• Title/Summary/Keyword: Transport properties

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Transport and Magnetic Properties of Ca3Mn2O7 ceramic (Ca3Mn2O7 세라믹스의 전기전도 및 자기적 특성)

  • Jung, Woo-Hwan
    • Journal of the Korean Ceramic Society
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    • v.42 no.9 s.280
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    • pp.613-617
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    • 2005
  • We present the results of a combined magnetization, dc and magneto-transport study of the n = 2 Ruddlesden-Popper compound $Ca_3Mn_2O_7$ The negative thermoelectric powder is observed. The magnetic measurement data show that there is sharp magnetic transition at 134 K. However, the de and magnetoresistance of $Ca_3Mn_2O_7$ show no particular transport. Transport properties of the compound $Ca_3Mn_2O_7$ are interpreted in terms of activated hopping of small polarons in non-adiabatic regime. Polarons are most probably formed around $Mn^{3+}$ sites created by oxygen sub-stoichiometry.

Numerical Analysis for Wave Propagation and Sediment Transport with Coastal Vegetation (연안식생에 의한 표사이동 특성에 관한 수치해석)

  • Lee, Seong-Dae
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.18-24
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    • 2007
  • The environmental value of coastal vegetation has been widely recognized. Coastal vegetation such as reed forests and seaweed performs several useful functions, including maintaining water quality, supporting fish (and, thus, fisheries), protecting beaches and land from wave attack, stabilizing sea beds and providing scenic value. However, studies on the physical and numerical process of wave propagation, sediment transport and bathymetric change are few and far between compared to those on the hydrodynamic roles of coastal vegetation. In general, vegetation flourishing along the coastal areas attenuates the incident waves through momentum exchange between stagnated water mass in the vegetated area and rapid mass in the un-vegetated area. This study develops a numerical model for describing the wave attenuation and sediment transport in a wave channel in a vegetation area. By comparing these results, the effects of vegetation properties, wave properties and model parameters are clarified.

Nanostructured Polymer Electrolytes for Li-Batteries and Fuel Cells

  • Park, Mun-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.71.2-71.2
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    • 2012
  • There are rising demands for developing more efficient energy materials to stem the depletion of fossil fuels, which have prompted significant research efforts on proton exchange fuel cells (PEFCs) and lithium ion batteries (LIBs). To date, both PEFCs and LIBs are being widely developed to power small electronics, however, their utilization to medium-large sized electric power resources such as vehicle and stationary energy storage systems still appears distant. These technologies increasingly rely upon polymer electrolyte membranes (PEMs) that transport ions from the anode to the cathode to balance the flow of electrons in an external circuit, and therefore play a central role in determining the efficiency of the devices; as ion transport is a kinetic bottleneck compared to electrical conductivity, enormous efforts have been devoted to improving the transport properties of PEMs. In present study, we carried out an in-depth analysis of the morphology effects on transport properties of PEMs. How parameters such as self-assembled nanostructures, domain sizes, and domain orientations affect conductivities of PEMs will be presented.

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SENSITIVITY ANALYSIS TO EVALUATE THE TRANSPORT PROPERTIES OF CdZnTe DETECTORS USING ALPHA PARTICLES AND LOW-ENERGY GAMMA-RAYS

  • Kim, Kyung-O;Ahn, Woo-Sang;Kwon, Tae-Je;Kim, Soon-Young;Kim, Jong-Kyung;Ha, Jang-Ho
    • Nuclear Engineering and Technology
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    • v.43 no.6
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    • pp.567-572
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    • 2011
  • A sensitivity analysis of the methods used to evaluate the transport properties of a CdZnTe detector was performed using two different radiations (${\alpha}$ particle and gamma-ray) emitted from an $^{241}Am$ source. The mobility-lifetime products of the electron-hole pair in a planar CZT detector ($5{\times}5{\times}2\;mm^3$) were determined by fitting the peak position as a function of biased voltage data to the Hecht equation. To verify the accuracy of these products derived from ${\alpha}$ particles and low-energy gamma-rays, an energy spectrum considering the transport property of the CZT detector was simulated through a combination of the deposited energy and the charge collection efficiency at a specific position. It was found that the shaping time of the amplifier module significantly affects the determination of the (${\mu}{\tau}$) products; the ${\alpha}$ particle method was stabilized with an increase in the shaping time and was less sensitive to this change compared to when the gamma-ray method was used. In the case of the simulated energy spectrum with transport properties evaluated by the ${\alpha}$ particle method, the peak position and tail were slightly different from the measured result, whereas the energy spectrum derived from the low-energy gamma-ray was in good agreement with the experimental results. From these results, it was confirmed that low-energy gamma-rays are more useful when seeking to obtain the transport properties of carriers than ${\alpha}$ particles because the methods that use gamma-rays are less influenced by the surface condition of the CZT detector. Furthermore, the analysis system employed in this study, which was configured by a combination of Monte Carlo simulation and the Hecht model, is expected to be highly applicable to the study of the characteristics of CZT detectors.

