• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.84-87
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• 1988

The Photophysical and photochemical properties of Ruthenium bipyridine with two long hydrocarbon chains, $[Ru(bipy)_2(dhbipy)]^{2+}$ and transient phenothiazine derivative cation radical $(PTD^+)$ in the cationic vesicle were studied. Transient absorption spectra of cation radical of phenothiazine derivative in the vesicle system containing the $Ru^{2+}$ complex, $[Ru(bipy)_2(dhbipy)]^{2+}$, (1) as sensitizer and phenothiazine derivative as electron donor was observed by XeCl excimer laser photolysis system. Thus the excited ruthenium complex would be quenched by phenothiazine derivative(PTD) reductively in the vesicle system. The quenching rate constant($K_Q$) of $Ru^{2+}$ with two long hydrocarbon chains in the vesicle by PTD was $9.6{\times}10^8M^{-1}S^{-1}$. The absorption decay kinetics showed that lifetime of phenothiazine derivative cation radical is a value in the 4-8m sec range.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.12
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• pp.695-702
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• 2009

Dynamic behavior of Libr-water absorption system using low-temperature hot water was investigated numerically. Thermal-hydraulic model of single-effect/double-lift 100 RT chiller was developed by applying transient conservation equations of total mass, Libr mass, energy and momentum to each component. Transient variations of system properties and transport variables were analysed during start-up operation. Numerical analysis were performed to quantify the effects of bulk concentration and part-load operation on the system performance in terms of cooling capacity, coefficient of performance, and time constant of system. For an absorption chiller considered in the present study, optimum bulk concentration was found to exist, which resulted in the minimum time constant with stable cooling capacity. COP and time constant increased as the load decreased down to 40%, below which the time constant increased abruptly and COP decreased as the load decreased further.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.10
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• pp.990-998
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• 2004

Dynamic behavior of an ammonia-water absorption system was investigated numerically. Thermal-hydraulic model for a single-effect 3 RT chiller was developed by applying transient conservation equations of total mass, $NH_3$ mass, energy and momentum to each component. Transient variations of system properties and transport variables were analysed during start-up operation. Numerical analyses were performed to quantify the effects of bulk concentration and charging ratio on the system performance in terms of cooling capacity, coefficient of performance, and time constant of system. For an absorption chiller considered in the present study, optimum charging ratio and bulk concentration were to found to exist, which resulted in the maximum cooling capacity and COP. The time constant increased as the charging ratio increased, but decreased with the increase of bulk concentration.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.1 no.1
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• pp.46-54
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• 1989

The purpose of this study is to obtain the dynamic characteristics of an absorption refrigerator powered by solar energy by experiments. Since the absorption refrigerator power by solar energy should have the characteristics which is suitable for the intermittence and rarity of solar energy, not only the characteristics of the steady state operations but also the partial load and the transient operations should be considered. The minimum available temperature of the storage tank should be known, and the absorption refrigerator can be suitably selected for air-conditioning systems. In this study, the experimental data of the transient state for on-off and warming-up operations has been obtained. Also the experiments are performed which test the minimum available temperature of the storage tank. The results show that it takes 1 hour to get to the steady state of the absorption refrigerator, and the minimum available temperature of the storage tank is about $68^{\circ}C$, and show that in the partial load operations the performance of the absorption refrigerator is improved by applying the modified control method to on-off operations.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.6
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• pp.102-107
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• 2007

A fast response $CO_2$ ($fCO_2$) analyzer for real-time measurement of carbon dioxide concentration during transient states of internal combustion engines has been developed. This analyzer uses non-dispersive infrared absorption (NDIR) technique for measuring $CO_2$ concentration and Kalman filter for removing noise components from output signals. The analyzer has good linearity, repeatability and drift with a response time of 11 ms; it is sufficiently fast to detect $CO_2$ concentration during transient states of internal combustion engines. The $fCO_2$ analyzer was used to measure transient $CO_2$ concentration of exhaust gas of the SI engine with a standard gas analyzer, and the signal of the $fCO_2$ analyzer was compared to that of the standard gas analyzer. The two concentrations were well matched during the steady state, and the $fCO_2$ analyzer could measure the variations of $CO_2$ concentration during the transient state.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.255-259
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• 1990

