• Structural Engineering and Mechanics
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• 제56권3호
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• pp.369-383
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• 2015

In this study, effect of various material hardening models based on Holloman's isotropic, Ziegler's linear kinematic, non-linear kinematic and mixture of the isotropic and nonlinear kinematic hardening laws on springback prediction of titanium alloy (Ti-3Al-2.5V) in a tube rotary draw bending (RDB) process was investigated with presenting the keynotes for a comprehensive step by step ABAQUS simulation. Influence of mandrel on quality of the final product including springback, wall-thinning and cross-section deformation of the tube was investigated, too. Material parameters of the hardening models were obtained based on information of a uniaxial test. In particular, in the case of combined iso-nonlinear kinematic hardening the material constants were calibrated by a simple approach based on half-cycle data instead of several stabilized cycles ones. Moreover, effect of some material and geometrical parameters on springback was carried out. The results showed that using the various hardening laws separately cannot describe the material hardening behavior correctly. Therefore, it is concluded that combining the hardening laws is a good idea to have accurate springback prediction. Totally the results are useful for predicting and controlling springback and cross-section deformation in metal forming processes.

• Nuclear Engineering and Technology
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• 제25권4호
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• pp.507-514
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• 1993

Titanium재료는 해수에서 좋은 내식성을 가지는 이유로 최근 원자력발전소 복수기에 사용되고 있다. 그러나, Ti이 tubesheet재 료인 Cu 합금에 접하고 이것이 water box 재료인 탄소강에 접하게될 경우 접촉금속에 심한 galvanic corrosion이 일어나게 된다. 전기화학적 실험에 의하면, 탄소강이 해수속에서 Ti나 Cu에 접할 때 탄소강의 부식속도는 증가할 것이며, Cu가 Ti에 해수중에서 장기간 접촉할 경우에는 Cu의 부식속도는 증가할 것으로 생각된다, 또한 표면적비, R$_1$(surface area of carbon steel/surface area of Ti).와 R$_2$(surface area of carbon steel/surface area of Cu)가 탄소강의 galvanic corrosion에 매우 중요하며. Water box 재료인 탄소강의 부식속도를 최소화하기 위해서는 이들 표면적비가 낮게 유지되어서는 안될 것이라고 생각된다 침지 galvanic 부식 시험결과 surface area of Fe/surface area of Al Brass값이 1일때 탄소강의 부식속도는 4.4mpy 이었으나 이 비가 $10^{-2}$ 일때는 570mpy이었다. 이렇게 연결된 galvanic시편에 Ti tube를 연결한 경우에는 이 비가 1일때 탄소강의 부식율이 4.4mpy에서 13mpy로 증가하였다. 이는 R$_1$가 R$_2$가 분극곡선에 복합적인 영향을 미치는것으로 설명할 수 있다.

• 열처리공학회지
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• 제32권2호
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• pp.68-73
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• 2019

${\alpha}$-titanium alloy has a relatively low heat treatment characteristic and it is mainly subjected to heat treatment for residual stress, recovery or dynamic recrystallization. In this study, commercially pure titanium hollow castings was fabricated by gravity casting. Heat treatments were carried out at $750^{\circ}C$, $850^{\circ}C$ and $950^{\circ}C$ to investigate the effect of post-heat treatment on microstructure and mechanical properties. Beta-transus temperature ($T_{\beta}$) was about $913^{\circ}C$, and equiaxed microstructure was shown at temperature below $T_{\beta}$ and lath-type microstructure at temperature above $T_{\beta}$. Microstructure and mechanical properties did not show any significant difference in the direction of solidification for titanium hollow billet, so it can be seen that it was a well-made material for extrusion process. The optimum heat treatment condition of hollow billet castings for the seamless tube production was $850^{\circ}C$, 4 hr, FC, indicating a combination of equiaxed microstructure and appropriate mechanical properties.

• 대한환경공학회지
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• 제30권3호
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• pp.339-344
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• 2008

티타늄 박막을 1 M의 황산나트륨 수용액과 0.5 wt%의 불화나트륨에 의해 제조된 전해질 용액에 담지하고 전기화학적 양극산화법으로 약 20분간 20$^{\circ}C$의 온도로 수행하여 티타늄다이옥사이드 나노튜브 필름을 제작하였다. 주사전자현미경과 X선회절분석기를 이용하여 각각 미세구조와 결정구조를 측정하였으며, 나노튜브의 직경은 대략 100 nm 정도이고, 길이는 1 $\mu$m 정도로 나타났다. 이 후 티타늄다이옥사이드 나노튜브는 450에서 풀림공정을 수행하였으며, 아나타제 결정형으로 나타났다. 또한 본 연구에서는 제작된 나노튜브 박막을 이용하여 물에 용존된 휴믹산의 제거실험을 수행하였으며 Langmuir-Hinshelwood kinetic 0차 반응의 경향을 보였으며, 약 0.3 g 정도의 파우더형 광촉매와 같은 효율을 보였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 춘계학술발표회 논문집
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• pp.255-255
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• 2012

The interactions between cells and nanotopographies are increasingly interested as nanotopographies that may be more efficient in promoting cell functions and, titanium nanotubes have attracted much attention. Titanium nanotube can be fabricated easily with precisely controlled diameters and lengths. Titanium nanotubes with the suitable tube dimensions have been observed to enhance bone cell functions, whereas, there is still some controversy. These nanotubes can also serve as carriers for drugs such as growth factors, antibacterial agents and other drugs and show promise in bone implant applications.

