• Asian Pacific Journal of Cancer Prevention
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• 제13권9호
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• pp.4249-4253
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• 2012

While associations between trace elements and heavy metals with prostate cancer are still debatable, they have been considered as risk factors for prostate cancer. Thus, this study aimed to detect any links between selected minerals and heavy metals including Se, Zn, Cu, Mn and Fe with prostate cancer. A case control study was carried out among 100 subjects (case n=50, control n=50), matched for age and ethnicity. Trace elements and heavy metals level in hair and nail samples were determined by ICP-MS. Mean selenium levels in hair and nail of the cases were significantly lower as compared to controls. A similar trend was noted for zinc in both hair and nail samples, whereas the mean level of copper was significantly higher in cases than controls. Similar elevation was noted for iron and manganese (p<0.05 for all parameters). Low levels of selenium and zinc and high levels of copper, iron and manganese appear to be associated with the risk of prostate cancer. Further studies to elucidate the causal mechanisms and appropriate chemopreventive measures are needed.

• 동굴
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• 제92호
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• pp.9-18
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• 2009

A number of closed metal mines act as point sources of contamination on nearby streams, soils and plants in our country. The contamination of twelve decomposed samples had earned from nine closed metal mines had been evaluated by TEA-3000. The contents of heavy metal with ion fraction exchange and carbonate fraction forms had been showed that the speciation of heavy metals represented with easy solubility, mobility and bioavailable of plants, and in case of sulfide compounds and organic residuals forms are related with the speciation of metals which may be stable forms because of strong bindable capacity. Also heavy metals elements in mosts of mines got with relative stable within crystal lattice, but results of trace element analyser showed that, in the most of tailings from mine areas, large portions of concentration of heavy metals were explained as stable from, sulfides/ organics and residual. In tailing from Imchun mines, the concentrations extracted by water were relatively high as compared with other mine areas whose total concentrations were very high because of large quantities of exchangeable ions and carbonates and low soil pH. Danger Index (D.I.) suggested in this study was based on the cumulative concentrations of step 1 and 2 from the result of trace element analyser. When the soil pH was considered, this index became better indicator to determine the priority for the remediation of mine area.

• 한국환경보건학회지
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• 제22권2호
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• pp.69-82
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• 1996

The samples for testing have been collected from Kangdong-myon, Nongso-myon, Beomseo-my on, and Cheongryang-myon in Ulju-Ku, Ulsan-city from July 1994 to March 1995 in order to grasp status of trace metals contained in some rice, soybean and soils, and to provide references in establishing their standard 96 collected samples(48 for cereals and 48 for soils) have been tested to measure levels of Hg, Pb, Cd, Cu, and Zn through methods of trace metal containing analysis and heavy metal analysis. moisture content was also analyzed. And at the same time 0.1N-HCl soluble heavy metal content of soil was measured. The average Hg containing level of samples is 0.006 ppm for cereal and 0.062 ppm for soil, Pb is 0.302 ppm for cereal and 1.137 ppm for soil, Cd is 0.012 ppm for cereal and 0.027 ppm for soil, Cu is 2.01 ppm for cereal and 0.885 ppm for soil, and Zn is 7.853 ppm for cereal and 2.366 ppm for soil.

• 한국식품과학회지
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• 제10권3호
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• pp.299-305
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• 1978

$1976{\sim}1977$년의 2년간 서부경남 일원에서 생산된 미곡을 도정도, 지역및 품종별로 중금속 함량을 분석한 결과는 다음과 같았다. 1. 중금속의 함량은 조곡, 현미, 7분도미, 9분도미 순으로 도정도가 커짐에 따라 그 양이 적었으며 각지역과 벼의 품종에는 큰 차이가 없었다. 2. 미곡중의 중금속 함량은 구리 $0.80{\sim}2.89{\;}ppm,$ 아연 $3.23{\sim}17.60ppm$, 망간 $6.72{\sim}70.25ppm$, 그리고 납은 0.64ppm 이하였다. 3. 조곡에서 니켈과 크롬의 함량은 각각 $2.04{\sim}60.64ppm,\;5.09{\sim}39.95\;ppm$범위이었으며 7분도미와 9분도미에서는 아주 미량이 검출되었다. 4. 수은과 카드뮴은 몇 종의 조곡에서 미량이 검출되었을 뿐 7분도미와 9분도미에서는 추적되지 않았다.

