical vapor deposition technique, whereas SiC buffer layers with varied thickness of 170 and 250 nm were fabricated inside a pulsed laser deposition chamber. Superconducting transition temperature and critical current density were verified by transport and magnetic measurement, respectively. With SiC buffer layer, the reduced delaminated area at the interface of $MgB_2$-Hastelloy and the slightly increased $T_c$ of $MgB_2$ tapes were clearly noticed. It was found that the upper critical field, the irreversibility field and the critical current density were reduced when $MgB_2$ tapes were buffered with SiC buffer layer. Clarifying the mechanism of SiC buffer layer in $MgB_2$ tape in affecting the superconducting properties is considerably important for practical applications.

Recent Progress in Bi-Te-based Thermoelectric Materials (Bi-Te계 열전소재 연구 동향)

  • Lee, Kyu Hyoung;Kim, Jong-Young;Choi, Soon-Mok
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.1-8
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    • 2015
  • Thermoelectric (TE) technology is becoming increasingly important in applications of solid-state cooling and renewable energy sources. $Bi_2Te_3$-based TE materials are widely used in small-scale cooling and temperature control applications; however, higher levels of TE performance are required for new applications such as large-scale cooling (e.g., domestic refrigerators or air conditioners) and for highly efficient power generation system. Recently, the TE performance of $Bi_2Te_3$-based materials has been remarkably enhanced by the introduction of nanostructuring technologies which can be used to prepare TE raw materials. Because it takes into account the theoretical and experimental characteristics, nanostructuring has been shown to be one of the most promising ways to realize the simultaneous control of the electronic and thermal transport properties. In this review, emphasis is placed on bulk-type nanostructured $Bi_2Te_3$-based TE materials. Nanostructuring technologies for enhanced TE performance are summarized, and a few important strategies are presented.