• Title/Summary/Keyword: Toxic gases

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Risk Analysis of Ammonia Leak in the Refrigeration Manufacturing Facilities (냉동제조 시설의 암모니아 누출사고 위험 분석)

  • Kang, Su-Jin;Lee, Ik-Mo;Moon, Jin-Young;Chon, Young-Woo
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.43-51
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    • 2017
  • Recently, ammonia leak occurred frequently in the domestic refrigeration manufacturing facilities. Ammonia caused great damage to the environment and human health in the event of an accident as combustible gases and toxic gases. After considering the types of ammonia accidents of domestic refrigeration manufacturing facilities and selected accident scenarios and to analyze the risk analysis through Impact range estimates and frequency analysis and there was a need to establish measures to minimize accident damage. In this study, depending on the method of analysis quantitative risk assessment we analyzed the risk of the receiver tank of ammonia system. Scenario analysis conditions were set according to the 'Technical guidelines for the selection of accident scenario' under the chemicals control act and 'Guidelines for chemical process quantitative risk analysis' of center for chemical process safety. The risk estimates were utilized for consequence analysis and frequency analysis by SAFETI program of DNV, event tree analysis methodology and part count methodology. The individual risk of ammonia system was derived as 7.71E-04 / yr, social risk were derived as 1.17E-03 / yr. The derived risk was confirmed to apply as low as reasonably practicable of the national fire protection association and through risk calculation, it can be used as a way to minimize accidents ammonia leakage accident damage.

Comprehensive Analysis of Exposed Adverse Factors in Disaster Response Activities - Focused on Fire - (재난 대응 활동 시 노출가능 유해인자 종합분석 -화재 현장을 중심으로-)

  • Park, Chanseok
    • Journal of the Society of Disaster Information
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    • v.10 no.3
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    • pp.420-430
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    • 2014
  • Firefighters performing disaster response activities such as Fire Suppression Rescue First Aid in fire are being exposed in various adverse factors, heat, smoke, toxic gases, emotional stress, biological toxic factors and physical overload by unnatural ergonomic posture required for firefighters. But so far, there is the study for this problem only separately. There is no study about comprehesive analysis of exposed adverse factors in fire-related disaster response activities and countermeasures. The purpose of this study is to contiribute to solving the health problems and prevention of accidents of firefighters by extracting hazardous agents in disaster such as fire and by proposing countermeasures. After analyzing circumstances such as fire-suppression, rescue first aid and life-environment, exposure factors of fire are derived and exposure status is suggested according to physical chemical biological psychological aspects. The countermeasure against the noise of the physical exposure factors are proposed. The countermeasures such as protective equipment and clean room in chemical factors, infection prevention education, vaccination and periodic check system in biological factors, PTSD alleviation booth and mentoring in psychological factors are proposed.

A Numerical Study for Fire Safety Evaluation of the Multi-story Residential Buildings -The Effects of the Openings of Stairwell on Fire Characteristics- (다세대주택의 화재안전평가에 대한 수치해석 연구 -계단실 개구부의 개폐가 화재특성에 미치는 영향-)

  • Jeon, Heung-Kyun;Choi, Young-Sang;Choo, Hong-Lok
    • Fire Science and Engineering
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    • v.21 no.3
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    • pp.15-23
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    • 2007
  • In the events of a fire in the residential building, highly flammable polyurethane foam sofa produce toxic smokes. In this type of fire, the residents of the building can be gotten into the difficulties of evacuating from the fire places or may be to death due to a lot of hot toxic gases. In this study, CFD simulations were carried out to study the effects of the openings of stairwell on the fire characteristics of fire room and stairwell. Also, analysis of fire hazard based on the tenability limits of fire and FED(fractional effective dose) was performed to evaluate the life safety of the residents of the building. In the fire room, maximum temperature was about $290^{\circ}C$, maximum CO concentration was about 4,740 ppm, and the time to incapacitation of residents in fire room was about t=144 s. In the stairwell, temperature and CO concentration in the condition of openings to be open were even lower than those in it to be closed. Time to the tenability limit with respect to smoke visibility in the stairwell with openings, which was open, was shorter than that of it without openings to be open. It has been shown from this study that opening the stairwell openings is able to decrease the fire hazards to the life safety in the multi-story residential building fire.

