• Bulletin of the Korean Chemical Society
• /
• 제20권11호
• /
• pp.1269-1276
• /
• 1999

Metallocenes, whether using a cocatalyst or not, act as catalysts in ethylene polymerization. The positive charge on the transition metal of a metallocene might have an important role in polymerization as an active site in our model approach. Using semiempirical calculations in the absence of cocatalyst, we show one of the possibilities that the positive charge on a metallocene might be more easily transferred through the Cp ring of a ligand to the ethylene than to transfer directly from the transition metal to the ethylene. In these calculations, the charge on titanium in an eight C2H4 system is transferred and a polymer chain is produced. This reaction takes place only when ethylenes are arranged in a particular direction with respect to the ring, but does not take place for ethylenes near Ti or Cl atoms. The same mechanism is shown for a metallocene ligand which is sterically hindered or where the Cp ring is replaced by fluorenyl. These results suggest an entirely new polymerization mechanism in the absence of a cocatalyst in which the Cp ring is the active site.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집
• /
• pp.497-500
• /
• 2001

Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e,g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
• /
• pp.286-290
• /
• 1999

Electroluminescence is occurred when phosphor is located in electric field. In this paper, we made powder electroluminescent device (PELD) with structured ITO film/Phosphor/Insulator/Silver paste. The transparent electrode was ITO film and green(2704-01), orange(2702-02) and blue-green(2703-01) were used as phosphor. The insulator was BaTiO$_3$ and $Y_2$O$_3$, back electrode was silver paste. To investigate electrical and optical properties of PELDs, EL spectrum, Brightness, Transferred charge density using Sawyer-Tower\`s circuit was measured.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
• /
• pp.497-500
• /
• 2001

Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e.g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current. 缀Ѐ㘰〻ሀ䝥湥牡氠瑥捨湯汯杹

• 대한화학회지
• /
• 제27권3호
• /
• pp.194-200
• /
• 1983

${\alpha}-Fe_2O_3$의 HCl 또는 $H_2SO_4$에 의한 용해반응에 있어서 금속염의 첨가효과를 분광광도법과 중량법으로 검토하였다. 환원성 금속염은 현저한 반응촉진 효과를 보이나 비환원성 금속염은 부의 효과를 나타내었다. $FeCl_2$와 같은 환원성 금속염을 첨가한 경우에 ${\alpha}-Fe_2O_3$의 용해속도가 크게 촉진되는 것은 $Fe^{3+}$ 와 $Fe^{2+}$ 사이에 chloro-brige가 형성되어 전하이동이 일어나면서 ${\alpha}-Fe_2O_3$ 표면의 격자에너지를 감소시키기 때문인 것으로 추측된다. 이 전하이동으로 인한 ${\alpha}-Fe_2O_3$ 표면의 격자 에너지 변화가 반응의 활성화에너지 변화와 대응된다고 보면 약 0.36e의 부분전하가 $Fe^{3+}$ 쪽으로 옮겨간 것으로 계산되었다.

• 한국광학회지
• /
• 제17권3호
• /
• pp.262-267
• /
• 2006

효율적인 PPLN 제작을 위하여 DC 전계를 인가하면서 $LiNbO_3$에 인가되는 전압 및 전류를 실시간으로 측정할 수 있는 실험 장치를 제안하였다. 제안된 실험 장치를 사용함으로써 PPLN의 분극반전에 필요한 충분한 전하량을 공급하기 위한 전계인가시간을 수초 단위로 증가시킬 수 있어 $LiNbO_3$에 주입되는 전하량의 조절을 용이하게 할 수 있었다. 또한 PPLN의 분극반전 과정을 단계별로 분류하고 각 단계별 실험결과를 바탕으로 분석함으로써 최적의 PPLN 제작조건을 구할 수 있었다.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2015년도 전력전자학술대회 논문집
• /
• pp.401-402
• /
• 2015

In this paper a direct cell-to-cell charge balancing circuit which can transfer the charge from any cell to any cell in the battery string is introduced. In the proposed topology the energy in the high voltage cell is transferred to the low voltage cell through the simple operation of a dc-dc converter to get fast equalization. Furthermore, the charge equalization can be performed regardless of the battery module operation whether it is being charged, discharged or relaxed. The monitoring circuit composed of a DSP and a battery monitoring IC is designed to monitor the cell voltage and protect the battery. In order to demonstrate the advantages of the proposed topology, a prototype circuit was designed and applied to 12 Lithium-Ion battery module. It has been verified with the experiments that the charge equalization time of the proposed method was shortest compared with those of other methods.

• Journal of Power Electronics
• /
• 제16권4호
• /
• pp.1277-1287
• /
• 2016

This study proposes a novel isolated high step-up galvanic converter, which is suitable for renewable energy applications and integrates a boost converter, a coupled inductor, a charge pump capacitor cell, and an LC snubber. The proposed converter comprises an input inductor and thus features a continuous input current, which extends the life of the renewable energy chip. Furthermore, the proposed converter can achieve a high voltage gain without an extremely large duty cycle and turn ratio of the coupled inductor by using the charge pump capacitor cell. The leakage inductance energy can be recycled to the output capacitor of the boost converter via the LC snubber and then transferred to the output load. As a result, the voltage spike can be suppressed to a low voltage level. Finally, the basic operating principles and experimental results are provided to verify the effectiveness of the proposed converter.

• 한국안전학회지
• /
• 제18권3호
• /
• pp.54-59
• /
• 2003

The discharge energy by electrostatic discharge of the charged human body is calculated under the assumption that the stored charge is dissipated completely. However, it is well-known that the charge is slightly remained after electrostatic discharge. Therefore, The Rompe-Weisel model of the discharge analysis, which has somewhat more of a physical justification than the conventional energy equation, is proposed. It is proposed that the electrical conductivity of the arc should be proportional to the energy density transferred to it by Ohmic dissipation. For the electrostatic discharge energy analysis, the Rompe-Weisel model was compared by quasi static analysis. As a consequence, a study on a reliable energy evaluation based on simulation models during electrostatic discharge is carried out in this paper and is adopted to estimate the explosion hazards of flammable gases.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2016년도 추계학술대회 논문집
• /
• pp.33-34
• /
• 2016

This paper presents a load sharing method based on the low bandwidth communication (LBC) applied to a DC microgrid in order to balance the state of charge (SOC) of the battery units connected in parallel to the common bus. In this method, SOC of each battery unit is transferred to each other through LBC to calculate average SOC value. After that, droop coefficients of battery units are adjusted according to the difference between SOC of each unit and average SOC value of all batteries in the system. The proposed method can effectively balance the SOC of battery units in charging and discharging duration with a simple low bandwidth communication system.