• Title/Summary/Keyword: Titanium carbide

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Simple Modeling for Laser Scribing (레이저 화선의 모델링)

  • Chung, Chulsup
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2002.10a
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    • pp.94-103
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    • 2002
  • Accurately controlling the shape of the read/write head structure is critical in the performance of a modern hard disk drive. The sliders investigated are composed of alumina and titanium carbide (AlTiC) and act as an air bearing when passing over the disks. Controlling the curvature of the slider is of primary importance. A laser scribing system that produces curvature by Inducing residual stress into the slider can be utilized. Predicting the curvature created by a pattern of scribes is of great importance to increase the control over the sliders' shape. Using finite element analysis a force system that produces stresses similar to the laser scribing is applied. The curvatures created by the force system are calibrated to experimental measurements.

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Mechanical Properties and Cutting Performance of Ti(CN) Based Carbonitride Ceramics (Ti(CN)기 탄화물질 세라믹스의 기계적 특성과 절삭성능)

  • Park, Dong-Su;Lee, Yang-Du;Jeong, Tae-Ju;Gang, Sin-Hu
    • 연구논문집
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    • s.28
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    • pp.193-207
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    • 1998
  • Fully dense THCN) based carbonitride ceramics were fabricated by pressureless sintering. During sintering, solid solutions were formed from the ceramic ingredients. The ceramics exhibited microvickers hardness of 1560-2050kgf/mm2, fracture toughness of 3.0-5.4 MPa $m^(1/2)$, and three point flexural strength of 645-1072 MPa. Some of the ceramics were shaped in a cutting tool, and the cutting performance was evaluated. In case of cutting SCM440 alloy steel, the ceramics showed better performance than the commercially available alumina-titanium carbide ceramic cutting tool. Considering the excellent productivity of pressureless sintering compared with other densification methods and their cutting performance, this new class of ceramics are very promising for wear resistant applications.

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Influence of Carbon Vacancies on CO Chemisorption on TiC(001): A Theoretical Study

  • Kang, Dae-Bok
    • Journal of the Korean Chemical Society
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    • v.61 no.1
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    • pp.7-11
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    • 2017
  • The extended $H{\ddot{u}}ckel$ method is employed to analyze the interaction of carbon monoxide with the TiC(001) surfaces, both perfect and containing carbon vacancies. CO exhibits a similar ${\sigma}$-donation interaction for both $Ti_{25}C_{25}$ and $Ti_{25}C_{23}$ clusters, as deduced from the fact that the populations of the CO $5{\sigma}$ orbital are identical upon adsorption, but it bonds more strongly with the $Ti_{25}C_{23}$ than with the $Ti_{25}C_{25}$ because the metal d electron density in $Ti_{25}C_{23}$ provides ${\pi}$ back-bonding interactions with CO that are absent in $Ti_{25}C_{25}$. This work suggests that a difference in reactivity toward CO of stoichiometric TiC and TiC with carbon defects is connected with the occupancy of $2{\pi}^*$ orbitals that leads to a significant weakening of the C-O bond.

A Study on the Cutting Characteristics and Analysis by a FEM in the Machining of Ti-6Al-4V alloy (Ti-6Al-4V 합금의 절삭특성과 FEM 해석 비교에 관한 연구)

  • 김남용;홍우표;이동주
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.6
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    • pp.29-35
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    • 2001
  • The cutting characteristics of Ti-6Al-4V alloy and total wear when machining Ti-6Al-4V alloy was studied to understand the machining characteristics. This material is one of the strong candidate materials present and future aerospace or met ical applications. Nowadays their usage has already been broaden to commercial applications such as golf club head, finger rings and many decorative items. Anticipating the general use of this material and development of the titanium alloy in domestic facilities, the review and the study of the machining parameters far those alloys are deemed necessary. This study is concentrated to the machining parameters of the Ti-6Al-4V alloy due to their dominant position in the production of tita mum alloys.