• 한국동물위생학회지
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• 제22권1호
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• pp.1-7
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• 1999

This study was performed to investigate the contents of the heavy metals such as cadmium(Cd), copper(Cu), iron(Fe), lead(Pb) and zinc(Zn) in meat and meat products. For this experiment, each 20 samples of beef and pork were collected at slaughterhouse in Seoul areas and 45 samples of meat products(ham, sausage, processed meat and seasoned meat) were purchased from commercial food markets. The contents of the heavy metals was determined by atomic absorption spectrophotometry from Jan. to Nov. In 1998. The results obtained were summarized as follows ; 1. In Korean native beef, mean values of the heavy metals(mg/kg) were Pb : 0.14$\pm$0.10, Cd : 0.07$\pm$0.02, Cu : 1.73$\pm$0.95, Zn : 42.82$\pm$8.17 and Fe : 67.43$\pm$24.18, respectively. 2. In imported beef, mean values of the heavy metals(mg/kg) were Pb : 0.03$\pm$0.08, Cd : 0.06$\pm$0.02, Cu : 1.41$\pm$0.62, Zn : 42.93$\pm$4.95 and Fe : 40.06$\pm$12.77, respectively. 3. In pork, mean values of the heavy metals(mg/kg) were Pb : not detected, Cd : 0.09$\pm$0.02, Cu : 1.08$\pm$0.23, Zn : 19.49$\pm$6.02 and Fe : 30.21$\pm$10.51, respectively. 4. In ham, mean values of the heavy metals(mg/kg) were Pb : trace, Cd : trace, Cu . 1.19$\pm$0.46, Zn : 13.58$\pm$4.99 and Fe : 31.43$\pm$11.74, respectively. 5. In sausage, mean values of the heavy metals(mg/kg) were Pb : 0.15$\pm$0.34, Cd : 0.08$\pm$0.05, Cu : 1.15$\pm$0.46, Zn : 13.70$\pm$7.13 and Fe . 27.28$\pm$15.05, respectively. 6. In processed meat, mean values of the heavy metals(mg/kg) were Pb : 0.08$\pm$0.13, Cd : 0.09$\pm$0.04, Cu : 1.28$\pm$0.60, Zn : 14.72$\pm$7.09 and Fe : 24.04$\pm$10.33, respectively. 7 In seasoned meat, mean values of the heavy metals(mg/kg) were Pb : 1.05$\pm$2.21, Cd : 0.13$\pm$0.03, Cu : 1.06$\pm$0.16, Zn : 17.53$\pm$8.72 and Fe : 26.76$\pm$9.02, respectively.

• 한국식품조리과학회지
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• 제9권3호
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• pp.195-197
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• 1993

This study investigated the contamination of trace metals on edible visceras : tongue, intestine, lung, testis, gira, blood, liver, stomach, and kidney. The edible visceras were selected at random from ten markets in Seoul. The edible visceras underwent freeze drying prior to analysis. The contents of arsenic, cadmium, cobalt, chromium, copper, magnases, molybdenum, lead, and zinc were detected by ICP(Inductively Coupled Plasma Spectrophotometry). The results showed that the levels of trace metals in all the samples fall within the tolerance limit and cadmium in lung tended to be high(>0.1 ppm). Therefore, we may study and investigate continuously on the food contamination of heavy metals for the public health.

• Nutritional Sciences
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• 제2권2호
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• pp.88-92
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• 1999

