• 제목/요약/키워드: Transient absorption

검색결과 97건 처리시간 0.026초

바이오 디젤 적용에 따른 대형엔진의 배출가스 특성 (The Emission Characteristics of Bio-Diesel Fuel in Heavy-Duty Engine)

  • 김선문;엄명도;홍지형
    • 한국대기환경학회지
    • /
    • 제26권5호
    • /
    • pp.499-506
    • /
    • 2010
  • Recently, a great deal of attention have been directed to the use of alternative fuels as a means to reduce vehicular emissions. As one of the promising alternative fuels, bio-diesel has advantages of a wide adaptability without retrofit of diesel engine. It is also effective enough to reduce CO, THC, $SO_x$, polycyclic aromatic hydrocarbons (PAHs) and PM. In this study, we investigated the emission characteristics of biofuels between different operating conditions, i.e., engine speed (1,400 rpm and 2,300 rpm), engine load (10% and 100%), bio-diesel blending (BD0, BD5 and BD20), and recirculation (EGR) rate of exhaust gas (0% and 20%). Relative performance of the system was evaluated mainly for the greenhouse gases ($CH_4$, $N_2O$ and $CO_2$). In addition, emission characteristics of ND-13 mode were also tested against both greenhouse gases and other airborne pollutants under emission regulation. The relative composition of bio-diesel has shown fairly clear effects on the emission quantities of CO, THC, and PM emission, although it was not on $NO_x$ and greenhouse gases. EGR rate has shown trade-off characteristics between $NO_x$ and PM.

고온.다습하(高溫.多濕下)에서의 복합재료(複合材料)의 수요특성(特性) 및 기계적특성(機械的特性)에 관한 연구(硏究) (A Study on the Dielectric Properties and Mechanical characteristics of Composit Materials due to the High-Temper, and-Humidity)

  • 이종호;이규철;황영한;김희대;이태식;박홍태
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1992년도 하계학술대회 논문집 B
    • /
    • pp.750-752
    • /
    • 1992
  • The paper presents the effects of environment on glass-cloth/epoxy composites exposed to humid air were investigated. Tests were performed at temperature 40$^{\circ}C$ and 70$^{\circ}C$ with the materials exposed to humid air at 76% and 90% relative humidity. This investigation surveyed include (a) the moisture absorption and desorption characteristics of single and multi layered composites exposed to steady and to transient ambients, and (b) the resulting changes in tensile strength, dielectric strength, tan $\delta$ and $\varepsilon_{\tau}$ and the effects of environment on these parameters were assessed.

  • PDF

Formation and Cycloreversion of 2-Silacyclobuta[2.3]cyclophances via Photoinduced Electron Transfer

  • Mizuno, Kazuhiko;Nakanishi, Kazuhisa;Otsuji, Yoshio;Hayamizu, Tomoo;Maeda, Hajime;Adachi, Tomohiro;Ishida, Akito;Takamuku, Setsuo
    • Journal of Photoscience
    • /
    • 제10권1호
    • /
    • pp.121-126
    • /
    • 2003
  • Irradiation of an acetonitrile solution containing dimethylbis(4-vinylphenylmethyl)silane 1a in the presence of 9,10-dicyanoanthracene leads to formation of the intramolecular photocycloadduct, 2-sila-cyclobuta[2.3]cyclophane(2a). In contrast, prolonged irradiation gave insoluble polymeric material. The photocycloreversion of 2a occurs efficiently (quantum yields exceeds unity) by use of redox-type photosensitization in the presence of magnesium perchlorate. The transient absorption spectra generated by pulse radiolysis and gamma-radiolysis show that the radical cation species generated from 1a is different from that arising from 2a.