A Study on the Effect of Fiber Type on the Water Vapor Transport Properties (섬유의 종류와 조합에 따른 직물의 수분전달 특성에 관한 연구)

  • Na Me Hee;Kim Eun Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.3 s.35
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    • pp.229-240
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    • 1990
  • The purpose of this study was to investigate the effect of hydrophilicity of the fiber on the water vapor transport properties of the fabric by using double layered fabrics of natural and synthetic fibers such as cotton, wool, nylon, dacron, orlon and polypropylene. Wickability and absorption rate were measured to determine the absorbancy of the fabrics. Dynamic and steady state water vapor transport properties were measured by cobaltous chloride method and evaporation method, respectively. Absorption was in the order of orlon> cotton > wool > nylon > polypropylene > dacron. Dynamic surface wetness of synthetic fabrics were faster than that of natural fabrics. For the double layered fabrics, higher water vapor transport was resulted when the natural fabric was exposed to lower vapor pressure and synthetic fabric was exposed to higher vapor pressure than when the fabrics were layered the other way around. Opposite result was obtained for orlon, which suggested that when the fabric of high absorbancy is exposed to the environment and lower absorbancy is to the skin, higher water vapor transpont could be resulted.

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Effect of Sputtering Power on Optical and Electrical Properties of SnOx Electron Transport Layer Deposited by RF-magnetron Sputtering (RF-마그네트론 스퍼터링으로 증착된 산화주석 전자수송층의 광학적 및 전기적 특성에 대한 증착 전력의 영향)

  • Hwang, Ji Seong;Lee, Wonkyu;Hwang, Jae Keun;Lee, Sang-Won;Hyun, Ji Yeon;Lee, Solhee;Jeong, Seok Hyun;Kang, Yoonmook;Kim, Donghwan;Lee, Hae-Seok
    • Current Photovoltaic Research
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    • v.9 no.1
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    • pp.1-5
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    • 2021
  • The properties of the electron transport layer (ETL) have a great effect on perovskite solar cell performance. Depositing conformal SnO2 ETL on bottom textured silicon cells is essential to increase current density in terms of the silicon-perovskite tandem solar cells. In the recent study, the SnO2 electron transport layer deposited by the sputtering method showed an efficiency of 19.8%. Also, an electron transport layer with a sputtered TiO2 electron transport layer in a 4-terminal tandem solar cell has been reported. In this study, we synthesized SnOx ETL with a various sputtering power range of 30-60W by Radio-frequency (RF)-magnetron sputtering. The properties of SnOx thin film were characterized using ellipsometer, UV-vis spectrometer, and IV measurement. With a sputtering power of 50W, the solar cell showed the highest efficiency of 13.3%, because of the highest fill factor by the conductivity of SnOx film.

Development a numerical model of flow and contaminant transport in layered soils

  • Ahmadi, Hossein;Namin, Masoud M.;Kilanehei, Fouad
    • Advances in environmental research
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    • v.5 no.4
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    • pp.263-282
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    • 2016
  • Contaminant transport in groundwater induces major threat and harmful effect on the environment; hence, the fate of the contaminant migration in groundwater is seeking a lot of attention. In this paper a two dimensional numerical flow and transport model through saturated layered soil is developed. Groundwater flow and solute transport has been simulated numerically using proposed model. The model implements the finite volume time splitting method to discretize the main equations. The performance, accuracy and efficiency of the out coming numerical models have been successfully examined by two test cases. The verification test cases consist of two-dimensional, groundwater flow and solute transport. The final purpose of this paper is to discuss and compare the shape of contaminant plume in homogeneous and heterogeneous media with different soil properties and control of solute transport using a zone for minimizing the potential of groundwater contamination; furthermore, this model leads to select the effective and optimum remedial strategies for cleaning the contaminated aquifers.

