• Title/Summary/Keyword: Trace component

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The Provenance and Characteristic Classification of the White Porcelain in the Gyeongsangnam-do by Neutron Activation Analysis (중성자방사화분석을 활용한 경상남도 백자의 산지 및 특성 분류)

  • Kim, Na-Young;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.21
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    • pp.89-100
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    • 2007
  • This study analyze concentration of minor and trace elements on 47 white porcelains excavated from Dudong-ri, Baekryeon-ri, Sachon-ri kilns in Gyeonsangnam-do by NAA(neutron activation analysis) and try to classify the provenance and characteristics according to the analytical result. Each kilns are divided into the group by PCA(principal component analysis) and LDA(linear discrimination analysis) using 17 elements; Ba Ce, Co, Cr, Cs, Dy, Eu, Hf, La Lu, Rb, Sc, Sm, Ta, Th, V, Yb. The contribution elements are Dy, Sm, La, Ce, Lu, Sc. And soft and hard white porcelains are similar with the chemical composition of the use materials therefore the difference of the chemical composition not confirmed a cause. The analytical results of the fine(I) and poor(II) quality white porcelains presume the difference of the povenance of clay materials or the poduction process such as difference purify and additive materials.

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Studies on the Antioxidative Substances in the Seeds of the Rutaceae Family (운향과(芸香科) 식물(植物) 종실(種實)의 항성화성(抗醒化性))

  • Kim, Seong-Jin;Kim, Ji-Soo;Joh, Yong-Goe
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.7-16
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    • 1994
  • Some seeds of the Rutaceae family, Zanthoxylum piperitum, Z. schinifolium officinalis, Poncirus trifoliata, Citrus unshin, were investigated to clarify their antioxidative components. Finely powdered samples were extracted by hexane, followed by dichioromethane and then 70% methanol in a hot bath. Its unsaponifiables containing X-and Y-tocopherol with trace amount of ${\beta}-and$\;{\delta}-tocopherol$. also showed comparatively weak activity, although the hexane fraction itself had no significant antioxidative effect on lard. Levels of total tocopherols in the samples averages 42. 24-154. 11 mg/lOOg total extractives. The dichloromethane-and 70% methanol extractives showed strong antioxidative activity, from which antioxidative substances were purified with benzene-acetone(6:5, V/V) on a silica gel column, and with a solvent mixture of acetonitrile-methanol-$H_2O$(40:40:20, V/V/V) on a Sep-Pak $C_{18}$ hydrolyzed by 5% KOH-ethanol. The recovered unsaponifiables were, then, separated on a column of high performance liquid chromatography. The unsaponifiables produced by hydrolysis of the isolates from dichloromethane extractives has epi-catechin(40.0-57.1%) and (+)-catechin<$l9.1{\sim}24.4%$ to total phenolic substances, on area base) as major component, accompanied by chlorogenic acid, gallic acid(?), trans-p-coumaric acid and tralls-p-ferulic acid including some unknown components, and those derived from 70% methanol extractives also comprise (+)-catechin($31.3{\sim}39.6%$ to total components, on area base), epi-catechin($2O.2{\sim}36.4%$), trans-p-cournaric acid(8.4-15.3%) and trans-p-ferulic acid($7.7{\sim}14.1%$) as predominant component with some minor coponents, but the fraction supposed to be gallic acid(?) is not present. The antioxidative activities of the phenolic components isolated in this work were in order of epi-catechin>catechin>chlorogenic acid>trans-p-ferluic acid>trans-p-coumaric acid.

Chemical characteristics of ions and trace metallic element of PM2.5 in Busan metropolitan area (부산지역 $PM_{2.5}$의 이온 및 미량 금속성분의 화학적 특성)

  • 전보경;서정민;최금찬
    • Journal of Environmental Health Sciences
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    • v.27 no.4
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    • pp.63-71
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    • 2001
  • PM 2.5/ samples were measured at two sites, Hadan(suburban site) and Anrak (roadside site) in Busan area. PM 2.5/ sampling was performed for 24-hour intervals by the FH9.5 particulate sampler. Aerosol samples were collected on PTFE filter. A total of 60 particulate samples were collected, dad samples were measured for Particulate mass concentration, metallic elements (Cr, Mn, Ni. Cu. Se, Fe, Pb, and Zn) and waer-soluble elements (C $l^{[-10]}$ , N $O_{3}$$^{[-10]}$ ,S $O_{4}$$^{2-}$, N $H_{4}$$^{+}$, $Ca_{2}$$^{+}$, $Mg_{2}$$^{+}$ and $^{+}$.Mass concentration in Hadan ranged 24.23~57.12 $\mu\textrm{g}$/㎥ and 60.22~72.12 $\mu\textrm{g}$/㎥m Yellow Sand Events. Major cations in Hadan and Anrak site is N $H_{4}$$^{+}$and N $a^{+}$ respectively. SO42$^{[-10]}$ was the abundant specie in the PM 2.5 fraction for Hadan site an dAnrak site. Hadan site showed igher concentration in S $O_{4}$$^{2.1}$ and N $H_{4}$ $^{+}$ In Anrak site the concentration of S $O_{4}$/sip 2-/and N $a^{+}$ was higher than other ions Prominent metallic elements were Fe and Pb in two sites. Principal component analysis showed that main source of PM 2.5 aerosol particles was non-metal related source which was resulted in relating elements as Cr, Ni, and Pb at Hadan site, Anrak site also has resulted PM2.5 aerosol paricles source, which was related its element like Zn, and Ni,. The SAS package analysis also showed that long-range transport effect at Hadan area due to Yellow Sand Event by the prevailing weaterlies.ling weaterlies.

