• 제목/요약/키워드: Toxic gases

검색결과 224건 처리시간 0.026초

화재 발생 지하철 역사에서의 여객 대피 해석에 관한 연구 (A Numerical Study on Passenger Evacuation in a Subway Station in Case of Fire Occurrence)

  • 김치겸;이성원;허남건;남성원
    • 설비공학논문집
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    • 제22권8호
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    • pp.509-514
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    • 2010
  • A numerical simulation of passenger evacuation in a subway station was performed by coupling the passenger flow analysis and the fire simulation. The algorithm of the passenger flow analysis was based on a DEM (Discrete Element Method) using the potential map of the direction vector for each passenger. This algorithm was improved in the present study as to use finer grid smaller than a passenger in order to resolve detailed geometry of the station and to resolve the behavior of passengers in the bottleneck at the ticket gate considering the collision of passengers to a wall or with other passengers. In the fire simulation, the CO distribution predicted by using CFD was used to take into account the effect of toxic gases on the passengers' mobility. The methodology proposed in the present study could be used in designing safer subway station in case of fire occurrence.

테트라진 계열의 추진 물질 합성 연구 (Synthesis and Characterization of Tetrazine Derivatives as High Energy Propellants)

  • 이웅희;박영철;주영혁
    • 한국추진공학회지
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    • 제17권6호
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    • pp.38-47
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    • 2013
  • 기존에 사용되어 온 추진제들은 연소 시 많은 양의 유해가스 발생으로 환경적인 문제점이 있다. 본 논문에서는 이러한 문제점을 개선하기 위하여 고체 연료로 적용 가능한 tetrazine 계열의 저탄소 고질소 화합물인 TATTz와 BTATz에 대한 합성공정을 확립하였다. 또한, 문헌에 빠져있는 구체적인 공정법 및 특성 분석 결과를 서술하였다. 합성된 모든 물질들은 분광분석 (NMR, IR)을 이용한 구조분석, DSC를 이용한 열분석, 측정된 밀도와 계산된 생성열을 근거로 폭발속도, 폭발압력 등을 계산하였다(EXPLO5).

폴리프로필렌의 금속첨가형 난연제에 의한 난연 특성 (Incombustibility of Polypropylene by Metal Addition Flame Retardant)

  • 이상은;송영호;정국삼
    • 한국안전학회지
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    • 제20권4호
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    • pp.40-45
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    • 2005
  • The principal actions of a flame retardant are to decrease or prevent the formation of volatile products and increase the formation of char layer. Use of flame retardant additives can decrease the overall fire hazard of the product containing them thus leading to an increase in overall fire safety. Although several flame retardants have been developed for use in polymers, many of these are known to increase the amount of smoke and toxic gases generated by them. This paper present a new flame retardant using metal addition flame retardant. For this study, the experiments of flame retardancy conducted are as follows : burning ratio, weight loss rate using TGA-DTA, the measurement of LOI and char yield. And smoke mass concentration and CO yield were measured. The metal addition flame retardant reduced burning ratio and weight loss rate, increased the LOI and yield of char formation with decreased smoke mass concentration and CO yield.

Efficiency Estimation of Toxicity Free Eire Resistance Cable

  • Yoon, Hun-Ju;Hon, Jin-Woong
    • Transactions on Electrical and Electronic Materials
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    • 제3권3호
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    • pp.34-38
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    • 2002
  • In this paper, efficiency estimation of toxicity fee fire resistance cable experiments was measured smoke density of toxicity free fire resistance polyolefin insulation material and electric field dependence of tree shape in low density polyethylene (LDPE). One of the most serious causes of failure in high-voltage cables, can be an electrical discharge across an internal gab or void in the insulating material. Treeing due to partial discharge is one of the main causes of breakdown in the insulating materials and reduction of the insulation life. Therefore the necessity for establishing a method to diagnose the aging of insulation materials and to predict the breakdown of insulation and research of the fire resistance character has become important. First, we have studied on electric field dependence of tree shape in LDPE about treeing phenomena occurring on the high electrical field. Second, the measurement method is the attenuation quantity of irradiation by smoke accumulating with in a closed chamber due to non-flaming heat decomposition and flaming combustion. A main cause of fire-growth and generating toxic gas when, it bums, should be dealt with great care in life. safety design. The fire gases were occurred carbon monoxide and decomposition than in polyolefin due to incomplete combustion of PVC, which has high content of carbon in chemical compound.

화재시 제연 및 피난을 위한 기능성 차압 조절장치 개발에 관한 연구 (The Development of a Functional Pressure Controller in Smoke Management Systems for the Fire Safety of Buildings)

  • 정기창;김정훈;이정윤
    • 한국안전학회지
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    • 제19권1호
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    • pp.44-48
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    • 2004
  • The smoke and toxic gases generated from the building fires are proved to cause human death. Therefore, the necessity and significance of smoke control have been emphasized, and lots of studies for developing improved smoke management system have been carried out. In this study, the experiments were conducted to evaluated a function and performance in newly developed smoke management system using mechanical pressurization. As a result of this experiment, the differential pressure was 40Pa${\sim}$60Pa and the air velocity through the door was 0.7m/s between safety zone and fire zone. The functional pressure control equipment which could make proper pressure and maintain differential pressure between safety zone and fire zone was developed. And it will give a lot of helps to evacuation activity for peoples in building and fire fighting.

