• Title/Summary/Keyword: Toxic Waste

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A Study on the Response Technique for Toxic Chemicals Release Accidents - Hydrogen Fluoride and Ammonia - (독성 화학물질 누출사고 대응 기술연구 - 불산 및 암모니아 누출을 중심으로 -)

  • Yoon, Young Sam;Cho, Mun Sik;Kim, Ki Joon;Park, Yeon Shin;Hwang, Dong Gun;Yoon, Jun heon;Choi, Kyung Hee
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.31-37
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    • 2014
  • Since the unprecedented hydrogen fluoride leak accident in 2012, there has been growing demand for customized technical information for rapid response and chemical accident management agencies including the Ministry of Environment, the National Emergency Management Agency, and the National Police Agency need more information on chemicals and accident management. In this regard, this study aims to provide reliable technical data and guidelines to initial response agencies, similar to accident management technical reports of the US and Canada. In this study, we conducted a questionnaire survey and interviews on initial response agencies like fire stations, police stations, and local governments to identify new information items for appropriate initial response and improvements of current guidelines. We also collected and reviewed the Canada's TIPS, US EPA's hydrogen fluoride documents, domestic and foreign literature on applicability tests of control chemicals, and interview data, and then produced items to be listed in the technical guidelines. In addition, to establish database of on-site technical information, we carried out applicability tests for accident control data including ① emergency shut down devide, safety guard, shut down valve, ground connection, dyke, transfer pipe, scrubber, and sensor; ② literature and field survey on distribution type and transportation/storage characteristics (container identification, valve, ground connection, etc.); ③ classification and identification of storage/transportation facilities and emergency management methodslike leak prevention, chemicals control, and cutoff or bypass of rain drainage; ④ domestic/foreign analysis methods and environmental standards including portable detection methods, test standards, and exposure limits; and ⑤ comparison/evaluation of neutralization efficiency of control chemicals on toxic substances.

Groundwater Contamination at the Seokdae Waste Landfill Area of Pusan City (부산 석대 폐기물 매립장 일대의 지하수 오염)

  • 정상용
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.1-8
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    • 1995
  • Wastes produce groundwater contamination, offensive odor, and hazardous gases. This study investigates the contamination of groundwater at the Seokdae waste landfill area and seeks the desirable ways to minimize the groundwater contamination. Groundwater levels, water chemistry and aquifer characteristics of wells were examined around the Seokdae waste landfill. The water chemistry of the Dong stream, the groundwater distribution and flow were also studied. The results of this research show that the estimated quantity of the percolation from the landfill base to the ground is 520 ㎥/day and the extent of groundwater contamination is about 1-1.5 km from the center of the waste landfill. The groundwater contains heavy metals and other toxic elements. The conservation and management of the groundwater of the waste landfill need several monitoring wells to check the quantity and quality of groundwater, pumping wells to extract the contaminated groundwater, and slurry walls to protect the movement of contaminated groundwater.

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Effect of Waste Glass Wool on Mechanical Properties of Concrete (폐글라스울이 콘크리트의 역학적 특성에 미치는 영향)

  • Kim, Jeong-Tae;Choi, Woo-Hyuk;Chung, Chul-Woo;Lee, Jae-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.2
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    • pp.117-123
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    • 2016
  • Glass wool is a material that has been used as a heat insulator in various fields including construction industry. Since it is a nonflammable material, it does not generate toxic gases on fire, and thus public agencies recommend using glass wool as a heat insulator instead of other organic materials. However, repeated drying and wetting cycles can deteriorate thermal property of glass wool due to the shrinkage and reduction in pore size. For this reason, it needs to be replaced periodically, and waste materials are generated. This research aims to utilize waste glass wool as additives for increasing mechanical properties of concrete. According to the experimental results, it was found that glass wool has weak pozzolanic activity, and beneficial effect on both compressive and flexural strength. The optimum amount found in this experimental work was 0.5% volumetric addition to the concrete.

Current Status of Recycling of LED Waste (LED 폐자원의 재활용 현황)

  • Lee, Duk-Hee;Shin, Dongyoon;Kim, Tae-Hyung;Lee, Chan-Gi;Park, Kyung-Soo;Lee, Ki Woong;Lee, Jaeryeong
    • Resources Recycling
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    • v.28 no.2
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    • pp.14-22
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    • 2019
  • Development of technology makes LED an economical option because of lower energy consumption and better environmental impact. Because higher consumer demand the LED market is expanding rapidly due to its environment-friendly advantages. Expansion of LED application, development of various fusion technologies, the emergence of new markets, and the large-scale expansion of markets would lead to a large volume of e-waste generation with valorization potential. Currently, most of the generated waste being that landfilled and incinerated due to the absence of technology and management system. In this paper, we review the current status of LED waste recycling and analyzes the available recycling technologies.

