• The Journal of Korean Academy of Prosthodontics
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• v.45 no.1
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• pp.119-130
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• 2007

Statement of problem: A few dry lubricants were applied to abutment screws for the improvement of joint stability. Purpose: The purpose of this study was to evaluate the surface change and fit of TiN-Coated abutment screw through the examination of tested screws in the field emission scanning electron microscope(FE-SEM;Netherland, Phillips co., model:XL 30 SFEG) after repeated closing and opening. Materials and method: Titanium(3i/implant Innovations Inc, USA) and Gold-Tite abutment screws(3i/implant Innovations Inc, USA) were selected for Group A and C respectively. TiN coated titanium abutment screws were also divided into two groups, Group B and D. Abutment screws of each group and the fit of abutment screw/implant fixture/abutment were observed on FE-SEM after repeated closing and opening test respectively. Results: 1. The abutment screws of TiN coated groups(Group B and D) showed more remarkable wear resistance in the threads of the screw than those of the other group(Group A and C). 2. There were more severe wear and defect of TiN coating in Group D tightened to 32 Ncm than Group B to 20 Ncm. 3. There was no difference in the fit of abutment screw/fixture/abutment among four groups, Group A, Group B, Group C and Group D. Conclusion: Under the conditions of this study, it is suggested that TiN coating of abutment screw be clinically acceptable and be expected to reduce the risk of abutment screw loosening. TiN coating of abutment screw showed good resistance against wear and the adequate fit of abutment screw/implant fixture/abutment.

• Korean Chemical Engineering Research
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• v.45 no.4
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• pp.335-339
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• 2007

In order to overcome the problem of poor hardness of transparent polycarbonate (PC) sheets, organic-inorganic hybrid hard coating solutions, which show a high refractive index above 1.58, were made by the sol-gel method. These hybrid coating solutions were obtained from mixture of titanium tetraisopropoxide (TTIP), and (3-glycidoxypropyl)trimethoxysilane (GPTMS). The PC sheets were spin-coated, and cured at $120^{\circ}C$ for 2 hr. Change of refractive index in the range of 1.53-1.61 was obtained by varying the GPTMS content. The refractive index of the coated film decreased with increasing the GPTMS content, while the pencil hardness of the coated film was found to increase with increasing the GPTMS content.

• The Journal of Advanced Prosthodontics
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• v.1 no.1
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• pp.47-55
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• 2009

STATEMENT OF PROBLEM. A few of studies which compared and continuously measured the stability of various surface treated implants in the same individual had been performed. PURPOSE. We aim to find the clinical significance of surface treatments by observing the differences in the stabilization stages of implant stability. MATERIAL AND METHODS. Eight different surface topographies of dental implants were especially designed for the present study. Machined surface implants were used as a control group. 4 nano-treated surface implants(20 nm $TiO_2$ coating surface, heat-treated 80 nm $TiO_2$ coating surface, CaP coating surface, heat treated CaP coating surface) and 3 micro-treated surface implants [resorbable blast media(RBM) surface, sandblast and acid-etched(SAE) surface, anodized RBM surface] were used as experiment groups. All 24 implants were placed in 3 adult dogs. $Periotest^{(R)}$ & ISQ values measured for 8 weeks and all animals were sacrificed at 8 weeks after surgery. Then the histological analyses were done. RESULTS. In PTV, all implants were stabilized except 1 failed implants. In ISQ values, The lowest stability was observed at different times for each individual. The ISQ values were showed increased tendency after 5 weeks in every groups. After 4 to 5 weeks, the values were stabilized. There was no statistical correlation between the ISQ values and PTV. In the histological findings, the bone formation was observed to be adequate in general and no differences among the 8 surface treated implants. CONCLUSIONS. In this study, the difference in the stability of the implants was determined not by the differences in the surface treatment but by the individual specificity.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.765-773
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• 2000

