• 한국초전도ㆍ저온공학회논문지
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• 제15권3호
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• pp.1-4
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• 2013

We investigated the effect of Nb substitution for Ru on the structural and magnetic properties of $(Ru_{1-x}Nb_x)\;Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$ Samples. X-ray diffraction measurements indicated that nearly single-phase samples are formed in the range from x = 0 to 1.0. The superconducting transition temperature determined from the inflection in the field-cooled magnetic susceptibility decreased only slightly from $T_c$ = 25 K for x = 0 to $T_c$ = 22 K for x = 1.0, in consistent with the change in room temperature thermopower of the samples. However, the Nb substitution for Ru above x = 0.25 significantly suppressed the weak ferromagnetic component of the field-cooled magnetic susceptibility. It was also found that the Nb substitution for Ru results in an enhanced diamagnetic susceptibility with Nb content above x = 0.5 in both zero field-cooled and field-cooled magnetization measurements, in contrast to the behavior of the samples with $x{\leq}0.5$ in which the diamagnetic susceptibility decreases as the Nb content increases.

• Progress in Superconductivity
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• 제13권3호
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• pp.163-168
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• 2012

The effects of Ta substitution on the superconducting and magnetic properties of the $(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z(0{\leq}x{\leq}0.5)$ system have been investigated. The X-ray diffraction measurements indicate that the Ta ion replaces Ru sites up to x = 0.4. It is found that the Ta substitution for Ru significantly reduces the weak-ferromagnetic component of the field-cooled magnetic susceptibility without an appreciable change of room temperature thermopower at lower Ta doping level below x = 0.2. The resistive transition temperature tends to decrease monotonically from 27 K for the x = 0 sample to 16 K (9 K) for the x = 0.4 (x = 0.5) sample. These results suggest that superconductivity of the $(Ru_{1-x}Ta_x)Sr_2(Gd_{1.4}Ce_{0.6})Cu_2O_z$ compound is not significantly affected by the magnetic state of the Ru sublattice. The experimental results are discussed in connection with previous reports on the effects of Nb substitution.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1621-1623
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• 1996

The dielectric and polarizable properties of 0.85Pb$Mg_{1/3}Nb_{2/3}$)$O_3$-$0.125PbTiO_3$-$0.25BaTiO_3$ Ceramics have been investigated as a addition of the amount of $La_{2}O_{3}$($0{\leq}x{\geq}0.05$). The Temperature-dependant electrostictive characteristics of 0.85PMN-0.125PT-0.25BT relaxor ferroelectic system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PT-BTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectic permittivity decreased by substituting $La_{2}O_{3}$ and the electic field-related hysteresis phenomena decreased with increasing $La_{2}O_{3}$ substitution amount. It is showed decreasing in induced strain for electric field with increasing $La_{2}O_{3}$ substitution.

• 한국전기전자재료학회논문지
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• 제22권6호
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• pp.484-488
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• 2009

In this study, in order to develop the lead-free piezoelectric ceramics with high piezoelectric and dielectric properties, $[(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}(Nb_{0.96}Sb_{0.04})]O_3$ ceramics were fabricated using $Ag_2O$ as sintering aid and a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $SrTiO_3$ substitution. $SrTiO_3$ substitution enhanced density, dielectric constant(${\varepsilon}_r$) and electromechanical coupling factor($k_p$). However, mechanical quality factor was deteriorated. And also, Curie temperature ($T_c$), and phase transition temperature($T_p$) were rapidly decreased. At the 0.5 mol% $SrTiO_3$ substitution, density, electromechanical coupling factor($k_p$), dielectric constant(${\varepsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.437\;g/cm^3$, 0.457, 1294, 265 pC/N, respectively.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2004년도 High Temperature Superconductivity Vol.XIV
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• pp.38-38
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• 2004

• 대한화학회지
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• 제41권1호
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• pp.22-46
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• 1997

25℃와 35℃에서 메탄올-아세토니트릴 혼합용매계에 대한 할로겐화 펜아실과 피리딘 치환체와의 친핵성치환반응을 속도론적으로 연구하였다. 전이상태 파라미터인 ΔH≠와 ΔS≠ 및 Brosted β값으로 보아 $S_N2$반응 메카니즘을 예상할 수 있었고, 이탈기 변화에 따른 QM모형의 적용으로 이들 반응의 전이상태 역시 생성물 닮은 구조임을 알 수 있었다.