Heavy Metals of Landfilled Biomass and Their Environmental Standard, Including CCA-treated Wood for Eco-housing Materials (방부처리 목재를 포함한 토양매립 바이오메스의 중금속 함량과 안전성 문제)

  • Lim, Kie-Pyo;Lee, Jong-Tak;Bum, Jung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.37-45
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    • 2006
  • Recently, wood-framed houses has been built in the Korea for pension. Wood is good material for human healthy, while the construction lumbers are treated with preservative such as CCA (chromated copper arsenate), which contain some toxic elements for human body. However, if the waste woody biomass treated with various heavy metals, which has been collected from house construction or demolition, was fired in the field, and incinerated or landfilled after mass collection, such components will result in the toxic air pollutants in the burning or land fills, and spreaded into other areas. So the careful selection of wood and chemicals are required in advance for house construction, in particular, for environment-friendly housings. Therefore, this study was carried out to determine the content of toxic heavy metals in woody materials such as domestic hinoki and imported hemlock treated with CCA for housing materials, and the post-treated wood components such as organic fertilizer, sludge, dry-distilled charcoal and carbonized charcoal, to be returned finally into soil. The results are as follows. 1) The chemical analysis of toxic trace elements in various solid biomass required accurate control and management of laboratory environment, and reagents and water used, because of the error of data due to various foreign substances added in various processing and transporting steps. So a systematic analyzers was necessary to monitor the toxic pollutants of construction materials. 2) In particular, the biomass treated with industrial biological or thermal conditions such as sludge or charcoals was not fully dissolvable after third addition of $HNO_3$ and HF. 3) The natural woody materials such as organic fertilizer, sludge. and charcoals without any treatment of preservatives or heavy metal components were nontoxic in landfill because of the standard of organic fertilizers, even after thermal or biological treatments. 4) The CC A-treated wood for making the construction wood durable should not be landfilled, because of its higher contents of toxic metals than the criterion of organic fertilizer for agriculture or of natural environment. So the demolished waste should be treated separately from municipal wastes.

A Study on Treatment of Wastes from the Uranium Ore Dissolution/purification and Nuclear Fuel Powder Fabrication (우라늄 정광의 용해/정제 및 핵연료 분말 가공공정에서 발생된 폐액의 처리에 관한 연구)

  • Jeong, Kyung-Chai;Hwang, Seong-Tae
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.99-107
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    • 1997
  • This study Provides the treatment methods of liquid wastes from the dissolution/purification process of nuclear fuel raw material and the fabrication process of nuclear fuel powder. One of the treatment methods is to process liquid waste from uranium raw material dissolution/purification process. This waste, of the strong acid, can be reused to dissolve the fine ADU particles in filtrate which is ADU waste of pH 8.0 converted from AUC waste after recovery of uranium. To dissolve the fine ADU particles, ADU filtrate was pretreated to pH 4.0 with the dissolution/purification waste, and then mixed with the lime to pH 9.2 and aged for 30 minutes. From this processing, uranium content of the filtrate was decreased to below 3ppm. The waste from fuel powder fabrication is emulsified solution dispersed with fine oil droplets. This emulsion was destroyed effectively by adding and mixing the nitric acid with rapid heating at the same time. After this processing, $Na_2U_2O_7$ compound is produced by addition of NaOH. Optimum condition of this processing was shown at pH 11.5, and uranium content of the filtrate was analyzed to 5ppm. To remove the trace of uranium in the filtrate, lime should be added. Otherwise, 4N nitric acid was used to destroy the emulsion directly, and then lime was added to this waste. Uranium content of the treated filtrate was below 1 ppm. In addition to these wastes, the trace of uranium in filtrate after recovery of uranium from the AUC waste which is produced during PWR power preparation, is treated with NaOH to takeup fluorine(F) in the waste because fluorine is valuable and toxic material. In the finally treated waste, uranium was not detected.