고질소 추진물질 합성 연구 (The Study on the Synthesis of Propellant with High Nitrogen Content)

  • 이웅희;김민준;박영철
    • 한국추진공학회지
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    • 제19권3호
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    • pp.96-102
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    • 2015
  • 기존에 사용되고 있는 대부분의 추진물질들은 연소 시 이산화탄소, 염산가스 등의 환경유해 물질을 다량 발생시킨다. 본 연구에서는 이러한 문제점을 개선하기 위한 테트라진 계열의 저탄소 고질소 화합물인 DAAT의 합성공정을 확립하였다. 또한, 문헌에 빠져있는 구체적인 공정법 및 특성 분석 결과를 서술하였다. 그리고 분광분석(NMR, IR)을 통한 DAAT의 구조분석과 열, 충격, 마찰 안정성을 측정하였고, Gaussian 09와 EXPLO5를 이용하여 생성열과 폭발 특성(폭압, 폭속) 등을 계산하였다.

교대근무자의 피로와 수행영향인자 간의 상관관계 분석 (반도체 산업을 중심으로) (Correlation Analysis between Fatigue and Performance Shaping Factor for Alternation Worker's (Focused on the Semiconductor industry))

  • 윤용구;박범
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2008년도 추계학술대회
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    • pp.303-316
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    • 2008
  • For the past 25 years, Korean semiconductor has experienced enormous growth to be the highest production country in the world. Semiconductor industry is very time sensitive and driven by technology and process, and requires 24-hour full operation. The environment includes many different types of equipment, utilities, different gases and toxic chemicals as well as high voltage electricity. We have performed a survey with 3-shift engineers and workers in one line. The content of the questionnaire was about the correlation between fatigue and performance shaping factor (work type and work ability), and as a result we were able to deduce the correlation, p-value and the pattern of scatter plot. The shape of the model was made of 4 blocks for fatigue, 5 blocks for work type and 5 blocks for work ability, i. e. 14 blocks in total. As a conclusion to this findings, there was a correlation between fatigue and work type and work ability specifically in semiconductor industry, and we need some effort to reduce this.

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독성가스 제거용 기포탑 반응기의 설계기법 (Design Parameters Estimations for Bubble Column Reactors to Remove Toxic Gases)

  • 오정환;홍민선
    • 한국위험물학회지
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    • 제6권2호
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    • pp.95-104
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    • 2018
  • Gas-liquid bubble column reactors are extensively used in industrial processes. A detailed knowledge of bubble size distribution is needed for determining the mass transfer in gas-liquid film. Experimental data on bubble size distribution and liquid-side mass transfer coefficient($k_L$) were used to calculate the estimated time to saturation in bubble column reactor. Also, the gas flux was evaluated to the liquid-side mass transfer coefficient($k_L$) and solubility data for hydrogen sulfide($H_2S$) and chlorine($Cl_2$) absorption into water. Simulation results show that $H_2S$ absorption time to 50 % of saturation concentrations are 611 sec and 1,329 sec when bubble diameters are 0.5 mm and 4.5 mm, while absorbing 1 % $H_2S$ gas. In case of $Cl_2$, absorption time range 657 to 1,400 sec when bubble size range 0.5 mm to 4.5 mm, while absorbing 1 % $Cl_2$ gas. Calculated simulation results can be used in the design of emergency relief bubble reactors.

신규 보호회로 적용을 통한 저전류 장비용 군 리튬전지 안전성 개선 (Safety Improvement of Military Primary Lithium Batteries by New Protection Circuit for Low Current System)

  • 윤성기;조유습
    • 한국전기전자재료학회논문지
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    • 제32권3호
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    • pp.256-261
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    • 2019
  • The use of military lithium batteries in this field accelerates the generation of internal pressure because the active materials, lithium and the electrolyte, react to form sulfur dioxide gas. This also reduces the amount of electrolyte. In this condition, batteries can 'vent' or 'explode' especially when completely discharged. Such venting and explosion can be regarded as a safety accident, as toxic gases and shrapnel are ejected from the batteries which can harm the user. A DTaQ was carried out in 2017 as a quality problem solution project to solve this safety issue. A protection circuit was thereby developed, which included a micro controller unit (MCU) which can stop battery usage when in an over-discharging state by sensing its low-voltage condition. In 2018, this concept was expanded to lithium batteries for the remote controlled ammunition system. This paper reports results of the improved performance.

Influence of oil pipe corrosion defects on the sealing performance of annular BOP

  • Dong, Liangliang;Tang, Yuan;Wang, Liuyang
    • Structural Engineering and Mechanics
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    • 제84권3호
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    • pp.337-344
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    • 2022
  • Due to corrosion defects on the surface of the oil pipe, the sealing performance of the annular blowout preventer (BOP) decreases, and the leakage of toxic and harmful gases such as H2S and SO2 will threaten the safety of operators on the well. Therefore, this paper establishes the FE model for evaluating the sealing performance of BOP-oil pipe corrosion defects, which is based on the rubber large deformation theory and rubber core sealing mechanism, and designs the experiment of BOP sealing performance to verify the accuracy of the FE model. The sealing performance of BOP sealing oil pipe with corrosion defects is studied. The research results show that the sealing performance of BOP is more sensitive to the axial size of corrosion defects. With the increase of oil pipe outer diameter, the critical size of defects increases continuously. The sensitivity of radial and depth dimensions is low, When for 88.9 mm outer diameter oil pipe, the axial critical size of corrosion defect is 20 mm, the radial critical size is 16 mm and the critical depth is 2 mm. Fit the formula between the outer diameter of oil pipe and the piston increment. According to the formula, the operator can calculate the piston stroke increment required by the BOP to complete the sealing when the oil pipe is corroded.