• Title/Summary/Keyword: Toxic Waste

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Waste Minimization Technology Trends in Semiconductor Industries (반도체 제조 공정에서의 환경 유해성 배출물 절감 기술 동향)

  • Lee, Hyunjoo;Yi, Jongheop
    • Clean Technology
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    • v.4 no.1
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    • pp.6-23
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    • 1998
  • Recently, semiconductor industry has grown rapidly because of the large demand for electronic devices and equipment. The semiconductor industries have also played an important role on the economic growth in Korea. As the environmental regulations become strict, the proper environmental management and the well-developed waste minimization technologies in semiconductor industries are two of urgent problems to be solved. The semiconductor manufacturing process consists of a series of continuous chemical processes, such as cleaning, oxidation, diffusion, photolithography, etching and film deposition. During the processes, various environmentally hazardous wastes are produced. The wastes may be classified as wastewater, gaseous pollutants, and solid wastes. For waste minimization, the substitution of raw materials and process optimization techniques are used, while the selective destruction technologies of toxic chemicals contained in the wastes have been reported. Also, new technologies have been developed for source reduction and waste reduction, such as reduction of toxic chemical use and substitution of hazardous liquids with gaseous reactants or solvent.

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Single and mixed chelants-assisted phytoextraction of heavy metals in municipal waste dump soil by castor

  • Wuana, Raymond A.;Eneji, Ishaq S.;Naku, Julius U.
    • Advances in environmental research
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    • v.5 no.1
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    • pp.19-35
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    • 2016
  • The phytoextraction of some toxic heavy metals from municipal waste dump soil by castor plant (Ricinus communis) was tested under natural and single or mixed chelant-assisted scenarios in pot microcosms. A sandy loam with total metal contents (mg/kg): Cd (84.5), Cu (114.5), Ni (70.3), Pb (57.8), and Zn (117.5), was sampled from an active dumpsite in Calabar, Nigeria and used for the study. Castor (small seed variety) was grown under natural phytoextraction or single/binary chelant (citric acid, oxalic acid, and EDTA) applications (5-20 mmol/kg soil) for 63 days. Castor exhibited no visual phytotoxic symptoms with typically sigmoid growth profiles at the applied chelant doses. Growth rates, however, decelerated with increase in chelant dose. Post-harvest biomass yields were higher under chelant application than for natural phytoextraction. Both root and shoot metal concentrations (mg/kg) increased quasilinearly and significantly ($p{\leq}0.05$) with increase in chelant dose, furnishing maximum levels as: Cd (55.6 and 20.9), Cu (89.5 and 58.4), Ni (49.8 and 19.6), Pb (32.1 and 12.1), and Zn (99.5 and 46.6). Ranges of translocation factors, root and shoot bioaccumulation factors were 0.21-3.49, 0.01-0.89 and 0.01-0.51, respectively. Overall, the binary chelant treatments were less toxic for R. communis growth and enhanced metal accumulation in shoots to a greater extent than the single chelant scenarios, but more so when EDTA was present in the binary combination. This suggests that the mixed chelants could be considered as alternative treatments for enhanced phytoextraction and revegetation of degraded waste dump soils.

Thermophilic Co-Digestion of Municipal Sewage Sludge and Food Waste (음식물쓰레기의 하수슬러지를 이용한 고온통합 소화)

  • Han, So-Young;Kang, Ho;Choi, Yeon-Seok;Kim, Chi-Yeol
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.731-743
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    • 2018
  • This study was performed to test the feasibility of thermophilic ($55^{\circ}$) co-digestion of municipal sewage sludge and food wastes. The management variables of co-digestion were the mixed ratios of municipal sewage sludge and food waste hydraulic retention times (HRTs). During the operation of thermophilic co-digestion, the reactor pH ranged from 7.0 to 7.5 and the reactor alkalinity remained above 3,200 to 4,000 mg/L as $CaCO_3$. The volatile fatty acids concentration increased as the HRT shortened from 20 days to 10 days and the mixture ratio increased to 1:4, but did not reach toxic levels for co-digestion of sewage sludge and food wastes. Methane productivity increased gradually as the organic loading rate increased. Maximum methane productivity reached 1.03v/v-d at an HRT of 10 days and at the mixture ratio of 1:4. The TVS removal efficiency decreased from 70.6% to 58.3% as the HRT shortened from 20 days to 10 days. TVS removal efficiency ranged from 57.0% to 77% during the entire operation. It is likely that thermophilic co-digestion of sewage sludge and food wastes is a very effective method both to environmentally treat food waste and to economically produce gas for energy.