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Study on quantitative & trace element analysis of metal objects (고대 청동기의 성분조성 및 산지추정 연구)

  • Chung, Kwang-Yong;Kang, Hyung-tae;Chong, Dong-Chan;Yun, Yong-hyun;Lee, Hoon
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.137-153
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    • 2004
  • We have analyzed the ingredients of 17 pieces of Bronze Age bronze ware, and an additional 22 pieces of Koryo and Chosun dynasty bronze ware. We have also conducted analysis of the extraction sites where these bronze ware items were found. For analyzing the main ingredient the bronze ware items have been divided into 3 groups - Cu-Sn(70?75:20), Cu-Pb-Sn(70:10:10), Cu-Pb-Sn(60:10:20) type respectively. In tile cases of the Cu-Pb-Sn groups the division comes down to differences in the Cu content as the main component, and elements such as Ni, Fe, Co contribute as a micro ingredient. The geographical and periodic characteristics of ancient bronze ware items show that theircompositional element changes from Cu:Sn to Cu:Pb:Sn and the Cu content decreases with the period,while the Pb content increases with the period. Bronze ware items from Suchon Ri, Gongju (that were used in 3 B.C.) form very different categories from 3rd ${\~}$ 2nd B.C.. They additionally formed very different categories from those bronze ware items analyzed in this research. These bronze ware itemsare shown to be geographically close and periodically overlapped, but made of a new elemental composition. This shows an inflow of a production technical culture present in the new bronze wares. The main component content of Cu is lower, and the Co and Fe contents (as microelements) are much higher than that of other bronze ware items. Such facts showthat those bronze ware items used completely different materials from bronze ware items in other cultural areas, or that there were differences in smelting techniques In the places where ancient bronze ware items have been extracted, it is presumed that the materials originated from the southern parts of Korea andnorthern parts and southern parts of China. .As more bronze ware scientific research is compiled one can conclude that that there will be enough scientific evidence to study the Bronze Age culture of Koreasystematically.

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Removal of Chlorinated Organic Compounds Using Crosslinked PDMS Pervaporation Membrane (가교된 PDMS 투과증발 막을 이용한 유기 염소계 화합물의 제거)

  • Kim, Yong Woon;Hong, Yeon Ki;Hong, Won Hi
    • Clean Technology
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    • v.7 no.3
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    • pp.195-202
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    • 2001
  • In this study the trace of chlorinated organic compound in aqueous solution was separated by pervaporation process using crosslinked PDMS (polydimethylsiloxane) membrane. The flux of trichloroethylene(TCE) increased linearly with feed composition but the flux of water was slightly increased. The partial flux of TCE was greater than that of tetrachloroethylene(PCE). The partial flux of TCE was not changed with operating temperature, but increased rapidly with feed flow rates. High crosslinking density causes the reduction of solubility and diffusivity for target component. The reduction of flux and selectivity for TCE is due to the chain immobilization and reduction of diffusivity with crosslinking density.

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Study on the alternatives to trace the origin and to diminish the sediments of drinking water (수돗물의 앙금발생규명 및 저감기술방안)

  • 김갑수;임병진;권은미
    • Journal of environmental and Sanitary engineering
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    • v.9 no.1
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    • pp.17-28
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    • 1994
  • There are many possibilities that may lead to low quality of drinking water Recently, some unknown deposits in tap water raised a lot of public concern regarding the safety of drinking water in Seoul. We analyzed the quality of tap water from several areas of Seoul, including the area where public complaints about tap water were high. The results shows that the quality of tap water in Seoul was good, well below the environmental standards. Only the tap water from the area with high public complaints showed turbidity higher than that of other area. Also, result shows that component of deposit in tap water was Al, Fe, Mn, and Zn. Based on the research result we propose several measures that might help to reduce the amount of deposit in tap water as follows : 1 Using coagulant aid when coagulating or adjusting pH when filtering. 2. Replacing old water pipeline with new corrosive- resistant one. 3. Increasing water treatment efficiency by enhancing water treatment system such as automation of water treatment system adjusting production capacity, and improving operational condition of filler basin. 4. Chlorine disinfection at the distribution reservoir would help maintaining the same pH level and chlorine concentration throughout the water pipeline and reduce corrosion of pipe.