  • PDF

Numerical and experimental investigation on the temperature distribution of steel tubes under solar radiation

  • Liu, Hongbo;Chen, Zhihua;Zhou, Ting
    • Structural Engineering and Mechanics
    • /
    • 제43권6호
    • /
    • pp.725-737
    • /
    • 2012
  • The temperature on steel structures is larger than the ambient air temperature under solar radiation and the temperature distribution on the affected structure is non-uniform and complicated. The steel tube, as a main structural member, has been investigated through experiment and numerical analysis. In this study, the temperature distribution on a properly designed steel tube under solar radiation is measured. A finite element transient thermal analysis method is presented and verified by the experimental results and a series of parametric studies are carried out to investigate the influence of various geometric properties and orientation on the temperature distribution. Furthermore, a simplified approach is proposed to predict the temperature distribution of steel tube. Based on both the experimental and the numerical results, it is concluded that the solar radiation has a significant effect on the temperature distribution of steel tubes. Under the solar radiation, the temperature of steel tubes is about $20.6^{\circ}C$ higher than the ambient air temperature. The temperature distribution of steel tubes is sensitive to the steel solar radiation absorption, steel tube diameter and orientation, but insensitive to the solar radiation reflectance and thickness of steel tube.

자동차용 고분자전해질형연료전지 스택에서의 막-전극접합체 설계인자가 저온시동에 미치는 영향성 연구 (Analyzing the Effects of MEA Designs on Cold Start Behaviors of Automotive Polymer Electrolyte Fuel Cell Stacks)

  • 곽건희;고요한;주현철
    • 한국수소및신에너지학회논문집
    • /
    • 제23권1호
    • /
    • pp.8-18
    • /
    • 2012
  • This paper presents a three-dimensional, transient cold-start polymer electrolyte fuel cell (PEFC) model to numerically evaluate the effects of membrane electrode assembly (MEA) design and cell location in a PEFC stack on PEFC cold start behaviors. The cold-start simulations show that the end cell experiences significant heat loss to the sub-freezing ambient and thus finally cold-start failure due to considerable ice filling in the cathode catalyst layer. On the other hand, the middle cells in the stack successfully start from $-30^{\circ}C$ sub-freezing temperature due to rapid cell temperature rise owing to the efficient use of waste heat generated during the cold-start. In addition, the simulation results clearly indicate that the cathode catalyst layer (CL) composition and thickness have an substantial influence on PEFC cold-start behaviors while membrane thickness has limited effect mainly due to inefficient water absorption and transport capability at subzero temperatures.

녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결 (The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor)

  • 박영조;이성훈;장욱경;윤창번;윤철수
    • 한국세라믹학회지
    • /
    • 제47권6호
    • /
    • pp.503-508
    • /
    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.

Pseudohypoaldosteronism Type 1

  • Cheong, Hae Il
    • Journal of Genetic Medicine
    • /
    • 제10권2호
    • /
    • pp.81-87
    • /
    • 2013
  • Pseudohypoaldosteronism (PHA), a rare syndrome of systemic or renal mineralocorticoid resistance, is clinically characterized by hyperkalemia, metabolic acidosis, and elevated plasma aldosterone levels with either renal salt wasting or hypertension. PHA is a heterogeneous disorder both clinically and genetically and can be divided into three subgroups; PHA type 1 (PHA1), type 2 (PHA2) and type 3 (PHA3). PHA1 and PHA2 are genetic disorders, and PHA3 is a secondary disease of transient mineralocorticoid resistance mostly associated with urinary tract infections and obstructive uropathies. PHA1 includes two different forms with different severity of the disease and phenotype: a systemic type of disease with autosomal recessive inheritance (caused by mutations of the amiloride-sensitive epithelial sodium channel, ENaC) and a renal form with autosomal dominant inheritance (caused by mutations of the mineralocorticoid receptor, MR). In the kidneys, the distal nephron takes charge of the fine regulation of water absorption and ion handling under the control of aldosterone. Two major intracellular actors necessary for the action of aldosterone are the MR and the ENaC. Impairment of the intracellular aldosterone signal transduction pathway results in resistance to the action of mineralocorticoids, which leads to PHA. Herein, ion handling the distal nephron and the clinico-genetic findings of PHA are reviewed with special emphasis on PHA type 1.

