• Title/Summary/Keyword: Transition prediction

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Study on Separation of Heavy Metal Ions in A Neutral Macrocycle-Mediated Emulsion Liquid Membrane System

  • Moon-Hwan Cho;Hea-Suk Chun;Jin-Ho Kim;Chang-Hwan Rhee;Si-Joong Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.474-477
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    • 1991
  • The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.

Numerical investigation of turbulence models with emphasis on turbulent intensity at low Reynolds number flows

  • Musavir Bashir;Parvathy Rajendran;Ambareen Khan;Vijayanandh Raja;Sher Afghan Khan
    • Advances in aircraft and spacecraft science
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    • v.10 no.4
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    • pp.303-315
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    • 2023
  • The primary goal of this research is to investigate flow separation phenomena using various turbulence models. Also investigated are the effects of free-stream turbulence intensity on the flow over a NACA 0018 airfoil. The flow field around a NACA 0018 airfoil has been numerically simulated using RANS at Reynolds numbers ranging from 100,000 to 200,000 and angles of attack (AoA) ranging from 0° to 18° with various inflow conditions. A parametric study is conducted over a range of chord Reynolds numbers for free-stream turbulence intensities from 0.1 % to 0.5 % to understand the effects of each parameter on the suction side laminar separation bubble. The results showed that increasing the free-stream turbulence intensity reduces the length of the separation bubble formed over the suction side of the airfoil, as well as the flow prediction accuracy of each model. These models were used to compare the modeling accuracy and processing time improvements. The K- SST performs well in this simulation for estimating lift coefficients, with only small deviations at larger angles of attack. However, a stall was not predicted by the transition k-kl-omega. When predicting the location of flow reattachment over the airfoil, the transition k-kl-omega model also made some over-predictions. The Cp plots showed that the model generated results more in line with the experimental findings.

Whole Stand Survival Prediction Model in Slash Pine Plantations Infected with Fusiform Rust (수병(銹病)에 감염(感染)된 슬래쉬소나무 조림지(造林地)에 대한 임분단위(林分單位)의 생존 (生存) 예측모형(豫測模型))

  • Lee, Young-Jin;Hong, Sung-Cheon
    • Journal of Korean Society of Forest Science
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    • v.89 no.4
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    • pp.480-487
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    • 2000
  • Repeated measurement of 472 permanent subplots in slash pine (Pinus elliottii Engelm.) plantations were used to develop survival prediction equations for predicting future number of planted slash pine trees. On the average, about 40 percent of the slash pines in the experimental sites had a stem cankers due to fusiform rust (Cronartium quercuum [Berk.] Miyabe ex Shirai f. sp. fusiforme) incidence. A stand level survival prediction model was developed that incorporated the incidence of fusiform rust and allowed the transition paths of trees from an uninfected stage to an infected stage. Predicted total surviving number of trees is obtained by adding together the predicted number of infected and uninfected trees. The influence of natural hardwood density and site quality on slash pine survivals tended to show a negative effects on future survivals.

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Overpressure prediction of the Efomeh field using synthetic data, onshore Niger Delta, Nigeria (합성탄성파 기록을 이용한 나이지리아의 나이저 삼각주 해안 에포메(Efomeh) 지역의 이상고압 예측)

  • Omolaiye, Gabriel Efomeh;Ojo, John Sunday;Oladapo, Michael Ilesanmi;Ayolabi, Elijah A.
    • Geophysics and Geophysical Exploration
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    • v.14 no.1
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    • pp.50-57
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    • 2011
  • For effective and accurate prediction of overpressure in the Efomeh field, located in the Niger delta basin of Nigeria, integrated seismic and borehole analyses were undertaken. Normal and abnormal pore pressure zones were delineated based on the principle of normal and deviation from normal velocity trends. The transition between the two trends signifies the top of overpressure. The overpressure tops were picked at regular intervals from seismic data using interval velocities obtained by applying Dix's approximation. The accuracy of the predicted overpressure zone was confirmed from the sonic velocity data of the Efomeh 01 well. The variation to the depth of overpressure between the predicted and observed values was less than 10mat the Efomeh 01 well location, with confidence of over 99 per cent. The depth map generated shows that the depth distribution to the top of the overpressure zone of the Efomeh field falls within the sub-sea depth range of 2655${\pm}$2m (2550 ms) to 3720${\pm}$2m (2900 ms). This depth conforms to thick marine shales using the Efomeh 01 composite log. The lower part of the Agbada Formation within the Efomeh field is overpressured and the depth of the top of the overpressure does not follow any time-stratigraphic boundary across the field. Prediction of the top of the overpressure zone within the Efomeh field for potential wells that will total depth beyond 2440m sub-sea is very important for safer drilling practice as well as the prevention of lost circulation.