Numerical Analysis of Transport Current Losses in Stacked HTS Conductors (적층 형태의 고온 초전도선재에서의 통전손실 수치 해석)

  • 최세용;나완수;김정호;주진호;류경우
    • Progress in Superconductivity
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    • v.5 no.2
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    • pp.89-93
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    • 2004
  • We have studied alternating transport current losses in the vertically stacked high temperature superconducting tapes(HTS) using numerical techniques. In the case of stacked conductors, HTS tapes are exposed to self-field generated by transport current itself and also experienced external magnetic field around adjacent tapes. It is well known that magnetic interactions between neighbored tapes have significant effect on their properties of superconducting tapes such as current distribution, AC loss, and critical current. In this paper, we investigated the transport current losses in stacked conductors consisting of a few of the HTS tapes using numerical analysis. Current distributions are calculated in HTS tape cross-section taking account of magnetic field dependencies, which are represented superconducting nonlinear properties. Dissipated losses in tape and stacked conductors were integrated with current distribution and electric field intensity in the whole conductor region. Finally estimated results were discussed and verified through the analytical theory.

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Transport Properties of Lennard-Jones Mixtures: A Molecular Dynamics Simulation Study

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.641-646
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    • 2008
  • Equilibrium molecular dynamics simulations in a canonical ensemble are performed to evaluate the transport coefficients of several Lennard-Jones (LJ) mixtures at a liquid argon states of 94.4 K and 1 atm via modified Green-Kubo formulas. Two component mixture of A and B is built by considering the interaction between A and A as the attractive (A) potential, that between A and B as the attractive potential (A), and that between B and B as the repulsive potential (R), labelled as AAR mixture. Three more mixtures - ARA, ARR, and RAR are created in the same way. The behavior of the LJ energy and the transport properties for all the mixtures is easily understood in terms of the portion of attractive potential (A %). The behavior of the thermal conductivities by the translational energy transport due to molecular motion exactly coincides with that of diffusion constant while that of the thermal conductivities by the potential energy transport due to molecular motion is easily understood from the fact that the LJ energy of AAR, ARR, and RAR mixtures increases negatively with the increase of A % from that of the pure repulsive system while that of ARA changes rarely.

Charge Carrier Photogeneration and Hole Transport Properties of Blends of a $\pi$-Conjugated Polymer and an Organic-Inorganic Hybrid Material

  • Han, Jung-Wook;An, Jong-Deok;Jana, R.N.;Jung, Kyung-Na;Do, Jung-Hwan;Pyo, Seung-Moon;Im, Chan
    • Macromolecular Research
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    • v.17 no.11
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    • pp.894-900
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    • 2009
  • This study examined the charge carrier photogeneration and hole transport properties of blends of poly (9-vinylcarbazole) (PVK), $\pi$-conjugated polymer, with different weight proportions (0~29.4 wt%) of (PEA)$VOPO_4{\cdot}H_2O$ (PEA: phenethylammonium cation), a novel organic-inorganic hybrid material, using IR, UV-Vis, and energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA), steady state photocurrent (SSPC) measurement, and atomic force microscopy (AFM). The SSPC measurements showed that the photocurrent of PVK was reduced by approximately three orders of magnitude by the incorporation of a small amount (~12.5 wt%) of (PEA) $VOPO_4{\cdot}H_2O$, suggesting that hole transport occurred through the PVK carbazole groups, whereas a reverse trend was observed at high proportions (>12.5 wt%) of (PEA)$VOPO_4{\cdot}H_2O$, suggesting that transport occurred via (PEA)$VOPO_4{\cdot}H_2O$ molecules. The transition to a trap-controlled hopping mechanism was explained by the difference in ionization potential and electron affinity of the two compounds as well as the formation of charge percolation threshold pathways.