• 제목/요약/키워드: Transition temperature elevation

검색결과 8건 처리시간 0.02초

압력용기강재 SA508 class 3 용착금속의 조사거동 (Irradiation Behavior of Reactor Pressure Vessel SA508 class 3 Steel Weld Metals)

  • 고진현;박형근;김수성;황용화;서윤석
    • Journal of Welding and Joining
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    • 제28권5호
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    • pp.69-74
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    • 2010
  • Irradiation behavior of the reactor pressure vessel SA508 class 3 steel weld metals was examined by Charpy V Notch impact specimens. The specimens were exposed to a fluence of $2.8{\times}1019$ neutrons(n)/$cm^2$(E>1 MeV) at $288^{\circ}C$. The irradiation damage of weld metal was evaluated by comparison between unirradiated and irradiated specimens in terms of absorbed energy and lateral expansion. The specimens for neutron irradiation were welded by submerged arc welding process at a heat input of 3.2 kJ/mm which showed good toughness in terms of weld microstructure, absorbed energy and lateral expansion. The post-irradiation Charpy V notch 41J and 68J transition temperature elevation were $65^{\circ}C$ and $70^{\circ}C$, respectively. This elevation was accompanied by a 20% reduction in Charpy V notch upper shelf energy level. The lateral expansion at 0.9mm irradiated Charpy specimens showed temperature elevation of $65^{\circ}C$ and was greatly decreased due to radiation damage.

초미세 발포 플라스틱의 재생 후 강도변화에 대한 연구 (The Study for Impact Strength change of Microcellular foamed Recycled ABS)

  • 성갑제;차성운;윤재동
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.896-899
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    • 2002
  • Microcellular foaming Process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This method make the glass transition temperature of polymers low, and diminish the residual stress of polymers. This characteristics of Microcellular foaming process influences the physical properties of recycled polymers. This paper describes about the impact strength change of Microcellular foamed recycled ABS.

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Synthesis of Poly(cinnam-4'-yl methyl methacrylate) Derivatives and Their Thermal Stability as Photoalignment Layer

  • 이종우;김학원;김홍두
    • Bulletin of the Korean Chemical Society
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    • 제22권2호
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    • pp.179-182
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    • 2001
  • Photocyclizable poly(cinnam-4'-yl methyl methacrylate) derivatives bearing methoxy benzene (PMCMMA), anthracene (PACMMA), and coumarin (PCCMMA) have been synthesized via Heck type reaction. Three different types of polymers are photoreactable usin g linearly polarized UV light and applicable as liquid crystal alignment layer. Anthracence and coumarin containing polymers (PACMMA, PCCMMA) have better thermal stability than PMCMMA. This observation may be attributed to the glass transition temperature elevation due to the bulky size and another photocrosslinking site provided by anthracene or coumarin group.

황체퇴화시 황체막 $Na^+-K^+$-ATPase 활성도의 변화 (Change in $Na^+-K^+$-ATPase Activity in Regressive Corpus Luteal Membrane)

  • 김인교;연동수;이승일
    • The Korean Journal of Physiology
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    • 제16권2호
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    • pp.111-117
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    • 1982
  • Slices of rat corpora lutea(CL) incubated with. prostaglandin $F_{{2{\alpha}}}(PGF_{2{\alpha}})$ in Krebs-Hensenleit (K-H) Ringer solution showed a decrease in $Na^+-K^+$-ATPase activity after 60 min of incubation. However, $PGF_{2{\alpha}}$ in vitro did not alter $Na^+-K^+$-ATPase activity of isolated luteal membrane fractions. Following $PGF_{2{\alpha}}$ induced in vivo luteal regression, reduction of Vmax an elevation of the activation energy above transition temperature of the lipid phase of the membrane occurred without changes of Km, optimum pH and transition temperature. These results suggest that reduction of $Na^+-K^+$-ATPase activity after $PGF_{2{\alpha}}$ treatment may be due to the reduction of the number of enzyme molecules or to masking of the active site of the enzyme without any change in enzyme characteristics. In addition, a change in membrane bound enzyme activity may be an early step in $PGF_{2{\alpha}}$ induced luleolysis.

