• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1269-1276
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• 1999

Metallocenes, whether using a cocatalyst or not, act as catalysts in ethylene polymerization. The positive charge on the transition metal of a metallocene might have an important role in polymerization as an active site in our model approach. Using semiempirical calculations in the absence of cocatalyst, we show one of the possibilities that the positive charge on a metallocene might be more easily transferred through the Cp ring of a ligand to the ethylene than to transfer directly from the transition metal to the ethylene. In these calculations, the charge on titanium in an eight C2H4 system is transferred and a polymer chain is produced. This reaction takes place only when ethylenes are arranged in a particular direction with respect to the ring, but does not take place for ethylenes near Ti or Cl atoms. The same mechanism is shown for a metallocene ligand which is sterically hindered or where the Cp ring is replaced by fluorenyl. These results suggest an entirely new polymerization mechanism in the absence of a cocatalyst in which the Cp ring is the active site.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.497-500
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• 2001

Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e,g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.286-290
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• 1999

Electroluminescence is occurred when phosphor is located in electric field. In this paper, we made powder electroluminescent device (PELD) with structured ITO film/Phosphor/Insulator/Silver paste. The transparent electrode was ITO film and green(2704-01), orange(2702-02) and blue-green(2703-01) were used as phosphor. The insulator was BaTiO$_3$ and $Y_2$O$_3$, back electrode was silver paste. To investigate electrical and optical properties of PELDs, EL spectrum, Brightness, Transferred charge density using Sawyer-Tower\`s circuit was measured.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.497-500
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• 2001

Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e.g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current. 缀Ѐ㘰〻ሀ䝥湥牡氠瑥捨湯汯杹

• Journal of the Korean Chemical Society
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• v.27 no.3
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• pp.194-200
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• 1983

Effect of metallic salts added to the ${\alpha}-Fe_2O_3-HCl\;or\;{\alpha}-Fe_2O_3-H_2SO_4$ reaction systems were investigated by colorimetric and gravimetric determinations. While reductive salts exhibited remarkably enhanced reaction rate, non-reductive salts showed inhibitive results. We supposed that the improvement of dissolution rate of ${\alpha}-Fe_2O_3$ by the addition of $FeCl_2$, a reductive salt, to the ${\alpha}-Fe_2O_3-HCl$ system can be attributed to the formation of chloro-bridge between $Fe^{3+}\;and\; Fe^{2+}$, and therefore some partial electronic charge transfer from $Fe^{2+}\;to\;Fe^{3+}$ on the surface of ${\alpha}-Fe_2O_3$ will be easily achieved through the bridged bond. The transferred charge to the surface will reduce the positive charge of initial $Fe^{3+}$, and also result to reduce the lattice energy of that site. Assuming tothat there is a linear relationship between the lattice energy change and the change of activation energy of the reaction system, the transferred partial electronic charge to $Fe^{3+}$ of ${\alpha}-Fe_2O_3$ surface was calculated to be ca. 0.36e.

• Korean Journal of Optics and Photonics
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• v.17 no.3
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• pp.262-267
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• 2006

We proposed a PPLN fabrication setup that measures the voltage and current applied to $LiNbO_3$ in real time during application of a DC electric field. Because the duration for transferring a sufficient electron charge to $LiNbO_3$ increases, we are able to control the electron charge flow transferred to $LiNbO_3$ efficiently. We divided the domain inversion process of PPLN into 5 states: Nucleation (state 1), Spread of the domain inversion region under the electrode(state 2), Accumulation of the electron charge at the insulator/$LiNbO_3$ interface(state 3), Domain inversion under the insulator layer after breakdown(state 4), and Lowering the electric field applied to $LiNbO_3$ (state 5). We have found that the Threshold Point is essential for the domain inversion and that the domain inversion process must be stopped within state 3 for the optimum PPLN. Using these results, we could fabricate a stable and reproducible PPLN efficiently.

• Proceedings of the KIPE Conference
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• 2015.07a
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• pp.401-402
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• 2015

In this paper a direct cell-to-cell charge balancing circuit which can transfer the charge from any cell to any cell in the battery string is introduced. In the proposed topology the energy in the high voltage cell is transferred to the low voltage cell through the simple operation of a dc-dc converter to get fast equalization. Furthermore, the charge equalization can be performed regardless of the battery module operation whether it is being charged, discharged or relaxed. The monitoring circuit composed of a DSP and a battery monitoring IC is designed to monitor the cell voltage and protect the battery. In order to demonstrate the advantages of the proposed topology, a prototype circuit was designed and applied to 12 Lithium-Ion battery module. It has been verified with the experiments that the charge equalization time of the proposed method was shortest compared with those of other methods.

• Journal of Power Electronics
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• v.16 no.4
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• pp.1277-1287
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• 2016

This study proposes a novel isolated high step-up galvanic converter, which is suitable for renewable energy applications and integrates a boost converter, a coupled inductor, a charge pump capacitor cell, and an LC snubber. The proposed converter comprises an input inductor and thus features a continuous input current, which extends the life of the renewable energy chip. Furthermore, the proposed converter can achieve a high voltage gain without an extremely large duty cycle and turn ratio of the coupled inductor by using the charge pump capacitor cell. The leakage inductance energy can be recycled to the output capacitor of the boost converter via the LC snubber and then transferred to the output load. As a result, the voltage spike can be suppressed to a low voltage level. Finally, the basic operating principles and experimental results are provided to verify the effectiveness of the proposed converter.

• Journal of the Korean Society of Safety
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• v.18 no.3
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• pp.54-59
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• 2003

The discharge energy by electrostatic discharge of the charged human body is calculated under the assumption that the stored charge is dissipated completely. However, it is well-known that the charge is slightly remained after electrostatic discharge. Therefore, The Rompe-Weisel model of the discharge analysis, which has somewhat more of a physical justification than the conventional energy equation, is proposed. It is proposed that the electrical conductivity of the arc should be proportional to the energy density transferred to it by Ohmic dissipation. For the electrostatic discharge energy analysis, the Rompe-Weisel model was compared by quasi static analysis. As a consequence, a study on a reliable energy evaluation based on simulation models during electrostatic discharge is carried out in this paper and is adopted to estimate the explosion hazards of flammable gases.

• Proceedings of the KIPE Conference
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• 2016.11a
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• pp.33-34
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• 2016

This paper presents a load sharing method based on the low bandwidth communication (LBC) applied to a DC microgrid in order to balance the state of charge (SOC) of the battery units connected in parallel to the common bus. In this method, SOC of each battery unit is transferred to each other through LBC to calculate average SOC value. After that, droop coefficients of battery units are adjusted according to the difference between SOC of each unit and average SOC value of all batteries in the system. The proposed method can effectively balance the SOC of battery units in charging and discharging duration with a simple low bandwidth communication system.