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Effect of culture pH and media composition on the ratio of tcicoplanin $A_1$ and $A_2$ biosynthesis

  • Kim, Yun-Jeong;Song, Yun-Seok;No, Yong-Taek
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.325-328
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    • 2001
  • Teicoplanin is a glycopeptide antibiotic produced by Actinoplanes teichomyceticus novo sp. A TCC 31121. It is active against Gram-positive bacteria and it is under evaluation for use in man. Teicoplanin mixture in fermentation broth contains major amounts of teicoplanin $A_1$ and $A_2$ and a minor amount tcicoplanin of $A_3$. Commercial teicoplanin product is composed of five major components of very similar polarity, designated T-$A_2$-l, 2, 3, 4 and 5, and the more polor component, designated T -$A_3$. The culture conditions were studied in order that hydrophilic teicoplanin $A_2$ components are more produced but hydrophobic teicoplanin $A_1$ with lower bioactivity are less produced in submerged culture. Effects of culture pH and nutrients on the biosynthes ratio of teicoplanin $A_1$ and $A_2$ were confirmed in flask culture using MOPS buffer system through TLC, bioautography and bioassay. It was elucidated that optimal pH is 7.4 for teicoplanin $A_2$ biosynthesis but is 5.2 for teicoplanin $A_1$ biosynthesis, and that trace elements stimulate $A_2$ production but malt extract stimulate $A_1$production.

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Component Analysis and Determination of Bioactivity of Oriental Therapeutic Drug for Hepatitis B (간염 치료제인 민간제제의 성분 분석 및 생리 활성 검색)

  • 김승호;이종우;이현선;함경수
    • Microbiology and Biotechnology Letters
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    • v.20 no.6
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    • pp.699-703
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    • 1992
  • An oriental drug, named NP-S, traditionally used as a therapeutic agent for hepatitis B was characterized by separating into volatile and non-volatile fractions. The volatile fraction contained ammonia as determined by ammonia kit and eight peaks when it was analyzed by gas chromatography that are not identified yet. The elemental analysis showed that the non-volatile fraction contained 15.5% carbon, 4.8% hydrogen, 11% nitrogen, and 10% sulfur along with a few trace elements such as Cl, Si, Mg and Zn. NP-S contained 6.7% peptide, 0.3% free amino acids such as Lys, Pro, Arg, lie, Tyr, Phe, His, Thr and Ser and 0.1% inorganic phosphate. The drug showed antimicrobial activity against Salmonella typhimurium, StaPhylococcus aureus and Candida albieans and also had antioxidant activity when thiobarbituric acid reacting substances(TBARS) method was applied.

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Polysaccharide Characteristics from Hot Water Extract of Aloe saponaria Callus (Aloe saponaria 캘러스의 열수 추출물 유래 다당의 특성)

  • Baek, Jin-Hong;Kim, Myung-Uk;Kang, Tae-Su;Hur, Won;Lee, Shin-Young
    • KSBB Journal
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    • v.24 no.1
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    • pp.59-64
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    • 2009
  • The callus formation from inferior leaf of Aloe saponaria was induced in M & S medium supplemented with 10-30 ${\mu}M$ NAA (${\alpha}$-naphthalene acetic acid) and 3-7 ${\mu}M$ kinetin under incubation in the dark at $25^{\circ}C$ for 6 weeks. The hot water extract ($100^{\circ}C$, 24 hrs) from cultured callus was obtained and the components analysis for the extract were examined to determine the callus can synthesized the bioactive component such as Aloe polysaccharide. The freeze dried extract contained the sugar of 53.2%, protein of 7.3%, ash of 18.5% and water of 21% (w/w). Two fractions (Fr-I and Fr-II) were obtained by Sepharose CL-4B gel permeation chromatography and Fr-I, major fraction was further purified with dialysis. From sugar analysis by TLC and GC, the purified Fr-I fraction consisted of glucose (77.6%), galactose (17.7%), mannose (4.7%, w/w) and uronic acid (trace). The molecular weight of purified Fr-I fraction determined by GPC was about 110 kDa.

The Simulation of Hybrid Electric Vehicle - ADVISOR(Advanced Vehicle Simulator) (하이브리드 전기자동차 시뮬레이션 - ADVISOR)

  • Nam Jong-Ha;Choi Jin-Hong;Baek Jong-Yeop;Jang Dae-Kyoung;Hwang Ho-Seok
    • Proceedings of the KIPE Conference
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    • 2006.06a
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    • pp.225-227
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    • 2006
  • The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) first developed ADVISOR in 1994. Between 1998 and 2003 it was downloaded by more than 7,000 individuals, corporations, and universities world-wide. In early 2003 NREL initiated the commercialisation of ADVISOR through a public solicitation. AVL responded and was awarded the exclusive rights to license and distribute ADVISOR world-wide. AVL is committed to continuously enhance ADVISOR's capabilities. Provides rapid analysis of the performance and fuel economy of conventional and advanced, light and heavy-duty vehicle models as well as hybrid electric and fuel cell vehicle models. ADVISOR Simulates the Following Vehicle Characteristics. - Optimal drivetrain component sizes that provide the best fuel economy Vehicle's ablility to follow the speed trace - Amount of fuel and/or electric energy required by various vehicle concepts - Peak power and efficiency achieved by the drivetrain components - Torque and speed distribution of the engine - Average efficiency of the transmission - Gradeability of vehicles at various velocities

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