An Experimental Study on Stabilization/Solidification of Plated Sludge using Cement (시멘트를 이용한 도금 슬러지 고형화에 대한 실험적 연구)

  • 김남중;김광서
    • Journal of the Korea Institute of Building Construction
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    • v.1 no.2
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    • pp.146-153
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    • 2001
  • Radical development has been made in the every field of our society for the past scores of year. Radical development of industry and lining environment has mass-produced various toxic wastes . Which comes to the fore as a serious environmental problem. The purpose of this is to suggest the optima mix design by studying the utility of a toxic waste, plated sludge as a building material and deciding the standards of quality and use of cement and evaluating the properties of mortar and concrete in which plated sludge mixed. From an experiment, compressive strength required high early strength cement or special cement. Watertightness proved to be excellent. Heavy metals, such as Cd, Pb, Cu came out below an environmental standard. Cr+6 exceeded an environmental standard under a steam curing, but came out below an environmental under a standard curing. The higher replacement rate was, the lower frost, fusion and resistance were. Thus, got better results above the goal by condition. It was possible that plated sludge was replaced and solidified to aggregate. Therefore, it is necessary to define the standards of quality on strength, replacement rate of wastes, water permeability, endurance in other to solidify plated sludge to concrete products.

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Enviromental Application of Plasma Technology

  • Lee, Won-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.119.1-119.1
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    • 2014
  • Toxic waste disposal: Many people think that when toxic waste is dumped into the ocean or into the air, it disappears. This belief is incorrect. Rather than disappearing, it accumulates over time and slowly destroys the environment. Ultimately, it leads to the destruction of human race. Plasma is environmentally friendly: Plasma is environmentally friendly because it is created and disappears. When plasma is formed on the earth, you need certain conditions such as accelerating electrons by an electrical discharge or a particle accelerator. When this is gone, plasma completely disappears, leaving no impact on the environment. Plasmas produce radicals: Even if plasma density is low at atmospheric pressure, many radicals (excited states of molecules) are created. These radicals are chemically very aggressive. So instead of using harmful chemicals, plasma can be utilized for less of an impact on the environment. Plasma can reach very high temperatures: Plasma is also useful because when you control the density, you can easily reach high temperatures up to $5000{\sim}6000^{\circ}C$ at atmosphere pressure. Because of this heat and the chemical aggressiveness of the plasma, there are many green applications for plasma technology. Pulsed power technology: Pulsed electric field for extraction, drying and killing bacteria. Treatment of biological tissue by pulsed electric fields: Extraction of substances from cells: Sterilisation, Medical applications, Growth stimulation, Food preparation. Each application has its specialities, especially with respect to pulse shape and electric field strength.

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Principles of Chemical Risk Assessment: The ATSDR Perspective

  • Johnson Barry L.
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.405-411
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    • 1994
  • Hazardous wastes released into the general environment are of concern to the public and to public health authorities. In response to this concern, the Comprehensive Environmental Response, Compensation, and Liability Act, as amended (commonly called Superfund), was enacted in 1980 to provide a framework for environmental, public health, and legal actions concerning uncontrolled releases of hazardous substances. The Agency for Toxic Substances and Disease Registry (ATSDR) was created by Superfund to address the public health issues of hazardous wastes in the community environment. Two key Agency programs, Public Health Assessments and Toxicological Profiles, are designed to assess the risk to human health of exposures to hazardous substances that migrate from waste sites or through emergency releases (e.g., chemical spills). The Agency's public health assessment is a structured process that permits ATSDR to identify which waste sites or other point sources require traditional public health actions (e.g.. human exposure studies, health studies, registries, health surveillance, health advisories). The ATSDR qualitative public health assessment complements the U.S. Environmental Protection Agency's quantitative risk assessment. For Superfund purposes, both assessments are sitespecific. ATSDR's toxicological profiles are prepared for priority hazardous substances found most frequently at Superfund sites. Each profile presents the current toxicologic and human health effects information about the substance being profiled. Each profile also contains Minimal Risk Levels (MRLs), a type of risk assessment value. This paper covers ATSDR's experience in conducting public health assessments and developing MRLs, and it relates this experience to recommendations on how to improve chemical risk assessments.