Effects of Incubation Temperature on Egg Development, Hatching and Pigment Plug Evacuation in Farmed Siberian Sturgeon Acipenser baerii

  • Park, Chulhong;Lee, Sang Yoon;Kim, Dong Soo;Nam, Yoon Kwon
    • Fisheries and Aquatic Sciences
    • /
    • 제16권1호
    • /
    • pp.25-34
    • /
    • 2013
  • Early ontogenic development in Siberian sturgeon Acipenser baerii was documented and the effects of different temperatures on embryonic and prelarval development were examined. Photograph-assisted data on morphogenesis in Siberian sturgeon prolarvae agreed well with published descriptions of their ontogeny and ecological behaviors, although certain aspects of differentiation, such as gill covering and scute development, could be rearing condition-sensitive. The present study provides the first characterization of the transient development of teeth during early larval stages; the pattern was congruent with the transition of prolarvae to exogenous feeding. From examinations of embryonic and prelarval development under different temperature conditions ($12-24^{\circ}C$), developmental speed was inversely related with temperature. Overall, hatchability was higher and hatching events were more synchronized at $20^{\circ}C$ than at lower temperatures. After hatching, similar patterns of temperature-dependency were observed in yolk sac absorption and the evacuation of the pigment plug. Our results suggest that the incubation of Siberian sturgeon embryos and prolarvae at temperatures close to $20^{\circ}C$ would be advantageous in hatcheries, based on reductions in the duration and uniformity of egg and prolarval developmental stages.

레이저-GMA 하이브리드 용접에서 유동에 의한 기포 및 기공 형성 해석 (Numerical Simulation of Bubble and Pore Generations by Molten Metal Flow in Laser-GMA Hybrid Welding)

  • 조원익;조정호;조민현;이종봉;나석주
    • Journal of Welding and Joining
    • /
    • 제26권6호
    • /
    • pp.67-73
    • /
    • 2008
  • Three-dimensional transient simulation of laser-GMA hybrid welding involving multiple physical phenomena is conducted neglecting the interaction effect of laser and arc heat sources. To reproduce the bubble and pore formations in welding process, a new bubble model is suggested and added to the established laser and arc welding models comprehending VOF, Gaussian laser and arc heat source, recoil pressure, arc pressure, electromagnetic force, surface tension, multiple reflection and Fresnel reflection models. Based on the models mentioned above, simulations of laser-GMA hybrid butt welding are carried out and besides the molten pool flow, top and back bead formations could be observed. In addition, the laser induced keyhole formation and bubble generation duo to keyhole collapse are investigated. The bubbles are ejected from the molten pool through its top and bottom regions. However, some of those are entrapped by solid-liquid interface and remained as pores. Those bubbles and pores are intensively generated when the absorption of laser power is largely reduced and consequently the full penetration changes to the partial penetration.

Ultrafast Time-Resolved Laser Spectroscopic Studies of trans-Bis(ferrocene-carboxylato)(tetraphenyl-porphyrinato)tin(IV): Intramolecular Electron-Transfer Dynamics

  • Jang, Joon-Hee;Kim, Hee-Jung;Kim, Hee-Joon;Kim, Chul-Hoon;Joo, Tai-Ha;Cho, Dae-Won;Yoon, Min-Joong
    • Bulletin of the Korean Chemical Society
    • /
    • 제28권11호
    • /
    • pp.1967-1972
    • /
    • 2007
  • Photophysical properties of a newly-synthesized porphyrin derivative, trans-bis(ferrocene carboxylato)- (5,10,15,20-tetraphenylporphyrinato)tin(IV) [Sn(TPP)(FcCOO)2] were investigated by means of steady-state and fs-time resolved laser spectroscopic techniques, and compared with those of a standard molecule, trans-dichloro( 5,10,15,20-tetraphenyl-porphrinato)tin(IV) [Sn(TPP)Cl2]. The fluorescence spectrum of Sn(TPP)- (FcCOO)2 was observed to exhibit dual emission bands originating from the S2-state and the S1-state, which was greatly quenched as compared to those of Sn(TPP)Cl2. The fs-time resolved fluorescence and transient absorption spectroscopic measurements revealed that the fluorescence quenching is due to formation of the long-lived charge transfer state by intramolecular electron transfer from ferrocene to the S2-excited SnTPP in addition to the enhanced non-radiative deactivation processes.