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Large Scale Production of Nanoparticles by Laser Pyrolysis

  • Tenegal, Francois;Guizard, Benoit;Reau, Adrien;Ye, Chang;Boulanger, Loic;Giraud, Sophie;Canel, Jerome
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.150-151
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    • 2006
  • Laser pyrolysis is a very suitable method for the synthesis of a wide range of nanoparticles. A pilot unit based on this process has been recently developed at CEA. This paper reports results showing the possibility to produce SiC and $TiO_2$ nanoparticles at rates of respectively 1 and 0.2 kg/h and also the possibility to adjust the mean grain size of the particles and their structure by changing the laser intensity and reactants flow rates. First tests of liquid recovery have been also successfully performed to limit the risks of nanoparticles dissemination in the environement during their recovery.

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Electrochemical Characteristics of 2-Dimensional Titanium Carbide(MXene)/Silicon Anode Composite Prepared by Electrostatic Self-assembly (정전기적 자가결합법으로 제조된 2차원 티타늄 카바이드(MXene)/실리콘 음극 복합소재의 전기화학적 특성)

  • Dong Min Kim;Jong Dae Lee
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.262-268
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    • 2024
  • In this study, the MXene/Si composite was prepared by electrostacic assembly with 2-dimensional structured titanium carbide (MXene) and nano silicon for anode material of high-performance lithium-ion battery. Ti3C2Tx MXene was synthesized by etching the Ti3AlC2 MAX with LiF/HCl, and the surface of nano silicon was charged to positively using CTAB (Cetyltrimethylammonium bromide). The MXene/Si anode composite was successfully manufactured by simple mixing process of synthesized MXene and charged silicon. The physical and electrochemical properties of prepared composite were investigated with MXene-silicon composition ratio, and the surface of electrode after cycles was analyzed to evaluate stability of the electrode. The MXene/Si composites demonstrated high initial discharge capacities of 1962.9, 2395.2 and 2504.3 mAh/g as the silicon composition ratio increased to 2, 3 and 4 compared to MXene, respectively. MXene/Si-4, which is MXene and silicon ratio with 1 : 4, exhibited 1387.5 mAh/g of reversible capacity, 74.5% of capacity retention at 100 cycles and high capacity of 700.5 mAh/g at high rate of 4.0 C. As the results, the MXene/Si composite prepared by electrostatic-assenbly could be applied to anode materials for high-performance LIBs.

Material Removal Rate Modeling of SiO2/TiO2 Mixed-Abrasive Slurry CMP for SiC (SiO2/TiO2 혼합입자 슬러리 SiC CMP의 재료제거율 모델링)

  • Hyunseop Lee
    • Tribology and Lubricants
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    • v.39 no.2
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    • pp.72-75
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    • 2023
  • Silicon carbide (SiC) is used as a substrate material for power semiconductors; however, SiC chemical mechanical polishing (CMP) requires considerable time owing to its chemical stability and high hardness. Therefore, researchers are attempting to increase the material removal rate (MRR) of SiC CMP using various methods. Mixed-abrasive CMP (MAS CMP) is one method of increasing the material removal efficiency of CMP by mixing two or more particles. The aim of this research is to study the mathematical modeling of the MRR of MAS CMP of SiC with SiO2 and TiO2 particles. With a total particle concentration of 32 wt, using 80-nm SiO2 particles and 25-nm TiO2 particles maximizes the MRR at 8 wt of the TiO2 particle concentration. In the case of 5 nm TiO2 particles, the MRR tends to increase with an increase in TiO2 concentration. In the case of particle size 10-25 nm TiO2, as the particle concentration increases, the MRR increases to a certain level and then decreases again. TiO2 particles of 25 nm or more continuously decreased MRR as the particle concentration increased. In the model proposed in this study, the MRR of MAS CMP of SiC increases linearly with changes in pressure and relative speed, which shows the same result as the Preston's equation. These results can contribute to the future design of MAS; however, the model needs to be verified and improved in future experiments.