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Research Investigations at the Municipal (2×35) and Clinical (2×5 MW) Waste Incinerators in Sheffield, UK

  • Swithenbank, J.;Nasserzadeh, V.;Ewan, B.C.R.;Delay, I.;Lawrence, D.;Jones, B.
    • Clean Technology
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    • v.2 no.2
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    • pp.100-125
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    • 1996
  • After recycle of spent materials has been optimised, there remains a proportion of waste which must be dealt with in the most environmentally friendly manner available. For materials such as municipal waste, clinical waste, toxic waste and special wastes such as tyres, incineration is often the most appropriate technology. The study of incineration must take a process system approach covering the following aspects: ${\bullet}$ Collection and blending of waste, ${\bullet}$ The two stage combustion process, ${\bullet}$ Quenching, scrubbing and polishing of the flue gases, ${\bullet}$ Dispersion of the flue gases and disposal of any solid or liquid effluent. The design of furnaces for the burning of a bed of material is being hampered by lack of an accurate mathematical model of the process and some semi-empirical correlations have to be used at present. The prediction of the incinerator gas phase flow is in a more advanced stage of development using computational fluid dynamics (CFD) analysis, although further validation data is still required. Unfortunately, it is not possible to scale down many aspects of waste incineration and tests on full scale incinerators are essencial. Thanks to a close relationship between SUWIC and Sheffield Heat&Power Ltd., an extended research programme has been carried out ar the Bernard Road Incinerator plant in Sheffield. This plant consists of two Municipal(35 MW) and two Clinical (5MW) Waste Incinerators which provide district heating for a large part of city. The heat is distributed as hot water to commercial, domestic ( >5000 dwelling) and industrial buildings through 30km of 14" pipes plus a smaller pipe distribution system. To improve the economics, a 6 MW generator is now being added to the system.

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Low & Intermediate Level Radioactive Waste Vitrification Using Plasma Arc Melting Technology

  • Min Byeong-Yeon
    • Nuclear Engineering and Technology
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    • v.35 no.5
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    • pp.482-496
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    • 2003
  • effectiveness of the PAM graphite-electrode technology for the treatment of many types of low-level radioactive waste including : combustible material, solidified resins in cement, inorganic materials, steel, glass, and solidified boric acid cement. The objectives of PAM-200 evaluation were to verify that 1) the facility meets air emission regulations, 2) the facility can be safely operated when processing hazardous and radioactive materials and 3) satisfactory final waste forms can be produced. Results, derived from KAERI's(Korea Atomic Energy Research Institute) analyses for samples of vitrified product, scrubbing solution and offgas collected during test period, show that PAM-200 can treat radioactive wastes as well as hazardous wastes with toxic constituents and radionuclides contained in the offgas exiting from the stack to the environment controlled to be far lower than the limit regulated by air conservation law and atomic law.

On the Research and Development for High Level Radioactive Waste Disposal in Korea (고준위 방사성폐기물 처분 기술개발 현황)

  • Lee, Young-Up
    • Economic and Environmental Geology
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    • v.28 no.3
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    • pp.279-286
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    • 1995
  • The amount of the high level radioactive wastes in Korea will be increased up to 14,297 MTU about 2010 year. Most of countries adopt the concept of deep burial repository in high level radioactive waste disposal. Because the high level radioactive wastes are very toxic in biosphere and to human, the data verifing its never return to the biosphere are requisite for the disposal. Presently, the evaluating techniques for the high level radioactive waste disposal are not fully developed. Therefore, in order to dispose the high level radioactive wastes in proper time the R & D of it is urged in our country. The R & D and/or the international joint research programme for the disposal of high level wastes have already been proceeded. In our country no plan for its disposal has been prepared. It is the time that the direction of the R & D is to be discused seriously. The R & D for the disposal of high level radioactive wastes in Korea is believed to be focused on developing the pecular techniques such as in situ characteristics of groundwater flowage, and change of properties of in situ rock mass at thermal effects.

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Recyling of Waste Materials for Iron Ore Sintering (제철소내 폐기물의 소결공정에서의 이용기술)

  • 문석민;이대열;정원섭;신형기
    • Resources Recycling
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    • v.3 no.3
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    • pp.12-20
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    • 1994
  • Difficulties lies on using the dust from iron making process as a raw material for sintering process mainly because of high amount of Zn or alkali content and its ultra fine characteristics. To eliminate these toxic influence, new fluxing materials were tested and could get a very successful results. This fluxing materials, Calcium-ferrite of magnesio-ferrite were made from various waste materials such as lime stone sludge, bag filter dust, waste EP dust and dolomite sludge by simple way of pre-sintering. Sintering behavior as a fluxing materials was revealed to be good in any aspects and new concept of total recycling system could be established.

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