• Title/Summary/Keyword: Transition temperature elevation

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Irradiation Behavior of Reactor Pressure Vessel SA508 class 3 Steel Weld Metals (압력용기강재 SA508 class 3 용착금속의 조사거동)

  • Koh, Jin-Hyun;Park, Hyoung-Keun;Kim, Soo-Sung;Hwang, Yong-Hwa;Seo, Yun-Seok
    • Journal of Welding and Joining
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    • v.28 no.5
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    • pp.69-74
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    • 2010
  • Irradiation behavior of the reactor pressure vessel SA508 class 3 steel weld metals was examined by Charpy V Notch impact specimens. The specimens were exposed to a fluence of $2.8{\times}1019$ neutrons(n)/$cm^2$(E>1 MeV) at $288^{\circ}C$. The irradiation damage of weld metal was evaluated by comparison between unirradiated and irradiated specimens in terms of absorbed energy and lateral expansion. The specimens for neutron irradiation were welded by submerged arc welding process at a heat input of 3.2 kJ/mm which showed good toughness in terms of weld microstructure, absorbed energy and lateral expansion. The post-irradiation Charpy V notch 41J and 68J transition temperature elevation were $65^{\circ}C$ and $70^{\circ}C$, respectively. This elevation was accompanied by a 20% reduction in Charpy V notch upper shelf energy level. The lateral expansion at 0.9mm irradiated Charpy specimens showed temperature elevation of $65^{\circ}C$ and was greatly decreased due to radiation damage.

The Study for Impact Strength change of Microcellular foamed Recycled ABS (초미세 발포 플라스틱의 재생 후 강도변화에 대한 연구)

  • 성갑제;차성운;윤재동
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.896-899
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    • 2002
  • Microcellular foaming Process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This method make the glass transition temperature of polymers low, and diminish the residual stress of polymers. This characteristics of Microcellular foaming process influences the physical properties of recycled polymers. This paper describes about the impact strength change of Microcellular foamed recycled ABS.

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Synthesis of Poly(cinnam-4'-yl methyl methacrylate) Derivatives and Their Thermal Stability as Photoalignment Layer

  • Lee, Jong U;Kim, Hak Won;Kim, Hong Du
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.179-182
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    • 2001
  • Photocyclizable poly(cinnam-4'-yl methyl methacrylate) derivatives bearing methoxy benzene (PMCMMA), anthracene (PACMMA), and coumarin (PCCMMA) have been synthesized via Heck type reaction. Three different types of polymers are photoreactable usin g linearly polarized UV light and applicable as liquid crystal alignment layer. Anthracence and coumarin containing polymers (PACMMA, PCCMMA) have better thermal stability than PMCMMA. This observation may be attributed to the glass transition temperature elevation due to the bulky size and another photocrosslinking site provided by anthracene or coumarin group.

Change in $Na^+-K^+$-ATPase Activity in Regressive Corpus Luteal Membrane (황체퇴화시 황체막 $Na^+-K^+$-ATPase 활성도의 변화)

  • Kim, In-Kyo;Yeoun, Dong-Soo;Lee, Syng-Ill
    • The Korean Journal of Physiology
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    • v.16 no.2
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    • pp.111-117
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    • 1982
  • Slices of rat corpora lutea(CL) incubated with. prostaglandin $F_{{2{\alpha}}}(PGF_{2{\alpha}})$ in Krebs-Hensenleit (K-H) Ringer solution showed a decrease in $Na^+-K^+$-ATPase activity after 60 min of incubation. However, $PGF_{2{\alpha}}$ in vitro did not alter $Na^+-K^+$-ATPase activity of isolated luteal membrane fractions. Following $PGF_{2{\alpha}}$ induced in vivo luteal regression, reduction of Vmax an elevation of the activation energy above transition temperature of the lipid phase of the membrane occurred without changes of Km, optimum pH and transition temperature. These results suggest that reduction of $Na^+-K^+$-ATPase activity after $PGF_{2{\alpha}}$ treatment may be due to the reduction of the number of enzyme molecules or to masking of the active site of the enzyme without any change in enzyme characteristics. In addition, a change in membrane bound enzyme activity may be an early step in $PGF_{2{\alpha}}$ induced luleolysis.