• 한국식품영양학회지
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• 제8권3호
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• pp.172-183
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• 1995

The nucleophilic substitution reactions of p-substituted benzyl bromide with l-substituted N,N-dimethylanilines in methanol and acetonitrile binary solvent mixture which is known to an isodielectric solvent system kinetically and the results are as follows. The positive charge is developed on the reaction center of the substrate and it means that the bond cleavage is preceded more than bond formation in the transition state on the analogy of Hammett px values. The bond form3tlon is not progressed in the case of electron donating substituent of substrate. However, the bond formation is much developed in the case of electron withdrawing substituent of substrate on the analogy of Hammett py values. The nucleophilic attacking ability is shown a highest at 80% (V/V) methanol content and the bond formation is well progressed at the same methanol composition on the result of a cross interaction coefficient, pxy. The result of transition state structure that is applicated to the potential energy surface model is in accord with the result that Is applicated to the reaction susceptibilities. The reaction Is subject to the polarity-polarizability term more than the hydrogen bond donor acidity term by application to the solvatochromic parameter eouation.

• 정보보호학회논문지
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• 제18권4호
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• pp.53-68
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• 2008

실용적인 프라이버시 보호 기술 중의 하나인 행렬 기반 랜덤화 기법에 대하여 세밀한 분석을 실시한다. 최적의 변환 행렬을 찾기 위한 프라이버시 손상 관점의 요구조건 및 정확성 측도로 제안된 행렬의 조건수 개념과 연관된 파라미터들간의 관계를 이론적으로 규명한다. 행렬 기반의 대표적 알고리즘인 랜덤 대치 기법의 효율적인 구현을 위하여 데이터 재구축 과정에서 필요한 역행렬을 간단히 구하는 공식을 제시하고, 행렬의 노름에 따른 변환 행렬의 조건수와 변환된 분포의 기댓값 및 분산을 계산함으로써 표준오차와 파라미터들 간의 관계식을 도출한다. 또한, 랜덤 대치 기법을 구현하여 다양한 시뮬레이션을 실시함으로써 이론적으로 얻은 결과를 실험적으로 검증한다.

• 대한화학회지
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• 제41권2호
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• pp.69-76
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• 1997

메탄올-아세토니트릴 혼합용매에서 벤조산 무수물의 아닐린에 의한 친핵성 치환반응을$35.0{\circ}C$에서 속도론적으로 연구하여 반응 메카니즘을 밝혔다. 벤조산 무수물에 있는 두 개의 카르보닐 탄소에서 경쟁적으로 치환반응이 일어나므로 반응 생성물의 비율로부터 각각의 반응속도$k_{XY}$와$k_{XZ}$를 구하였다. Hammett$p_i$값과 교차작용상수$p_{ij}$를 이용하여 전이상태구조 및 반응메카니즘을 규명하였다. 현저히 큰$p_X,\;p_{XY},\;p_{XZ}$및 양의값을 갖는$p_Y$의 크기로부터, 본 반응이 사각고리 전이상태를 갖는 전면공격$SN_2$메카니즘으로 진행됨을 알았다.

• Journal of Magnetics
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• 제10권1호
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• pp.10-13
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• 2005

We have studied effects of the partial substitution of $La^{3+}$ for $A^{2+}$ on the magnetic properties of double perovskites $A_2FeMoO_6$ (A=Ca, Sr and Ba). Polycrystalline $A_{2-x}La_xFeMoO_6(0{\leq}x{\leq}0.2)$ samples have been prepared by the conventional solid-state reaction in a stream of 5% $H_2$/Ar gas. The x-ray data indicate that A=Ca is monoclinic with the space group P$2_1$/n, A=Sr is tetragonal with the space group I4/mmm, and A=Ba is cubic with the space group Fm3m. The substitution of $La^{3+}$ for $A^{2+}$ results in a cell volume increase for A=Ca and a cell volume reduction for A=Ba. The decrease of saturation magnetization with increasing x arises from the reduction of magnetic moment associated with the electron doping and the disorder at the Fe and Mo sites. The partial substitution of magnetic $La^{3+}$ for $A^{2+}$ considerably enhances the Curie temperature $T_c$ from 316 K for x = 0 to 334 K for x = 0.2. This enhancement of $T_c$ with $La^{3+}$ doping originates from electron doping effects in addition to ionic size ones.