The nitrogen-laser flash photolysis apparatus has been set up to detect directly the transient produced from the excited Benoxaprofen (BXP). The function of the instrument has been tested by using anthracene as a standard sample. The laser photoexcitation of BXP in ethanol has been carried out under a constant stream of $N_2$ gas and a transient absorption spectrurn has been recorded over the 400-600 nm. The effects of oxygen and ${\beta}-carotene$ on the transient spectrum reveal that thee maximum transient absorption at 415 nm is attributed to the triplet state of BXP and the triplet energy of BXP is above 22 Kcal/mole. In addition to the triplet state, another transient species has been observed to be produced, which is probably a radical form of BXP. The photosensitization mechanism of BXP is discussed based on these results.

• Rapid Communication in Photoscience
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• v.1 no.2
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• pp.35-37
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• 2012

Photoinduced electron-transfer process of 1,8-naphthalimide-linker-trimethylsilane (NI-O3-TMS, O3 = 3,6,9-trioxaundecyl) and NI-O3 has been investigated using the transient absorption measurements in $CH_3CN$ and $CH_3CN/H_2O$. The excitation of NI-O3-TMS in $CH_3CN$ produced the NI radical anion ($NI^{{\cdot}-}$) with a transient absorption band around 413 nm, via the intermolecular electron-transfer between NI moieties in the excited singlet state. In contrast, in a protic polar solvent mixture of $CH_3CN/H_2O$, a proton abstraction process occurred from $NI^{{\cdot}-}$ to generate the NI ketyl radical ($NIH^{\cdot}$), which showed a transient absorption band around 405 nm. The decay time constants of $NIH^{\cdot}$ were quite long compared to those of $NI^{{\cdot}-}$ in $CH_3CN$.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.1
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• pp.121-130
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• 1986

Using the sbsorption coefficients and the weighting factors of the gray gas, the total emissivities of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures can be expressed by the following equation, [a numerical formula] Where, $a_{i}$ and $K_{i}$ represent the weighting factor and the absorption coeffient of i-gray gas respectively; L is the pathlength of the gas. This equation is widely used for the analyses of the radiation heat transfer in the combustors of internal combustion engines and in the furnace of external combustion engines. In this work, a simple calculation model of the weighting factor and the absorption coeffient of the above equation was developed. The weighting factors and the absorption coefficients of combustion products were calculated by applying the model to various kinds of fossil fuels such as coal and heavy oil. Then, the computed total emissivities for each fuel and pathlength were compared with measured and calculated values which have been already published in the literatures. The followings were the results obtained through the comparisons between the calculated emissivites and the published values; the developed model for the calculations of the weighting factor and the absorption coefficient of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures could be applied over the wide ranges of the temperature and the pathlength; the errors between the total emissivities calculted and the values published were maximum 10%, and average 1%, respectively.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.165-169
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• 2008

Binary nanofluids(Binary mixture + nanoparticles) have been extensively paid attention for application in absorption system as a new working fluid. Thermal property evaluation of the new refrigerants is inevitable to apply them for actual system. The objectives of this paper are to measure the thermal conductivity of the binary nanofluids by the transient hot-wire method, and to assess the application possibility of the binary nanofluids for absorption system. It was found that the thermal conductivity of the binary nanofluids ($H_2O/LiBrAl_2O_3$) increased with increasing the concentration of the nanoparticles ($Al_2O_3$) and enhanced up to 27% at 0.1 vol % of the nanoparticles.

• Journal of the Korean Vacuum Society
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• v.8 no.3B
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• pp.353-360
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• 1999

The global balance model is applied to investigate the transient behavior of the electron density and temperature in helicon plasmas. The power absorption calculated from the solutions of the Maxwell equations is used in solving the power balance equation. A balance model for the neutral gas is also considered to fins its density self-consistently. It is turned out that the numerical results reasonably explain consequences of the ion pumping effect including the occurrence of two distinct modes of pulsed helicon discharge which have been observed experimentally. The behavior of the discharge parameters are fond to be primarily dependent on the power absorption and the gas flow rate, but the pressure controls the electron density and temperature of the final steady state as well as the transient state even with the same flow rate. Finally, it is shown that the electron density virtually the linear relationship between the density and the magnetic field is retained for a higher pressure when the effect of the ion pumping is negligible.