• 한국분말재료학회지
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• 제21권5호
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• pp.371-376
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• 2014

In this study, modified catalytic chemical vapor deposition (CCVD) method was applied to control the CNTs (carbon nanotubes) growth. Since titanium (Ti) substrate and iron (Fe) catalysts react one another and form a new phase ($Fe_2TiO_5$) above $700^{\circ}C$, the decrease of CNT yield above $800^{\circ}C$ where methane gas decomposes is inevitable under common CCVD method. Therefore, we synthesized CNTs on the Ti substrate by dividing the tube furnace into two sections (left and right) and heating them to different temperatures each. The reactant gas flew through from the end of the right tube furnace while the Ti substrate was placed in the center of the left tube furnace. When the CNT growth temperature was set $700/950^{\circ}C$ (left/right), CNTs with high yield were observed. Also, by examining the micro-structure of CNTs of $700/950^{\circ}C$, it was confirmed that CNTs show the bamboo-like structure.

• 대한치과교정학회지
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• 제33권4호
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• pp.307-317
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• 2003

본 연구는 miniplate(Titanium C-tube, Martin Co., Germany)를 교정적 고정원으로 사용하여 교정력 및 악정형력을 즉시 가했을 때 miniplate의 안정성 및 주위 조직 반응을 관찰하여 고정원으로서의 유용성을 밝히고자 시행되었다. 네 마리의 비글 성견을 대상으로 하악의 좌우 협측 제3소구치와 제4소구치 사이에 두개의 titanium miniscrew(직경 2.0mm, 길이 7.0mm)에 의해 고정되는 miniplate를 식립하여 15주 동안 200-250gm의 힘을 가한 교정력 적용군과 8주 동안 400-450gm의 힘을 가한 악정형력 적용군으로 분류하였고 대조군은 제4소구치와 제1대구치사이에 식립하고 힘을 가하지 않았다. 동요도는 식립 직후와 희생 직전에 측정하여 비교하였고 희생 후 제작된 조직 절편을 방사선적으로 검사하여 주위 골의 흡수 여부를 관찰하였다. 실험 동물은 관류 고정하고 조직 절편은 레진 포매하여 비탈회 경조직 표본을 제작하였다 miniplate 제거 후의 조직의 치유와 연조직의 관찰을 위해 일부 조직편은 탈회 표본으로 제작하였다. 표본은 H&E 염색 후 광학 현미경하에서 검경하였고 위의 실험내용을 통해 다음과 같은 결과를 얻었다. 1. 교정력과 악정형력을 적용한 두 그룹 모두 miniscrew와 골간의 계면에는 직접적인 골유착이 일어났다. 힘의 크기에 따른 차이는 관찰되지 않았고, 힘의 적용기간이 증가함에 따라 골침착이 증가되었으며, 하중이 가해지지 않은 대조군이 실험군에 비해 골조직이 덜 침착되었다. 2. Miruplate와 miniscrew를 피개하고 있는 연조직은 염증소견 없이 모두 치유가 잘 일어났다. 3. 모든 실험군에서 동요도는 발생되지 않았고, 하중이 가해지지 않은 대조군의 경우 경미한 동요도를 보였으며, 교합력이 직접 가해진 대조군에서 고정원이 탈락될 정도의 동요도를 보였다. 4. Miniscrew 제거 후의 연조직 및 경조직은 정상조직의 형태와 구조로 치유되었다. 이상의 결과로 miniplate(Titanium C-tube, Martin Co., Germany)는 식립 즉시 악정형력 정도의 힘까지 수용할 수 있고, 인접 조직에 자극이 적은 골내 고정원으로서 충분한 가치가 있다고 판단되어 진다.

• Membrane and Water Treatment
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• 제9권6호
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• pp.481-487
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• 2018

Membrane clogging or fouling of the membrane caused by organic, inorganic, and biological on the surface is one of the main obstacles to achieve high flux over a long period of the membrane filtration process. So researchers have been many attempts to reduce membrane fouling and found that there is a close relationship between membrane surface hydrophilicity and membrane fouling, such that the same conditions, a greater hydrophilicity were less prone to fouling. Nanotechnology in the past decade is provided numerous opportunities to examine the effects of metal nanoparticles on the both hydrophilic and antibacterial properties of the membrane. In the present study the improvement of hydrophilic and antimicrobial properties of the membrane was evaluated by adding nanoparticles of titanium dioxide and copper oxide. For this purpose, 4% copper oxide and titanium dioxide nanoparticles with a ratio of 0, 30, 50, and 70% of copper oxide added to the polymeric membrane and compare to the pure polymeric membrane. Comparison experiments were performed on E. coli PTCC1998 in two ways disc and tube and also to evaluate membrane hydrophilic by measuring the contact angle and diameter of pores and analysis point SEM has been made. The results show that the membrane-containing nanoparticle has antibacterial properties and its impact by increasing the percentage of copper oxide nanoparticles increases.

• 한국세라믹학회지
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• 제31권6호
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• pp.637-642
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• 1994

Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

• 한국표면공학회지
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• 제55권1호
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• pp.1-8
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• 2022

Titanium dioxide (TiO₂) is one of the most intensively investigated materials in materials science. Mostly, TiO₂ has been used in the form of nanoparticles, but recently new highly ordered TiO₂ nanotubes (U-tube) has been introduced and applied to various applications due to their one-dimensional charge path way. In the present paper, we described the formation process and physical properties of U-tube then, gave examples of applications in sequence. Firstly, in photocatalysis, U-tube was used with Au/Pt co-catalysts and showed enhanced photogenerated H₂ efficiency compared to bare TiO₂. Secondly, photoelectrochemical performance of U-tube was evaluated with different heat-treatment temperatures. As a further application, two different types of electrical cell (Ti-TiO₂-Pt and Ti-TiO₂-Pt_NP) was configurated to observe memristive behavior of U-tube. Both cells behaved as switching electrodes and follow a memristive movement in the high and low resistance state extremely well with high reproducibility.