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Levels of Persistent Organic Pollutants in Waste Paper and Waste Lumber and Evaluation of their Sources (폐지와 폐목재에서의 잔류성 유기오염물질의 농도 및 배출원 추정)

  • Hwang, In-Kyu;Lee, In-Seok;Oh, Kwang-Joong;Kim, Ji-Won;Park, Hung-Suck;Oh, Jeong-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.870-878
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    • 2010
  • We investigated the concentration and the sources of ubiquitous persistent organic pollutants [i.e., 17 toxic polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), 12 coplanar polychlorinated biphenyls (Co-PCBs), and 16 priority polycyclic aromatic hydrocarbons (PAHs)] in waste papers and lumbers from industrial complexes. The total concentrations in waste papers and lumbers ranged from 9.69~176.77 pg/g-dry and 0.14~0.25 pg/g-dry for 17 PCDD/Fs, 109.95~4097.25 pg/g-dry and 28.23~59.88 pg/g-dry for 12 Co-PCBs and 9.30~52.18 ng/g-dry and 0.82~1.82 ng/g-dry for 16 PAHs respectively. Generally, the concentration of these pollutants in waste papers was higher than those in waste lumbers. OCDD was dominant in waste papers and lumbers and the PCDD/F patterns of these samples were similar with that of stack gas. The distribution patterns of Co-PCBs in wastes were related with commercial PCB products, indicating the effect of commercial PCB products on ubiquitous environment. The diagnostic ratios of several PAH compounds in waste paper showed that they were related with pyrogenic sources.

Comparison of USEPA Digestion Methods for Trace Metal Analysis Using SRM

  • Shin, Mi-Young;Yoon, Hyeon;Kim, Youn-Tae;Yoon, Cheol-Ho;Woo, Nam-Chil
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.223-226
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    • 2004
  • The importance of a proper sample preparation and analysis technique has getting attention due to the complicity of toxic elements of interest from environmental samples depend on analytical purposes. It is critical to use proper analytical method to evaluate trace elements concentration in many environmental samples especially for making remediation decisions. Therefore, it is critical to apply a proper sampling and analytical method such as EPA publication SW-846 (Test Methods for Evaluating Solid Waste, Physical/chemical Methods). The objective of this study was to compare the USEPA Methods 3050B, modified 3050B, 305 la, and KBSI method (modified EPA 3052 Method) in term of recovery rate of metals. The NIST SRM (Montana soil) was used to compare the extraction and digestion efficiency. After sample has been collected the analysis were achieved by ICP-MS (Elan 6100, Perkin Elmer) as well as ICP-AES (Ultima 2C, JY) for trace elements and major elements.

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Trend of Toxic Nanomaterial Detecting Sensors (독성 나노물질 검출 센서 동향)

  • Jang, Kuewhan;Na, Sungsoo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.24 no.12
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    • pp.977-984
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    • 2014
  • Nanomaterial have grown from scientific interest to commercial products and the nanomaterial market has grown 19.1 % each year. As the nanomaterial market size increases, it is expected that nanomaterial production will increase and its contamination of outdoor environmental system will also increase in the form of industrial waste. Since most of nanomaterials are known as biologically non-degradable materials, nanomaterials will accumulate in the environment, and this will increase the potential threats to human health along the food chain. Recent studies have investigated the toxicity effect of nanomaterials due to their size, chemical composition and shape. For the development of nanomaterial while taking human health into consideration, a nanomaterial detecting sensor is required. In this paper, we have observed the trend of nanomaterial detecting sensor of mechanical, electrochemical, optical and kelvin probe force microscopy sensors and we believe that this trend will shed the light on the development of real-life nanomaterial detecting sensors.

Fed Batch Culture of Hybridoma for Reduction of Lactate and Higher Monoclonal Antibody Productivity (젖산 생성 감소 및 단일군항체 생산성 향상을 위한 하이브리도마의 유가배양)

  • 이은열;김희숙
    • Journal of Life Science
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    • v.9 no.3
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    • pp.293-299
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    • 1999
  • Accumulation of toxic waste byproducts in hybridoma culture can limit cell growth and monoclonal antibody (MAb) productivity, and one of the major toxic metabolites is lactate produced via glycolytic pathway of glucose metabolism. The factors affecting the glucose to lactate conversion rate were investigated. The conditions of high initial glucose concentration and high growth rate stimulated glucose to lactate conversion rate. The glucose-controlled fed-batch culture was investigated, and 19% reduction in lactate formation and 41% enhancement of MAb titer could be achieved by fed-batch culture.

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