• Title/Summary/Keyword: Transient liquid phase processing

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Low Temperature Sintering of PZTN by the Liquid Phase Transient Processing (액상천이공정에 의한 PZTN의 저온소결에 관한 연구)

  • Kim, Chan-Yeong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.12
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    • pp.593-598
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    • 2001
  • Transient liquid phase processing was investigated to decrease processing temperatures while maintaining useful piezoelectric properties in the lead zirconate titanate (PZT) system. Niobium oxide$(Nb_2O_5)$ modified crystalline PZT (PZTN) powder was combined with lead silicate $(PS; PbO-SiO_2)$ glass powder and crystalline titania, zirconia, and niobia. Firing above the melting temperature of the lead silicate $(PS; Tm \risingdotseq\; 714^{\circk}C)$ resulted in liquid phase densification of the PZTN followed by dissolution of the titania, zirconia, and niobia into the liquid phase, and crystallization of additional PZTN. The addition of crystalline titania, zirconia, and niobia to react with the lead oxide from the lead silicate phase resulted in an increase in the dielectric and Piezoelectric properties.

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Investigation of molten fuel coolant interaction phenomena using real time X-ray imaging of simulated woods metal-water system

  • Acharya, Avinash Kumar;Sharma, Anil Kumar;Avinash, Ch.S.S.S.;Das, Sanjay Kumar;Gnanadhas, Lydia;Nashine, B.K.;Selvaraj, P.
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1442-1450
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    • 2017
  • In liquid metal fast breeder reactors, postulated failures of the plant protection system may lead to serious unprotected accidental consequences. Unprotected transients are generically categorized as transient overpower accidents and transient under cooling accidents. In both cases, core meltdown may occur and this can lead to a molten fuel coolant interaction (MFCI). The understanding of MFCI phenomena is essential for study of debris coolability and characteristics during post-accident heat removal. Sodium is used as coolant in liquid metal fast breeder reactors. Viewing inside sodium at elevated temperature is impossible because of its opaqueness. In the present study, a methodology to depict MFCI phenomena using a flat panel detector based imaging system (i.e., real time radiography) is brought out using a woods metal-water experimental facility which simulates the $UO_2-Na$ interaction. The developed imaging system can capture attributes of the MFCI process like jet breakup length, jet front velocity, fragmented particle size, and a profile of the debris bed using digital image processing methods like image filtering, segmentation, and edge detection. This paper describes the MFCI process and developed imaging methodology to capture MFCI attributes which are directly related to the safe aspects of a sodium fast reactor.

The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor (녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결)

  • Park, Young-Jo;Lee, Sung-Hoon;Jang, Wook-Kyung;Yoon, Chang-Bun;Yoon, Chul-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.