The purpose of this study was to study the intake of heavy metals such af arsenic, lead and cobalt and the relationship of dietary heavy metals with serum iron, topper, and zinc, which play important roles in hematopoiesis, in healthy college women living in Choongnam Korea, where we have detected heavy metals (As, Pb, Co) in some marine products in previous studies. The nutritional status of the subjects (35 women) was evaluated by anthropometric measurements, 24-hr dietary recall for 3 days. And 3-day diets (by weighing method) and blood were collected to analyze As, Pb, Co, Fe, Cu, Zn, Hb, Hct, and MCHC. The mean age, height, weight, and BMI were 20 years, 158 cm, 55 kg and 22.42 kg/$m^2$, respectively. The mean daily energy intake was 85.85% of RDA for Koreans. The ratio of energy from carbohydrate, protein, and fat was 60 : 24 : 16. The mean daily intake of heavy metals (As, Pb, Co) was 1.77 mg/day, 75.21 $\mu$g/day and 21.12 $\mu$g/day. And the mean daily intake of iron, copper, and Zinc concentrations were 97, 68, and 92% of normal values. The mean serum heavy metals (As, Pb, Co) were 16.14 $\mu$g/dl, 4.32 $\mu\textrm{g}$/dl and 0.02 $\mu$g/dr, respectively Mean blood levels of Fe, Cu, Zn, Hb, Hct, and MCHC were at normal levels. Dietary heavy metals except Co were not significantly different from serum Fe, Cu, Zn and Hb, Hct, and MCHC. However, there was a tendency toward lower serum concentration of Fe, Hb, Hct, and MCHC in the subjects with higher heavy metals (As) intake. Among heavy metals, only dietary Co showed a significant negative correlation with Hb (p< 0.001) and Hct (p < 0.001).

• 한국식품과학회지
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• 제32권4호
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• pp.970-973
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• 2000

전남 도내 5개 지역과 광주시 근교 1개 지역에서 재배되고 있는 미나리의 안전성 평가를 위해 중금속 함유량과 기생충 감염 여부를 조사하였다. 그 결과 비교적 독성을 지니고 있는 중금속인 수은과 비소는 각각 흔적 수준과 극히 미량인 $0.003{\sim}0.01\;ppm$으로 나타났다. 납은 모든 지역에서 검출되지 않았으며, 카드뮴은 $0.013{\sim}0.036\;ppm$ 범위를 보였으며, 또한 농작물 생장에 필수원소로 작용하는 구리, 망간과 아연의 함유량은 $0.285{\sim}0.627\;ppm,\;1.337{\sim}12.884\;ppm,\;2.105{\sim}4.221\;ppm$이 검출되었다. 또한 미나리에서 흡충류인 간질과 간흡충, 수인성원 충류인 람블 편모충과 크립토스포리듐속 그리고 선충류인 회충과 십이지장충 6종에 대한 기생충 검사 결과 모두 검출되지 않았다.

• 한국입자에어로졸학회지
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• 제8권2호
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• pp.47-54
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• 2012

Paved road dust emissions were investigated 14 times on 12 main roads in Seo-Cho Gu, Seoul, Korea by vehicle-based mobile sampling system(Road Dust Monitoring System) during September to December 2011. Also, fourteen heavy metals present in the dust samples were analyzed by ICP. ICP analysis showed that one of major source of the road dust would be urban construction. A large amount of silt was found, which might be originated mainly from building construction and open beds of trees. Trace element and pollution indices of heavy metals(Cd, Cu, Ni, Pb, Zn) on the roads adjacent to the commercial area had higher concentrations than those on the roads adjacent to the construction and residential areas because of traffic density and heavy traffic.

• 분석과학
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• 제32권6호
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• pp.233-242
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• 2019

Substance identification is the first step of the REACH registration. It is essential in terms of Classification, Labelling and Packaging (CLP) regulation and because even trace amounts of impurities or additives can affect the classification. In this study, a scheme for the screening, quantification, and interpretation of trace amounts of hazardous inorganic substances is proposed to detect the presence of more than 0.1% hazardous inorganic substances that have been affecting the hazard classification. An exemplary list of hazardous inorganic substances was created from the substances of very high concern (SVHCs) in REACH. Among 201 SVHCs, there were 67 inorganic SVHCs containing at least one or ~2-3 heavy metals, such as As, Cd, Co, Cr, Pb, Sb, and Sn, in their molecular formula. The inorganic SVHCs are listed in excel format with a search function for these heavy metals so that the hazardous inorganic substances, including each heavy metal and the calculated ratio of its atomic weight to molecular weight of the hazardous inorganic substance containing it, can be searched. The case study was conducted to confirm the validity of the established scheme with zinc oxide (ZnO). In a substance that is made of ZnO, Pb was screened by XRF analysis and measured to be 0.04% (w/w) by ICP-OES analysis. After referring to the list, the presence of Pb was interpreted just as an impurity, but not as an impurity relevant for the classification. Future studies are needed to expand on this exemplary list of hazardous inorganic substances using proper regulatory data sources.