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Effect of Cr Addition on the High Temperature Deformation Behavior of Fe-Al Intermetallics (Fe-Al 금속간 화합물의 고온변형거동에 미치는 Cr 첨가의 효과)

  • Bang W.;Lim H. T.;Ha T. K.;Song J. H.;Chang Y. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.167-171
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    • 2001
  • High temperature deformation behavior of Fe-28Al-5Cr alloy has been investigated known to show anomalous temperature dependence of yield strength. Specifically, the effect of Cr addition has been examined. A series of tensile and load relaxation tests have been carried out to obtain the flow behavior of Fe-28Al-5Cr alloy at the elevated temperatures. The flow curves have then been analyzed using the inelastic deformation theory recently proposed. Firstly, high temperature flow stress of iron aluminides can be resolved into internal stress and frictional stress. Secondly, the temperature corresponding to peak strength gets higher level at faster strain rate, which presumably due to the increased contribution of internal stress in observed flow stress. And thirdly, the alloying of Cr seems to cause solid-solution strengthening of frictional stress level and the elevation of 2nd order transition temperature. In this analogy, Fe-28Al-5Cr exhibits better strength especially at relatively higher temperature and lower strain rate than Fe-28Al.

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Properties of Alumina Powder Prepared by Precipitation Method(II) : Properties of Alumina Powder on Heat-Treatment (침전법으로 제조한 Alumina 분말의 특성(II) : 열처리에 따른 Alumina 분말의 특성)

  • 홍기곤;이홍림
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.193-200
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    • 1988
  • The starting materials were aluminum hydroxide prepared by precipitation method at the conditions of pH values; 7, 9, 10 and 11. The properties of alumina powder on heat-treatment were studied. After dehydrating structural water from amorphous aluminum hydroxide, the first formed phase was amorphous alumina and its specific surface are was decreased. The specific surface area was increased by dehydration of structural water from aluminum hydroxides except amorphous aluminum hydroxide. The specific surface area was increased with increase of the ratio of A1OOH to $A1(OH)_3$ in the region of transition aluminas. The rate of transition from aluminum hydroxide to alpha alumina occurred in the order of 7, 10, 9 and 11 of pH values. The morphology of alpha alumina powders was skeleton particles remaining outer shape of aluminum hydroxide. Both the elevation of heat-treatment temperature and the transition toalpha alumina decreased specific surface area and brought about the growth of particles.

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Cell morphology of microcellular foaming injection molding products with pressure drop rate (초미세 발포 사출 시 핵 생성장치를 이용한 셀 크기의 변화)

  • 김학빈;차성운
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.491-495
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    • 2004
  • The industries use polymer materials for many purposes for they have many merits. The costs of these materials take up too great a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2$, $N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This characteristic of microcellular foaming process has influenced by cell morphology. The cell morphology means cell size and cell density. The cell morphology has influenced by many factors. The examples of factor are pressure drop rate, foaming temperature, foaming time, saturation pressure, saturation time etc. Among their factors, pressure drop rate is the most important factor for cell morphology in microcellular foaming injection molding process. This paper describes about the cell morphology change in accordance with the pressure drop rate of microcellular foaming injection molding process.

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The Study for Cell Morphology with Gas Cocktail in Microcellular Foaming Process (초미세 발포 공법 시 가스 혼합에 따른 셀 형상 연구)

  • Cha Sung Woon;Yoon Jae Dong;Lee Yoon Sung;Kim Hak Bin
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.6 s.171
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    • pp.168-174
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    • 2005
  • Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.