Plasticity and Fracture Behaviors of Marine Structural Steel, Part IV: Experimental Study on Mechanical Properties at Elevated Temperatures (조선 해양 구조물용 강재의 소성 및 파단 특성 IV: 고온 기계적 물성치에 관한 실험적 연구)

  • Choung, Joon-Mo;Im, Sung-Woo;Park, Ro-Sik
    • Journal of Ocean Engineering and Technology
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    • v.25 no.3
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    • pp.66-72
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    • 2011
  • This is the fourth of a series of companion papers dealing with the mechanical property reductions of various marine structural steels. Even though a reduction of the elastic modulus according to temperature increases has not been obtained from experiments, high temperature experiments from room temperature to $900^{\circ}C$ revealed that initial the yield strength and tensile strength are both seriously degraded. The mechanical properties obtained from high temperature experiments are compared with those from EC3 (Eurocode 3). It is found that the high temperature test results generally comply with the prediction values by EC3. Based on the prediction of EC3, time domain nonlinear finite element analyses were carried out for a blast wall installed on a real FPSO. After applying the reduced mechanical properties, corresponding to $600^{\circ}C$ to the FE model of the blast wall, more than three times the deflections were observed and it was observed that most structural parts experience plastic deformations exceeding the reduced yield strength at the high temperature. It is noted that a protection facility such as PFP (passive fire protection) should be required for structures likely to be directly exposed to fire and explosion accident.

Fundamentals of Particle Fouling in Membrane Processes

  • Bhattacharjee Subir;Hong Seungkwan
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.1-18
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    • 2005
  • The permeate flux decline due to membrane fouling can be addressed using a variety of theoretical stand-points. Judicious selection of an appropriate theory is a key toward successful prediction of the permeate flux. The essential criterion f3r such a decision appears to be a detailed characterization of the feed solution and membrane properties. Modem theories are capable of accurately predicting several properties of colloidal systems that are important in membrane separation processes from fundamental information pertaining to the particle size, charge, and solution ionic strength. Based on such information, it is relatively straight-forward to determine the properties of the concentrated colloidal dispersion in a polarized layer or the cake layer properties. Incorporation of such information in the framework of the standard theories of membrane filtration, namely, the convective diffusion equation coupled with an appropriate permeate transport model, can lead to reasonably accurate prediction of the permeate flux due to colloidal fouling. The schematic of the essential approach has been delineated in Figure 5. The modern approaches based on appropriate cell models appear to predict the permeate flux behavior in crossflow membrane filtration processes quite accurately without invoking novel theoretical descriptions of particle back transport mechanisms or depending on adjust-able parameters. Such agreements have been observed for a wide range of particle size ranging from small proteins like BSA (diameter ${\~}$6 nm) to latex suspensions (diameter ${\~}1\;{\mu}m$). There we, however, several areas that need further exploration. Some of these include: 1) A clear mechanistic description of the cake formation mechanisms that clearly identifies the disorder to order transition point in different colloidal systems. 2) Determining the structure of a cake layer based on the interparticle and hydrodynamic interactions instead of assuming a fixed geometrical structure on the basis of cell models. 3) Performing well controlled experiments where the cake deposition mechanism can be observed for small colloidal particles (< $1\;{\mu}m$). 4) A clear mechanistic description of the critical operating conditions (for instance, critical pressure) which can minimize the propensity of colloidal membrane fluting. 5) Developing theoretical approaches to account for polydisperse systems that can render the models capable of handing realistic feed solutions typically encountered in diverse applications of membrane filtration.

Analysis of Intention in Spoken Dialogue based on Classifying Sentence Patterns (문형구조의 분류에 따른 대화음성의 의도분석에 관한 연구)

  • Choi, Hwan-Jin;Song, Chang-Hwan;Oh, Yung-Hwan
    • The Journal of the Acoustical Society of Korea
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    • v.15 no.1
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    • pp.61-70
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    • 1996
  • According to topics or speaker's intentions in a dialogue, utterance spoken by speaker has a different sentence structure of word combinations. Based on these facts, we have proposed the statistical approach. IDT(intention decision table), which is modeling the correlations between sentence patterns and the intention. In a IDT, the sentence is splitted into 5 different factors, and the intention of a sentence is determined by the similarity between and intention and 5 factors that have represent a sentence. From the experimental results, the IDT has indicated that the prediction rate of an intention is improved 10~18% over the word-intention correlations and is enhanced 3~12% compared with the MIG(Markov intention graph) that models the intention with a transition graph for word categories in a sentence. Based on these facts, we have found that the IDT is effective method for the prediction of an intention.