Evaluation of the Burning Properties of Various Carpet Samples by using the Cone Calorimeter and Gas Toxicity Test (콘칼로리미터와 가스유해성 시험법을 이용한 카페트류의 연소특성 평가)

  • Lee, Bong-Woo;Kwon, Seong-Pil;Lee, Jang-Won;Lee, Byoung-Ho;Kim, Hee-Soo;Kim, Hyun-Joong
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.1-9
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    • 2009
  • In this study, the burning behaviours of five different kinds of carpet samples covered with nylon, PP (polypropylene), PTT (poly(trimethylene terephthalate)), wool fabric and NW (nylon and wool) were evaluated by using the cone calorimeter having a radiant flux of 50kW/$m^2$. And the combustion gas toxicity was evaluated according to KS F 2271 test method. As a result of the cone calorimeter test (KS F ISO 5660-1), nylon carpet samples were ignited most easily. In ignition ability or initial flammability, NW carpet samples showed the highest value. In heat release rate (HRR), fire intensity, PP carpet samples were larger than any other samples. Nylon carpet samples were the highest smoke production rate, while N/W carpet samples the lowest. The following were in mass loss rates: NW > wool > nylon > PP > PTT. CO (carbon monoxide) was one of the most toxic gases released from the combustion. PTT carpet samples gave rise to the highest CO concentration, while NW carpet samples the lowest. In addition, PP carpet samples caused the highest $CO_2$ (carbon dioxide) concentration, while NW carpet samples the lowest. Toxicity of the gas produced from carpet samples was determined by the mouse stop motion, and it resulted in the fact that the combustion gas of PTT carpet samples was more toxic than that of any other samples.

A Study on Measures to Prevent Leakage of Process Fluid from the VCR Fitting used in the Semiconductor Manufacturing Process (반도체 제조 공정에서 사용되는 이송배관 연결부위(VCR Fitting)로부터 공정유체 누출사고 예방 대책에 관한 연구)

  • Dae Joon Lee;Sang Ryung Kim;Sang Gil Kim;Chung Sang Kang;Joon Won Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.79-85
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    • 2023
  • Recently, in the semiconductor process, large companies are seeking process changes from memory semiconductors to the foundry due to the increase in demand due to the 4th industry. industry is expanding. The characteristics of special gases and precursors, which are raw materials used to produce these semiconductor chips, are toxic, pyrophoric, inflammable, and corrosive. These semiconductor raw materials are operated in a closed system and do not leak to the outside during normal times, but when leaked, they spread to the inside of the gas box, and when proper ventilation is not provided inside the gas box, they spread to the outside, causing fires, explosions, or toxic substances. It can lead to major accidents such as leakage. Recently, there have been cases of accidents in which hazardous materials leaked from the closed system of the semi conductor process and spread to the inside and outside of the gas box. . In this study, we propose preventive measures based on the case of an accident in which raw material leaked from the VCR fitting, which is the connection part of the semiconductor raw material transfer pipe, and spread to the outside of the gas box.

The effect of exit opening rate on exhaust gas pressure, temperature, and engine performance (배기 출구 개도율이 배기 압력과 온도 및 엔진 성능에 미치는 영향)

  • Kim, Cheol-Jeong;Choi, Byung-Chul;Park, Kweon-Ha
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.1
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    • pp.15-22
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    • 2014
  • Multiple devices have been installed to reduce exhaust emissions and to increase thermal efficiency. Those devices reduce the exhaust pipe opening area and increase the exhaust gas pressure. The pressure increase disturbs a gas flow and has a bad effect on the engine performance. However there is some study that NOx can be reduced with exhaust gas pressure increase. In this study an engine performance is tested with various opening ratios. The result shows that the fuel consumption rate is reduced in case of little amount of the pressure increase, and NOx is reduced with the pressure increase, while the concentration of the toxic exhaust gases are increased in the case of high back-pressure.