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Fe-Al 금속간 화합물의 고온변형거동에 미치는 Cr 첨가의 효과 (Effect of Cr Addition on the High Temperature Deformation Behavior of Fe-Al Intermetallics)

  • 방원규;임현태;하태권;송진화;장영원
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2001년도 춘계학술대회 논문집
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    • pp.167-171
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    • 2001
  • High temperature deformation behavior of Fe-28Al-5Cr alloy has been investigated known to show anomalous temperature dependence of yield strength. Specifically, the effect of Cr addition has been examined. A series of tensile and load relaxation tests have been carried out to obtain the flow behavior of Fe-28Al-5Cr alloy at the elevated temperatures. The flow curves have then been analyzed using the inelastic deformation theory recently proposed. Firstly, high temperature flow stress of iron aluminides can be resolved into internal stress and frictional stress. Secondly, the temperature corresponding to peak strength gets higher level at faster strain rate, which presumably due to the increased contribution of internal stress in observed flow stress. And thirdly, the alloying of Cr seems to cause solid-solution strengthening of frictional stress level and the elevation of 2nd order transition temperature. In this analogy, Fe-28Al-5Cr exhibits better strength especially at relatively higher temperature and lower strain rate than Fe-28Al.

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침전법으로 제조한 Alumina 분말의 특성(II) : 열처리에 따른 Alumina 분말의 특성 (Properties of Alumina Powder Prepared by Precipitation Method(II) : Properties of Alumina Powder on Heat-Treatment)

  • 홍기곤;이홍림
    • 한국세라믹학회지
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    • 제25권3호
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    • pp.193-200
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    • 1988
  • 침전법에 의해서 pH가 7, 9, 10, 11인 조건에서 생성된 알루미늄 수산화물을 출발물질로 하여 열처리에 따른 알루미나 분말의 특성을 연구하였다. $600^{\circ}C$에서 2시간 동안 열처리하였을 때 비정질 알루미늄 수산화물의 결정수가 탈수된 후에 생성된 최초의 상은 비정질 알루미나의 비표면적은 감소하였다. 비정질 알루미늄 수산화물을 제외한 나머지 알루미늄 수산화물로부터 결정수의 탈수는 비표면적을 증가시켰으며 AlOOH 형태의 수산화물의 존재비가 클수록 전이 알루미나 존재영역까지는 비표면적이 더 크게 나타났다. $\alpha-Al_2O_3$로의 전이속도는 동일온도에서 pH=7 > pH=10 > pH=9 > pH=11의 순서로 일어났으며, 생성된 $\alpha-Al_2O_3$ 분말의 morphology는 알루미늄 수산화물의 외형을 남긴 형골입자(skeleton particle였다. 또한, 열처리 온도의 증가와 $\alpha-Al_2O_3$로의 전이가 일어남에 따라 비표면적의 감소와 더불어 입자성장이 일어나다.

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초미세 발포 사출 시 핵 생성장치를 이용한 셀 크기의 변화 (Cell morphology of microcellular foaming injection molding products with pressure drop rate)

  • 김학빈;차성운
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.491-495
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    • 2004
  • The industries use polymer materials for many purposes for they have many merits. The costs of these materials take up too great a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2$, $N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This characteristic of microcellular foaming process has influenced by cell morphology. The cell morphology means cell size and cell density. The cell morphology has influenced by many factors. The examples of factor are pressure drop rate, foaming temperature, foaming time, saturation pressure, saturation time etc. Among their factors, pressure drop rate is the most important factor for cell morphology in microcellular foaming injection molding process. This paper describes about the cell morphology change in accordance with the pressure drop rate of microcellular foaming injection molding process.

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초미세 발포 공법 시 가스 혼합에 따른 셀 형상 연구 (The Study for Cell Morphology with Gas Cocktail in Microcellular Foaming Process)

  • 차성운;윤재동;이윤성;김학빈
    • 한국정밀공학회지
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    • 제22권6호
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    • pp.168-174
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    • 2005
  • Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.