• 한국막학회:학술대회논문집
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• 한국막학회 2001년도 제14회 심포지엄 : 제2회 분리막 표준화(The 2nd Standardization of Membranes)
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• pp.39-50
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• 2001

The performance of membranes is governed their pore struture. Pore structures of porous materials can be determined by a number of techniques. However, The novel technique, capillary folw porometry has a number of advantages. In this technique, the sample is brought in contact with a liquid that fills the pores in the membrane spontaneously. Gas under pressure is used to force the liquid from the pores and increase gas flow. Gas flow rate measured as a function of gas pressure in wet and dry samples yield data on the largest pore size, the mean flow pore size, flow distribution and permeability. Pore characteristics of a number of membranes were measured using this technique. This technique did not require the use of any toxic material and the pressure employed was low. Capillary flow porometry is a suitable technique for measurement of the pore structure of many membranes.

• E2M - 전기 전자와 첨단 소재
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• 제11권10호
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• pp.78-80
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• 1998

Metallo-phthalocyanines(MPcs) are very sensitive to toxic molecules such as electron affinitive NO2 gas and also chemically and thermally stable since losts of MPcs have been studied for the potential chemcial gas sensors for $NO_2$ using their electrical conductivity. In this study, thin films of octa-dodecyloxy copper -phthalocyanine were prepared by Langmuir-Blodgett(LB) method and characterized by using UV/Vis absorption spectroscopy, and ellipsometry. It was found that the proper transfer surface pressure for the film deposition was 25mN/m and the limiting area per molecule was $112\AA$/molecule. The film thickness of one layer was $64\AA$. Current-voltage(I-V) characteristics of these films were investigated as a function of film thickness.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.711-714
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• 2001

A new technology to make fluoride gas such as NF$_3$contained in the exhaust gas from semiconductor manufacturing plants convert directly into a harmless substance have been established and new concept on the disposal treatment of global warming gases were presented. Experimental results verify that the chemical reactions can be take place at substantially lower temperature of 80-40$0^{\circ}C$ as compared with the combustion treatment method. Reaction product is mainly metal fluoride which is a harmless and a valuable chemical material as one of new resources. The other favorable characteristics are that the continuous treatment is possible at a low temperature under atmospheric pressure. Furthermore this process is compact, easily controllable and safely operable at low running cost. This paper concerns with a new harmless disposal treatment of toxic global warming gas.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.782-784
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• 2008

Ag/Ni bimetallic cluster loading on porous carbon fibers was accomplished in order to enhance the HCl removal efficiency of the carbons. The surface properties of the Ag/Ni/carbons were determined by XRD and SEM. N2/77 K adsorption isotherms were investigated using BET and Boers t-plot methods. The HCl removal efficiency was confirmed by a gas chromatography technique, and it was found that that efficiency was predominantly improved in the presence of Ag/Ni clusters compared with the efficiencies of the as-received and single-metal-plated carbons. This indicates that synergetic reactions exist between Ag/Ni and HCl gas, resulting in advanced HCl removal capacity of porous carbons.

• 한국전기전자재료학회논문지
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• 제35권1호
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• pp.11-17
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• 2022

Direct exposure to toxic and hazardous gases has always been considered as the most pervasive problem worldwide, leading to a gradual increase in the number of asthma patients due to NO_x/SO_x gases inhaling and exposure to 50 ppm formaldehyde gases. Therefore, the development of accurate gas sensors is a key issue for resolving these problems. To address such issues, the development of membranes for selective filtering of target molecules as well as nanocatalyst for enhancing the sensing selectivity is highly crucial. In this review, the research progress for porous membrane materials (e.g. MOFs, and graphene) and nanocatalyst technology for the development of selective and accurate gas sensors will be discussed.

• 한국가스학회지
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• 제4권1호
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• pp.16-25
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• 2000

스틸렌 공중합체의 열적특성과 독성인자를 평가하기 위하여 활성화 에너지, 물리적 특성 및 마취성 기체와 같은 독성물질의 발생가능성에 대하여 조사하였다 고온 분해시에 Kissinger법과 DSC법에 의해 계산된 활성화 에너지는 25${\~}$50 Kcal/mol이었다. 이것은 화재발생가능성에 대하여 좋은 정보가 될 것이다 FED계산으로부터 PS, SAN 및 ABS에 대한 $LC_{50}$의 값은 8,580, 265 및 308 $mg/m^3$이 되었다. FT-IR에 의해 분석한 열분해 반응의 메카니즘은 측쇄반응이 아니고 주쇄반응이었다.

