• Title/Summary/Keyword: Transport Phenomena

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Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

Analysis of Thermal Recovery Characteristics for $SF^6$ Gas-Blast Arc within Laval Nozzle (Laval Nozzle에 대한 $SF^6$ 아크의 열적회복특성 해석)

  • Song, Gi-Dong;Lee, Byeong-Yun;Gyeong-Yeop;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.51 no.9
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    • pp.522-529
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    • 2002
  • In this paper, computer simulations of the physical Phenomena occurring in the arc region before and after current zero were carried out to evaluate the thermal recovery characteristics of a Laval nozzle. A commercial CFD program "PHOENICS" is used for the simulation and the user-coded subroutines to consider the arcing phenomena were added to this program by the authors. The computed results were verified by the comparison with the test results presented by the research group of GE Co.(General Electric Company). In order to investigate the state of the arc region after current zero, the simulation was carried out with three steps. They are steady state arc simulation, transient arc simulation before current zero, and transient hot-gas flow simulation after current zero. The semi-experimental arc radiation model is adapted to consider the radiation energy transport and Prandtl's mixing length model is employed as the turbulence model. The electric field and the magnetic field were calculated with the same grid structure used for the simulation of the flow field. The post-arc current was calculated to evaluate the thermal recovery characteristics after current zero. Compared with the results obtained by GE Co., it has been found that the critical RRRV(ratio of rise of recovery voltage) will be determined previously by this study.his study.

Surface Segregation of Hydroniums and Chlorides in a Thick Ice Film at Higher Temperatures

  • Lee, Du Hyeong;Bang, Jaehyeock;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.263-263
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    • 2013
  • This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

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Feature of Spray Transport and Atomization from Two-Phase Swirling Jet with Air-to-Liquid Mass Ratio (공기액체질량비에 따른 이류체 선회형 분사의 분무거동 및 미립화 특성)

  • Lee, Sam-Goo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.2
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    • pp.39-45
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    • 2004
  • Experiments were performed in a two-phase swirling spray facility that has been described elsewhere. Measurements of spray transport and drop size distribution are analyzed over wide ranges of air to liquid mass flow ratios, utilizing four different internal mixing pneumatic nozzles. The spatial distributions of mean velocities. fluctuating velocities, and velocity-diameter correlation were quantitatively analyzed. Also, the exponential correlation curves were obtained with ALR along the spray centerline, which indicated an approximately identical formulation regardless of ALR. It indicated that the atomization characteristics were remarkably superior in the case of 30o of swirl angle with higher ALR. Among other things. nozzle configuration is one of the significant parameters affecting spray phenomena from an internal mixing nozzle. Turbulence intensities are increasingly degenerated with an increase of nozzle configuration, allowing a rapid increment of drop size distribution.

An Effectiveness of Simultaneous Measurement of PM10, PM2.5, and PM1.0 Concentrations in Asian Dust and Haze Monitoring

  • Cho, Changbum;Park, Gilun;Kim, Baekjo
    • Journal of Environmental Science International
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    • v.22 no.6
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    • pp.651-666
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    • 2013
  • This study introduces a novel approach to the differentiation of two phenomena, Asian Dust and haze, which are extremely difficult to distinguish based solely on comparisons of PM10 concentration, through use of the Optical Particle Counter (OPC), which simultaneously generates PM10, PM2.5 and PM1.0 concentration. In the case of Asian Dust, PM10 concentration rose to the exclusion of PM2.5 and PM1.0 concentration. The relative ratios of PM2.5 and PM1.0 concentration versus PM10 concentration were below 40%, which is consistent with the conclusion that Asian Dust, as a prime example of the coarse-particle phenomenon, only impacts PM10 concentration, not PM2.5 and PM1.0 concentration. In contrast, PM10, PM2.5 and PM1.0 concentration simultaneously increased with haze. The relative ratios of PM2.5 and PM1.0 concentration versus PM10 concentration were generally above 70%. In this case, PM1.0 concentration varies because a haze event consists of secondary aerosol in the fine-mode, and the relative ratios of PM10 and PM2.5 concentration remain intact as these values already subsume PM1.0 concentration. The sequential shift of the peaks in PM10, PM2.5 and PM1.0 concentrations also serve to individually track the transport of coarse-mode versus fine-mode aerosols. The distinction in the relative ratios of PM2.5 and PM1.0 concentration versus PM10 concentration in an Asian Dust versus a haze event, when collected on a national or global scale using OPC monitoring networks, provides realistic information on outbreaks and transport of Asian Dust and haze.

Effects of 3D Flow-Channel Configurations on the Performance of PEMFC using Computational Fluid Dynamics (전산유체역학을 이용한 PEMFC의 성능에 대한 3차원 유로 구조의 영향)

  • Han, Kyoung-Ho;Yoon, Do Young
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.847-853
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    • 2016
  • Here has been examined a 3-dimensional computational fluid dynamics (CFD) modeling in order to investigate the performance analysis of proton exchange membrane (PEM) fuel cells with serpentine flow fields. The present CFD model considers the isothermal transport phenomena in a fuel cell involving mass, momentum transport, electrode kinetics, and potential fields. Co-current flow patterns for a PEMFC are considered for various geometries in the single straight cell. Current density distribution from the calculated distribution of oxygen and hydrogen mass fractions has been determined, where the activation overpotential has been also calculated within anode and cathode. CFD results showed that profiles differ from those simulations subjected to each the calculated activation overpotential. It is interesting that the present serpentine flow field shows the specific distribution of current density with respect to the aspect ratio of depth to width and the ratio of reaction area for various serpentine geometries. Simulation results were considered reasonable with the other CFD results reported in literature and global comparisons of the PEMFC model.