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A Study on the Prediction of Thermally-Induced Residual Stress and Birefringence in Quenched Polystyrene Plate Including Free Volume Theory (자유 체적이론을 고려한 급냉 폴리스티렌판에 발생하는 잔류응력과 복굴절 형성에 관한 연구)

  • Kim, Jong-Sun;Yoon, Kyung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.77-87
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    • 2003
  • The residual stress and birefringence in injection-molded plastic parts can be divided into the flow-induced residual stress and birefringence produced in flowing stage, the thermally-induced residual stress and birefringence produced in cooling stage. However, the physics involved in the generation of the thermally-induced residual stress and birefringence still remains to be understood. Because polymer experiences viscoelastic history near the glass-transition temperature it is hard to model the entire process. Volume relaxation phenomenon was included to predict the final thermally-induced residual stress and birefringence in quenched plastic parts more accurately. The present study focused on comparing the predicted values far thermally-induced residual stress and birefringence with and without volume relaxation behavior (or free volume theory) under free and constrained quenching conditions. As a result, tile residual stress remained as a tensile stress at the center and as a compressible stress near the surface for the free quenching cases. In contract the residual stress remained as a compressible stress at the center and as a tensile stress near the surface fur the constrained quenching cases. The residual birefringence remained as minus values at the center and as plus values near the surface for the free quenching cases. Interestingly the residual birefringence showed minus values in entire zone for the constrained quenching cases. In the prediction of birefringence only the case including free volume theory showed the correct result for the distribution of birefringence in thickness direction.

Prediction of energy expenditure from a tri-axial accelerometer during treadmill walking (트레드밀 보행 시 단일 3축 가속도센서를 사용한 대사에너지 소모량 예측)

  • Lee, H.Y.;Park, S.W.;Kim, S.H.;Lee, D.Y.;Kim, Y.H.
    • Journal of Biomedical Engineering Research
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    • v.32 no.2
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    • pp.79-84
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    • 2011
  • The purpose of this study was to investigate the relevance of the prediction equations derived from the relationship between metabolic energy expenditure and kinetic energy, for different speeds of walking and running over the treadmill. Seven male subjects participated in this study. A tri-axial accelerometer was attached on between the left and right posterior superior iliac spines. Kinetic energy was calculated by the integration of acceleration data and compared with the metabolic energy measured by a gas analyzer. Correlation coefficients were determined to find a relationship between the kinetic energy and the metabolic energy expenditure. Also, the difference between measured and predicted values was used to find the relevance for individual and group equations. Results showed a relatively good correlation between the measured metabolic energy and the calculated kinetic energy. In addition, a dramatic increase in kinetic energy was observed at the transition speed of walking and running (6 km/h). There was no difference in how to predict the kinetic energy expenditure for individual and group even though people have different physical characteristics. This study would be useful to predict metabolic energy expenditures by the regression analysis with acceleration data.

A Comparison of Correction Models for the Prediction of Tropospheric Propagation Delay of GPS Signals (GPS 신호의 대류층 지연 예측을 위한 보정모델의 비교)

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    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.20 no.3
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    • pp.283-291
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    • 2002
  • Since GPS's SA cancellation, the interest is converged in correction of errors such as atmospheric delay and multipath that weight had been small relatively, which can improve the accuracy of positioning through modelling research. The aim of this study have an extensive comparison of the various tropospheric delay models (Goad&Goodman, A&K, Hopfield and Sasstamoinen) and mapping functions(Niell, Chao, and Marini). Expecially, the tropospheric delay amounts by change of the GPS satellite elevations, and the delay by various combination between zenith delay models and mapping functions, compared and examined. For this, programmed the total delay models and the combined models which can be described as a product of the delay at the zenith and a mapping function. The result of study, especially, as the minimum elevation of included data is reduced under $10^{\circ}$, it was considered to be reasonable that the prediction of tropospheric delay considering combination and mapping character of functions about the transition of the zenith delay to a delay with arbitrary zenith angle.