Osteopromotive effect of Titanium Reinforced-ePTFE membrane (티타늄강화 차폐막의 골유도 재생 효과)

  • Lee, Jean;Kwon, Young-Hyuk;Park, Joon-Bong;Herr, Yeek;Chung, Jong-Hyuk;Kim, Chong-Kwan
    • Journal of Periodontal and Implant Science
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    • v.34 no.4
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    • pp.711-722
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    • 2004
  • The purpose of this study is to evaluate the regenerated bone histollogically using titanium reinforced ePTFE(TR-ePTFE) membrane and to investigate cell occlusiveness, wound stabilization and tissue integration of TR-ePTFE membrane. Adult male rabbits (mean BW 2kg) and TR9W (W.L.Gore&Associate.INC,USA) were used in this study. Intramarrow penetration defects were surgically created with round carbide bur(HP long #6) on calvaria of rabbits. TR-ePTFE membrane was applied to defect. Then guided bone regeneration was carried out using TR-ePTFE membrane and resorbable suture. At 2,4,8,12 weeks after the surgery, animals were sacrificed. Nondecalcified specimens were processed for histologic analysis. The result and conclusion of this study were as follows: 1. TR-ePTFE membrane had good ability of biocompatibility and cell occlusiveness. 2. space making for guided bone regenerayion was good at TR-ePTFE membrane. 3. Tissue integration was not good at TR-ePTFE membrane. So, wound stabilization was not good. 4. At 8 weeks, 12 weeks after GBR procedure, bone formation was seen. From the above results, TR-ePTFE membrane fixed tightiy on alveolar bone might be recommended for the early bone formation.

Tribological Characteristics of TiC, TiN and TiC/TiN Coatings (TiC, TiN과 TiC/TiN 코팅의 트라이볼로지 특성)

  • Jeon, Chan Yeal
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.3
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    • pp.1253-1258
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    • 2014
  • The tribological properties of TiC, TiN and TiC/TiN coatings on steels prepared by the cathodic-arc (CA) ion plating technique were investigated. Experiments were carried out on a tribo-test machine using a Falex journal V block system. The friction and wear characteristics of the coatings were determined by varying the applied load and sliding speed. The TiC, TiN and TiC/TiN coatings markedly increased the tribological characteristics of the surface. As far as a single layer coating was concerned, TiN goes better results than TiC. However, the TiC/TiN multilayer coating performed better than either single layer coating. The major factor in the improved performance of the multilayer coating was the role of TiC in improving the adhesion between the external TiN layer and the substrate steel.

Influence of abutment materials on the implant-abutment joint stability in internal conical connection type implant systems

  • Jo, Jae-Young;Yang, Dong-Seok;Huh, Jung-Bo;Heo, Jae-Chan;Yun, Mi-Jung;Jeong, Chang-Mo
    • The Journal of Advanced Prosthodontics
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    • v.6 no.6
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    • pp.491-497
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    • 2014
  • PURPOSE. This study evaluated the influence of abutment materials on the stability of the implant-abutment joint in internal conical connection type implant systems. MATERIALS AND METHODS. Internal conical connection type implants, cement-retained abutments, and tungsten carbide-coated abutment screws were used. The abutments were fabricated with commercially pure grade 3 titanium (group T3), commercially pure grade 4 titanium (group T4), or Ti-6Al-4V (group TA) (n=5, each). In order to assess the amount of settlement after abutment fixation, a 30-Ncm tightening torque was applied, then the change in length before and after tightening the abutment screw was measured, and the preload exerted was recorded. The compressive bending strength was measured under the ISO14801 conditions. In order to determine whether there were significant changes in settlement, preload, and compressive bending strength before and after abutment fixation depending on abutment materials, one-way ANOVA and Tukey's HSD post-hoc test was performed. RESULTS. Group TA exhibited the smallest mean change in the combined length of the implant and abutment before and after fixation, and no difference was observed between groups T3 and T4 (P>.05). Group TA exhibited the highest preload and compressive bending strength values, followed by T4, then T3 (P<.001). CONCLUSION. The abutment material can influence the stability of the interface in internal conical connection type implant systems. The strength of the abutment material was inversely correlated with settlement, and positively correlated with compressive bending strength. Preload was inversely proportional to the frictional coefficient of the abutment material.