The degradation of humic acid using $TiO_2$ coatings was studied, $TiO_2$ coatings were prepared by dip-coating method. Sol solutions for coating were prepared by mixing the gel, which can be produced by the reaction of $TiOCl_2$ and $NH_4OH$ solution, and hydrogen peroxide solution, and hydrolysis of titanium tetraisopropoxide (TTIP). It was shown from XRD that coatings from sol aged at $100^{\circ}C$ for 18h with titanium peroxo solution were crystallized to anatase in the range of temperatures of $25^{\circ}C$ to $500^{\circ}C$. In contrast, those coated from TTIP were crystallized to anatase at temperature above $400^{\circ}C$. So the sols originated from $TiCl_4$ can be applied for not only on the heat-resistance substrates but on the plastic substrates. Thickness and the quality of the films were dependent on the withdrawing speed, the concentration of sol, and the number of coating. The films showed various interference colors depending on the thickness of them. In the case that the films coated 2 times at withdrawing speed of 2.5cm per minute by 0.2M sol, the films had a transparent light blue color with thickness of around 50nm. It was known from the result of photo-degradation by $TiO_2$ coatings using humic acid that the removal efficiency of $COD_{cr}$ was over 85% after illumination of $UV/H_2O_2$ for 40min. and that of UV/VIS absorbable materials was over 95%.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.152.1-152.1
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• 2007

• Journal of Periodontal and Implant Science
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• v.25 no.2
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• pp.418-437
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• 1995

The effect of the hydroxyapatite coatings on Titanium implants has been the subject of recent investigations. So far, the use of HA coating remains substantially controversial.This study was aimed to evaluate histologically the bone healing patterns around titanium plasm sprayed(TPS) amd HA-coated implant after implantation into the femur neck of ten adult dogs. After implantation, animals were sacrificed at the intervals of 2,4,6,8 and 12 weeks.The fluorescent dyes were injected on the postoperative 4th and 12th week into the animals supposed to be killed at the 12th week. The morphology and direction of new bone formation was similar in both TPS and HA-coated implants.There was a tendency toward more bone formation in the cortical bone area than in the cancellous bone area. Histologically,in the interface of the HA-coated implants, bone response and bone maturation was faster, compared to the TPS implants in the 2nd and 4th week. By fluorescent microscopy, new bone formation was active in the 4th week around both implants and was directed from the periosteum overlying cortical bone to the cancellous bone. These results suggest that the bone formation and maturation is faster during the early healing stage in the interface of the HA-coated implant and where the cortical bone quality is poor, HA coated implant is superior to the TPS implant in the early phase of new bone formation.

• Journal of Korea Foundry Society
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• v.27 no.3
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• pp.135-139
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• 2007

To produce higher quality of titanium casting at a lower cost, the new titanium casting technology by using a permanent metal mold was developed and applied to fabricate hip joint for biomedical application. The present study was carried out to investigate the reactivity and fluidity of the Ti-6.0 wt%Al-4.0 wt%V alloy with metal mold by applying various ceramic powders coating on the mold surface. The molten titanium for manufacturing hip joint was poured into steel mold. No reaction layer was formed on the surface of specimens fabricated steel mold coated with $Y_2O_3$ powder.

• Journal of Energy Engineering
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• v.14 no.2 s.42
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• pp.105-111
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• 2005

In this study, the photocatalytic degradtion of D-glucose with the micro channel reactor was performed on the various experimental conditions. To apply the $TiO_2$ coating on the micro channel reactor, $TiO_2$ solution was synthesized by hydrolysis of titanium oxysulfate. The feeding rate was proportional to degradation rate of D-glucose solution over the micro channel reactor. Also, the reaction rate constant and Langmuir adsorption coefficient were calculated under various experimental conditions. And the results of these system photonic efficiencies were calculated. This study aims to understand the photocatalytic degradation characteristics on $TiO_2$ coating in the micro channel reactor experimented by the feed batch reaction system.

• Journal of Technologic Dentistry
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• v.31 no.4
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• pp.15-23
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• 2009

The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

• Journal of Powder Materials
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• v.29 no.4
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• pp.297-302
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• 2022

This study compares the characteristics of a compact TiO₂ (c-TiO₂) powdery film, which is used as the electron transport layer (ETL) of perovskite solar cells, based on the manufacturing method. Additionally, its efficiency is measured by applying it to a carbon electrode solar cell. Spin-coating and spray methods are compared, and spray-based c-TiO₂ exhibits superior optical properties. Furthermore, surface analysis by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibits the excellent surface properties of spray-based TiO₂. The photoelectric conversion efficiency (PCE) is 14.31% when applied to planar perovskite solar cells based on metal electrodes. Finally, carbon nanotube (CNT) film electrode-based solar cells exhibits a 76% PCE compared with that of metal electrode-based solar cells, providing the possibility of commercialization.