• 한국안전학회지
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• 제10권3호
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• pp.68-80
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• 1995

A series of parametric calculations have been performed in order to investigate the short-term and short-range plume and puff behavior of toxic gaseous and solid pollutant dispersion in an open atmosphere. The simulation is made by the use of the computer program developed by this laboratory, in which a control-volume based finite-difference method is used together with the SIMPLEC algorithm for the resolution of the pressure-velocity coupling appeared In Wavier-Stokes equation. The Reynolds stresses are solved by the standard two-equation k-$\varepsilon$ model modified for buoyancy together with the RNG(Renormalization Group) k-$\varepsilon$ model. The major parameters considered in this calculation are pollutant gas density and temperature, the relative velocity of pollutants to that of the surrounding atmospheric air, and particulate size and density together with the height released. The flow field is typically characterized by the formation of a strong recirculation region for the case of the low density gases such as $CH_4$ and air due to the strong buoyancy, while the flow is simply declining pattern toward the downstream ground for the case of heavy molecule like the $CH_2C1_2$and $CCl_4$, even for the high temperature, $200^{\circ}C$. The effect of gas temperature and velocity on the flow field together with the particle trajectory are presented and discussed in detail. In general, the results are physically acceptable and consistent.

• 한국안전학회지
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• 제28권1호
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• pp.125-131
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• 2013

When fire occurs in complex or building, toxic gas is important factor for evacuation because it cause death of evacuees. The effect of toxic gas which effects human motion is calculated using Purser's Fractional Effective Dose(FED). The FDS_EVAC is used for evacuation. However, FED of FDS_EVAC has some problem of application because it dose not considers evacuees's gender and age groups but using single subject. In this study, numerical analysis using modified FED which considers gender and age group of evacuees was performed. We investigate the effect of improved FED on the evacuation. We applied evacuation analysis to exhibition centre where the evacuees was set one thousand five hundred people. The FED is increasing with children 2%, male 17%, female 4%, adult 13% and elderly people 22%. Fatality is increasing due to increased FED.

• Design & Manufacturing
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• 제13권1호
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• pp.13-18
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• 2019

The size and prospects of the domestic semiconductor equipment market are increasing every year. In the case of various parts used inside semiconductor equipments, high durability such as high strength and abrasion resistance is demanded. Particularly, the gases used in semiconductor production processes are toxic. In order to prevent such toxic gas leakage, a precision processing technique and a surface treatment technique for preventing corrosion are required. Electro-polishing is an electro-chemical method of polishing a metal surface to make it smooth and polished. Electro-polishing is mainly used in the finishing process of metal surface. Unlike mechanical polishing, electro-polishing is used in many fields, such as fine chemical etching equipment, since no damaged layer or burr, fine polishing groove and particles are generated. However, in order to withstand the gas used in the semiconductor equipment, the parts must have high corrosion resistance. However, the surface hardness generally become lowered through electro-polishing. Therefore, in this study, surface hardness were experimentally observed before and after electro-polishing. Then, a method of improving hardness by preparing a nitrided layer by plasma ion nitriding treatment.

• 대한금속재료학회지
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• 제48권3호
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• pp.225-234
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• 2010

Salt bath nitriding, which has been developed recently by domestic company, is an emerging ecofriendly surface treatment. The salt bath nitriding is accompanied by the electrolysis process in the pretreatment step, and this whole processis called Pseudo-Electrolysised Salt bath Nitriding (PESN). The PESN creates only $NH_3$ and non-toxic salts without harmful $CN^{-}$ or toxic gas such as that found in previous salt bath nitriding. In general, ion nitriding and gas nitriding create high hardness and a strong brittle white layer on the surface. However, the PESN shows a thin white and gray layer. The PESN was applied to the defense material, 3%Cr-Mo-V steel, to study the surface characteristics at $480^{\circ}C$, $530^{\circ}C$, and $580^{\circ}C$ for 4 hrs, 20 hrs, 40 hrs, and 60 hrs of nitriding time condition. As a result, the best nitriding layer was found at $530^{\circ}C$ for 40 hrs. If we improve corrosion resistance and nitriding layer depth, the PESN will be able to be applied to the defense industry parts.