A Study on MDA Analysis & blood chemical test for Mouse which were exposed HF Gases from Fire (화재로 인한 불화수소(HF)가스에 노출된 마우스의 혈액생화학분석 및 MDA분석을 통한 세포손상에 관한 연구)

  • Cho, Nam-Wook;Oh, Eun-Ha
    • Journal of the Korean Institute of Gas
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    • v.17 no.6
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    • pp.58-66
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    • 2013
  • Among the risks which can be faced with fire, combustion toxicity is a significant influence on the survival. Fire toxicity researches have been limited generally on the lethal aspects. In this study, HF gas which can be generated from fire, and also found in general industrial site was used for analysis. Blood analysis and biochemistry analysis performed to find internal demage of experimental animals which were used for measuring average activity stopping time from Animal test(KS F2271: Gas hazard test). In addition, Using the malondialdehyde analysis, indicators of oxidative damage, we had quantitative analysis to target lymphocyte for measuring the oxidative damage caused by toxic substances.

A Study on Comparison and Shortening of Evacuation Time Required of University Library by Simulation (시뮬레이션을 통한 대학도서관의 피난 소요시간 비교 관한 연구)

  • An, Jeong-Pill;Kim, Gwang-Hee
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.16 no.2
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    • pp.10-18
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    • 2017
  • The University library is a reality where facilities can be a massive upset by the space of students to study space and book materials. Also, many print materials can cause fires quickly in fires, resulting in massive amounts of human casualties caused by many toxic gases. This study purpose is compares the time spent in the evacuation of the current state through the simulation, which seeks to derive a reasonable library of evacuation design, and improved inside the evacuation. As a result, the most obvious way to reduce the time required to evacuate is to diversify the evacuation routes and to disperse them. However, if the extension of the gate is not feasible, it is possible to reduce the time of escape by increasing the width of the gate and the width of the stair. If the results of this study are applied to new construction or remodeling of the library and prepare for fire evacuation, it will be a much safer library facility.

An Investigation of Ingredients and Hazardous Substances in Some Consumer Products - Focusing on Cleaners and Disinfectants - (일부 생활화학용품에 함유된 성분 및 유해물질 조사 - 세정제와 소독제를 중심으로 -)

  • Heo, Da-An;Huh, Eun-Hae;Park, Ji Young;Moon, Kyong Whan;Lee, Kiyoung
    • Journal of Environmental Health Sciences
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    • v.41 no.5
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    • pp.314-326
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    • 2015
  • Objectives: This study was conducted to identify the ingredients used in ten consumer product categories and determine hazardous substances among these ingredients. Methods: A total of 542 commercial products in ten consumer product categories were selected. The consumer products were sticker removers, washing machine cleaners, multi-purpose cleaners, mold removers, glass cleaners, chlorinated sanitizers, air conditioner cleaners, disposal cleaners, drain cleaners and disinfectant sprays. The company list was complied from governmental records and a market survey. The respective companies were contacted for a list of ingredients found in the 542 products. Results: The corresponding companies listed 163 ingredients. According to European Union (EU) Directive 67/548/EEC, 38 of the 163 ingredients were classified as dangerous substances. Among these substances, 28 ingredients were hazardous to the skin, 15 were hazardous to the eye, and nine were hazardous if inhaled. Three ingredients were classified as CMR (carcinogenic, mutagenic or toxic for reproduction) substances: liquefied petroleum gases (LPG) with carcinogenicity and mutagenicity, and VM&P naphtha and ligroine with carcinogenicity. Conclusion: Various chemicals, including hazardous substances, were used in consumer products. Risk assessment of consumer products is required in order to protect the population from health risks.

Groundwater Contamination at the Seokdae Waste Landfill Area of Pusan City (부산 석대 폐기물 매립장 일대의 지하수 오염)

  • 정상용
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.1-8
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    • 1995
  • Wastes produce groundwater contamination, offensive odor, and hazardous gases. This study investigates the contamination of groundwater at the Seokdae waste landfill area and seeks the desirable ways to minimize the groundwater contamination. Groundwater levels, water chemistry and aquifer characteristics of wells were examined around the Seokdae waste landfill. The water chemistry of the Dong stream, the groundwater distribution and flow were also studied. The results of this research show that the estimated quantity of the percolation from the landfill base to the ground is 520 ㎥/day and the extent of groundwater contamination is about 1-1.5 km from the center of the waste landfill. The groundwater contains heavy metals and other toxic elements. The conservation and management of the groundwater of the waste landfill need several monitoring wells to check the quantity and quality of groundwater, pumping wells to extract the contaminated groundwater, and slurry walls to protect the movement of contaminated groundwater.

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