UV Photo Response Driven by Pd Nano Particles on LaAlO3/SrTiO3 Using Ambient Control Kelvin Probe Force Microscopy

  • Kim, Haeri;Chan, Ngai Yui;Dai, Jiyan;Kim, Dong-Wook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.207.1-207.1
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    • 2014
  • High-mobility and two dimensional conduction at the interface between two band insulators, LaAlO3 (LAO) and SrTiO3 (STO), have attracted considerable research interest for both applications and fundamental understanding. Several groups have reported the photoconductivity of LAO/STO, which give us lots of potential development of optoelectronic applications using the oxide interface. Recently, a giant photo response of Pd nano particles/LAO/STO is observed in UV illumination compared with LAO/STO sample. These phenomena have been suggested that the correlation between the interface and the surface states significantly affect local charge modification and resulting electrical transport. Water and gas adsorption/desorption can alter the band alignment and surface workfunction. Therefore, characterizing and manipulating the electric charges in these materials (electrons and ions) are crucial for investigating the physics of metal oxide. Proposed mechanism do not well explain the experimental data in various ambient and there has been no quantitative work to confirm these mechanism. Here, we have investigated UV photo response in various ambient by performing transport and Kelvin probe force microscopy measurements simultaneously. We found that Pd nano particles on LAO can form Schottky contact, it cause interface carrier density and characteristics of persistence photo conductance depending on gas environment. Our studies will help to improve our understanding on the intriguing physical properties providing an important role in many enhanced light sensing and gas sensing applications as a catalytic material in different kinds of metal oxide systems.

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Seasonal Characteristics of the Near-Surface Circulation in the Northern South China Sea Obtained from Satellite-Tracked Drifters

  • Park, Gill-Yong;Oh, Im-Sang
    • Ocean Science Journal
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    • v.42 no.2
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    • pp.89-102
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    • 2007
  • The surface circulation of northern South China Sea (hereafter SCS) for the period 1987-2005 was studied using the data of more than 500 satellite-tracked drifters and wind data from QuikSCAT. The mean flow directions in the northern SCS except the Luzon Strait (here after LS) during the periods October_March was southwestward, and $April{\sim}September$ northeastward. A strong northwestward intrusion of the Kuroshio through the LS appears during the $October{\sim}March$ period of northeasterly wind, but the intrusion became weak between April and September. When the strong intrusion occurred, the eddy kinetic energy (EKE) in the LS was $388cm^2/s^2$ which was almost 2 times higher than that during the weak-intrusion season. The volume transport of the Kuroshio in the east of the Philippines shows an inverse relationship to that of the LS. There is a six-month phase shift between the two seasonal phenomena. The volume transport in the east of the Philippines shows its peak sis-month earlier faster than that of the LS. The strong Kuroshio intrusion is found to be also related to the seasonal variation of the wind stress curl generated by the north easterly wind. The negative wind stress curl in the northern part of LS induces an anticyclonic flow, while the positive wind stress curl in the southern part of LS induces a cyclonic flow. The northwestward Kuroshio intrusion in the northern part of LS happened with larger negative wind stress curl, while the westward intrusion along $20.5^{\circ}N$ in the center of the LS occurred with weaker negative wind stress curl.

The Simulation and Experiment of Flexible Media with High Exit Velocity (고속의 출구속도를 가지는 유연매체의 거동해석 및 실험)

  • Hong, Sung-Kwon;Jee, Jung-Geun;Jang, Yong-Hoon;Park, No-Cheol;Park, Young-Pil
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.380-383
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    • 2006
  • The media transport system is used in a printer, a ATM(Automated Tellor Machine), and so on. The media transport system has many problems through miniaturization and rapid transportation of these machines. In the paper feeding mechanism, it is important to feed the sheet without jamming under any conditions. To avoid sheet jamming, first we need to predict the behavior of the sheet exactly. In this paper, the analysis of media behavior is based on J. Stolte's studies. In all of OA machines, a flexible beam or plate is pushed from the channel. The motion may be constrained by guides. This leads to a transient and geometrically nonlinear problem. The behavior of paper is simulated by dynamic elastica theory. The shape of guide is represented by parametric cubic curve. But J. Stolte's studies did not considered contact condition between sheet and guide. So Klarbring's Model. will be applied. And the analysis of flexible media has to include aerodynamic effect for more exact behavior analysis, because the flexible media can be deformed drastically by a little force. Therefore aerodynamic force must be applied to the governing equation. Lastly, the simulation of this model is performed, and the experiment is performed for verification of this model. The experimental results of low exit velocity are consistent with the simulation results, however experimental results of high exit velocity do not agree well with analytical results. The reason is that there may be other effects like nip Phenomena

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Multiscale Modeling and Simulation of Water Gas Shift Reactor (Water Gas Shift Reactor의 Multiscale 모델링 및 모사)

  • Lee, Ukjune;Kim, Kihyun;Oh, Min
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.582-590
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    • 2007
  • In view of the analysis of the phenomena and the prediction of the performance, mathematical modelling and simulation of a high temperature pilot reactor for water gas shift reaction (WGSR) has been carried out. Multiscale simulation incorporated computational fluid dynamics (CFD) technique, which has the capability to deal with the reactor shape, fluid and energy transport with extensive degree of accuracy, and process modeling technique, which, in turn is responsible for reaction kinetics and mass transport. This research employed multiscale simulation and the results were compared with those from process simulation. From multiscale simulation, the maximum conversion of was predicted approximately 0.85 and the maximum temperature at the reactor was calculated 720 K, resulting from the heat of reaction. Dynamic simulation was also performed for the time transient profile of temperature, conversion, etc. Considering the results, it is concluded that multiscale simulation is a safe and accurate technique to predict reactor behaviors, and consequently will be available for the design of commercial size chemical reactors as well as other commercial unit operations.